Frits for use in vacuum insulating glass (VIG) units, and/or associated methods
Certain example embodiments of this invention relate to vacuum insulating glass (VIG) units having improved seals made using two different frit-based edge seal materials, and/or methods of making the same. In certain example embodiments, a first frit material is applied around peripheral edges of first and second glass substrates. The first frit material, which may be bismuth-based in certain example embodiments, is fired with a heat treatment (e.g., thermal tempering) process. A second frit material, which may be VBZ-based in certain example embodiments, is applied and at least partially overlaps with the fired first frit material. The first frit material acts as a primer, and the second frit material helps seal together the VIG unit. The second frit material is fired at a significantly lower temperature that enables the glass to retain the temper or other strength imparted by the heat treatment.
1. A kit comprising first and second frit materials for use in forming an edge seal for a vacuum insulating glass (VIG) window unit, wherein:
the first frit material is a bismuth oxide based frit material, and the second frit material is a vanadium oxide based frit material, these being the largest components of the first and second frit materials, respectively;
the first frit material comprises, by weight, 70-80 wt. % bismuth oxide, 2-7 wt. % zinc oxide, 5-15 wt. % silicon oxide, 2-7 wt. % aluminum oxide, 0-5% magnesium oxide, 0-5% chromium oxide, 0-5% iron oxide, 0-5% cobalt oxide, 0-5% sodium oxide, 0-5% manganese oxide, and 0-5% barium oxide; and
the second frit material comprises vanadium oxide, barium oxide, and zinc oxide, in amounts that total at least 65% by weight, wherein vanadium oxide, barium oxide and zinc oxide are the three largest components of the second frit material,
the first frit material configured to be fusable to glass when the glass reaches a first temperature of 550 degrees C. or higher, and
the second frit material configured to form a bond with the first frit material in making the edge seal for the VIG window unit and be meltable when the glass reaches at a second temperature of no more than 400 degrees C., the first frit material being wettable at the second temperature.
2. The kit of claim 1 , wherein the second frit material comprises 45-67 wt. % vanadium oxide, 7-25 wt. % barium oxide, and 4-17 wt. % zinc oxide.
3. The kit of claim 2 , wherein the second frit material further comprises 0-13 wt. % tellurium oxide, 0-13 wt. % molybdenum oxide, 0-13 wt. % tantalum oxide, and 0-13 wt. % niobium oxide, and
wherein at least one of the tellurium oxide, molybdenum oxide, tantalum oxide, and niobium oxide is provided at at least 0.25 wt. %.
4. The kit of claim 1 , wherein the first and/or second frit material(s) comprise(s) coefficient of thermal expansion (CTE) filler material, the CTE filler material lowering the CTE thereof when introduced therein.
5. The kit of claim 1 , wherein the first and/or second frit materials are lead free.
6. The kit of claim 1 , wherein the first and/or second frit materials contain less than 1 ppm lead.
7. The kit of claim 1 , wherein the first frit material is a primer frit material and the second frit material is a sealing frit material.
8. The kit of claim 7 , wherein the first frit material and second frit materials are also usable in forming a seal between a pump-out tube of a VIG unit and an inner surface of a hole formed in a substrate of the VIG unit in which the pump-out tube is located.
9. The kit of claim 1 , further comprising first and second glass substrates to be hermetically sealed together using the first frit as a primer frit and the second frit as a sealing frit.
10. A system for use in forming an edge seal for a vacuum insulating glass (VIG) window unit, the system comprising:
a first frit material that is a bismuth oxide based frit material, and a second frit material that is a vanadium oxide based frit material, these being the largest components of the first and second frit materials, respectively;
wherein the first frit material comprises, by weight, 70-80 wt. % bismuth oxide, 2-7 wt. % zinc oxide, 5-15 wt. % silicon oxide, 2-7 wt. % aluminum oxide, 0-5% magnesium oxide, 0-5% chromium oxide, 0-5% iron oxide, 0-5% cobalt oxide, 0-5% sodium oxide, 0-5% manganese oxide, and 0-5% barium oxide;
wherein the second frit material comprises vanadium oxide, barium oxide, and zinc oxide, in amounts that total at least 65% by weight, wherein vanadium oxide, barium oxide and zinc oxide are the three largest components of the second frit material,
the first frit material configured to be fusable to glass for the VIG window unit when the glass reaches a first temperature of 550 degrees C. or higher, and
the second frit material configured to form a bond with the first frit material in making the edge seal for the VIG window unit and be meltable when the glass reaches at a second temperature of no more than 400 degrees C., the first frit material being wettable at the second temperature.