IP Library › Granted Patent US 12,576,560
Granted Patent B2
US 12,576,560 · App. 18/274,750 · Granted Mar 17, 2026

Method for obtaining a recycled material from multilayer pet containers and recycled material obtained using same

Inventors: Cristina Paola Pavón Vargas (Valencia, ES); José Miguel Ferri Azor (Valencia, ES); Joaquín Vilaplana Cerda (Ibi, ES); Santiago Ferrándiz Bou (Valencia, ES); Luis Jesús Quiles Carillo (Valencia, ES); Asunción Martínez García (Ibi, ES); Francisco José Parres García (Valencia, ES); José Enrique Crespo Amorós (Valencia, ES); Harrison De La Rosa Ramírez (Valencia, ES); María Dolores Samper Madrigal (Valencia, ES); Miguel Fernando Aldas Carrasco (Valencia, ES); Daniel García García (Valencia, ES); Juan López Martínez (Valencia, ES)
Assignees: Universitat Politècnica de València; ASOCIACIÓN DE INVESTIGACÓN DE LA INDUSTRIA DEL JUGUETE, CONEXAS Y AFINES (AIJU)
B29B17/0036B29B17/0412B29C48/022B29C48/05B29B2017/0286B29B2017/042B29K2023/06B29K2023/12B29K2067/003B29K2105/0088B29K2105/26B29L2009/00B29L2031/712
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Quick Facts
Patent No.
US 12,576,560
App. No.
18/274,750
Granted
Mar 17, 2026
Kind
B2
Abstract

A method for obtaining mechanically recoverable recycled material from multilayer PET (polyethylene terephthalate) containers of post-consumer and/or post-industrial origin involves cleaning the containers, crushing them into pieces, mixing the pieces with a compatibilizing mixture and melting the mixed product to obtain a continuous filament. The compatibilising mixture is formed by at least: 10-45% thermoplastic polyolefin matrix; a reagent of plant origin in a percentage of less than 7.5% of the total mixture; and a rosin-based tackifier in a percentage of less than 7.5% of the total mixture.

Claims (16)

1 . A method for obtaining a recycled material from multilayer PET containers of post-consumer and/or post-industrial origin, comprising the steps of:

cleaning the multilayer PET containers using a soapy solution,

separating film and/or labels from the multilayer PET containers, obtaining a clean multilayer PET material,

crushing the clean multilayer PET material into pieces having a size of at least 1 mm,

mixing the clean crushed multilayer PET material in a percentage of 50% to 85% of a total mixture, with a compatibilising mixture formed by at least a thermoplastic polyolefin matrix in a percentage of between 10% and 45% of the total mixture, a reagent of plant origin in a percentage of less than 7.5% of the total mixture, and a rosin-based tackifier in a percentage of less than 7.5% of the total mixture, and

melting the mixture obtained in the preceding step by means of extrusion at a temperature of between 270° C. and 300° C. to obtain a continuous filament.

2 . The method for obtaining a recycled material from multilayer PET containers according to claim 1 , wherein the cleaning step is performed by means of mechanical stirring, at a temperature of at least 60° C. and wherein the soapy solution is formed by an aqueous solution with 2% soap, the soap being formed by 15% anionic surfactants and 5% non-ionic surfactants.

3 . The method for obtaining a recycled material from multilayer PET containers according to claim 1 , wherein in the crushing step the clean crushed multilayer PET material is obtained in the form of flakes with a size smaller than 5 mm by 5 mm.

4 . The method for obtaining a recycled material from multilayer PET containers according to claim 1 , further comprising the step of cutting by means of a pellet press to section the continuous filament obtained in the melting step, resulting in thermoplastic chippings.

5 . The method for obtaining a recycled material from multilayer PET containers according to claim 1 , further comprising a moulding step involving modelling of the continuous filament obtained in the melting step by means of a nozzle having a configuration such that it allows obtaining thermoplastic sheets and/or profiles.

6 . A recycled material obtained from the method according to claim 1 , wherein the recycled material is formed by clean crushed multilayer PET material in a percentage of 50% to 85% of the total mixture and a compatibilising mixture formed by at least a thermoplastic polyolefin matrix in a percentage of between 10% and 45% of the total mixture, a reagent of plant origin in a percentage of less than 7.5% of the total mixture, and a rosin-based tackifier in a percentage of less than 7.5% of the total mixture.

7 . The recycled material according to claim 6 , wherein the thermoplastic polyolefin matrix is made up of polyethylene and/or polypropylene.

8 . The recycled material according to claim 6 , wherein the thermoplastic polyolefin matrix is made up of copolymers of ionomers, ethylene-vinyl acetate, or random copolymers of polypropylene.

9 . The recycled material according to claim 6 , wherein the reagent of plant origin is an epoxidised soybean oil, an epoxidised linseed oil, and/or a maleinised linseed oil.

10 . The recycled material according to claim 6 , wherein the recycled material is in a format of thermoplastic chippings.

11 . The recycled material according to claim 6 , wherein the recycled material is in a format of thermoplastic sheets or profiles.

Assignments (2)
CORRECTIVE ASSIGNMENT TO CORRECT THE SECOND ASSIGNEE'S NAME PREVIOUSLY RECORDED AT REEL: 64415 FRAME: 103. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT. Recorded Feb 13, 2025
From: PAVÓN VARGAS, CRISTINA PAOLA; FERRI AZOR, JOSÉ MIGUEL; VILAPLANA CERDA, JOAQUÍN; FERRÁNDIZ BOU, SANTIAGO; QUILES CARRILLO, LUIS JESÚS; MARTÍNEZ GARCÍA, ASUNCIÓN; PARRES GARCÍA, FRANCISCO JOSÉ; CRESPO AMORÓS, JOSÉ ENRIQUE; DE LA ROSA RAMÍREZ, HARRISON; SAMPER MADRIGAL, MARÍA DOLORES; ALDAS CARRASCO, MIGUEL FERNANDO; GARCÍA GARCÍA, DANIEL; LÓPEZ MARTÍNEZ, JUAN
To: UNIVERSITAT POLITÈCNICA DE VALÈNCIA; ASOCIACIÓN DE INVESTIGACIÓN DE LA INDUSTRIA DEL JUGUETE, CONEXAS Y AFINES (AIJU)
Reel/Frame 070208/0642 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 28, 2023
From: PAVÓN VARGAS, CRISTINA PAOLA; FERRI AZOR, JOSÉ MIGUEL; VILAPLANA CERDA, JOAQUÍN; FERRÁNDIZ BOU, SANTIAGO; QUILES CARRILLO, LUIS JESÚS; MARTÍNEZ GARCÍA, ASUNCIÓN; PARRES GARCÍA, FRANCISCO JOSÉ; CRESPO AMORÓS, JOSÉ ENRIQUE; DE LA ROSA RAMÍREZ, HARRISON; SAMPER MADRIGAL, MARÍA DOLORES; ALDAS CARRASCO, MIGUEL FERNANDO; GARCÍA GARCÍA, DANIEL; LÓPEZ MARTÍNEZ, JUAN
To: UNIVERSITAT POLITÈCNICA DE VALÈNCIA; ASOCIACIÓN DE INVESTIGACIÓN DE LA INDUSTRIAL DEL JUGUETE, CONEXAS Y AFIJES (AIJU)
Reel/Frame 064415/0103 →
Priority Claims (1)
ES ESP202130117 · Feb 15, 2021 · national
Continuity (1)
Related Publication 20250018612A1 · Jan 16, 2025
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