IP Library Granted Patent US 10,429,757
Granted Patent B2
US 10,429,757 · App. 15/974,187 · Granted Oct 1, 2019

Toner

Inventors: Sara Yoshida (Mishima, JP); Shinsuke Mochizuki (Yokohama, JP); Tsuneyoshi Tominaga (Suntou-gun, JP); Kenta Kamikura (Yokohama, JP); Tsutomu Shimano (Mishima, JP); Kentaro Yamawaki (Mishima, JP); Akane Masumoto (Suntou-gun, JP); Tomonori Matsunaga (Suntou-gun, JP); Kunihiko Nakamura (Gotemba, JP); Toshihiko Katakura (Kashiwa, JP); Shiro Kuroki (Suntou-gun, JP)
Assignee: Canon Kabushiki Kaisha
G03G9/09328G03G9/08G03G9/0819G03G9/0821G03G9/0825G03G9/08711G03G9/08755G03G9/08773G03G9/09307G03G9/09342G03G9/09364G03G9/09371G03G9/09392G03G9/09708G03G9/09783G03G9/1136G03G9/0833G03G9/107
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Quick Facts
Patent No.
US 10,429,757
App. No.
15/974,187
Granted
Oct 1, 2019
Kind
B2
Abstract

A toner comprising a toner particle that contains a binder resin and a release agent, wherein the toner particle has a surface layer that contains an organosilicon polymer and the luminance histogram of a backscattered electron image of the toner particle has two peak values P 1 and P 2 and a minimum value V between P 1 and P 2 , P 2 originates from the organosilicon polymer, and the luminance giving P 1 and P 2 are in specific ranges, percentages for P 1 and P 2 are each at least 0.50%, and using the luminance Bl at V as a reference point, specific relationships are satisfied by A 1 , AV, and A 2 , where A 1 is the total number of pixels at luminance from 0 to (Bl−30 ), AV is the total number of pixels at luminance from (Bl−29 ) to (Bl+29 ), and A 2 is the total number of pixels at luminance from (Bl+30 ) to 255.

Claims (19)

1. A toner comprising a toner particle containing a binder resin and a release agent, wherein

the toner particle has a surface layer that contains an organosilicon polymer; and

for a luminance histogram, obtained by acquiring a backscattered electron image of a 1.5 μm-by-1.5 μm square of the surface of the toner particle in scanning electron microscopic observation of the toner particle surface, and classifying a luminance of each pixel constituting this backscattered electron image into 256 levels from a luminance of 0 to a luminance of 255, and moreover placing the luminance on an abscissa and the number of pixels on an ordinate in this luminance histogram,

(i) two peak values P 1 and P 2 and a minimum value V between P 1 and P 2 are present, and the peak containing P 2 is a peak originating from the organosilicon polymer,

(ii) the luminance giving P 1 is from 20 to 70,

(iii) the luminance giving P 2 is from 130 to 230,

(iv) a percentage for P 1 and a percentage for P 2 with respect to the total number of pixels in the backscattered electron image are each at least 0.50%, and

(v) formulas (1) and (2) below are satisfied

( A 1/ AV )≥1.50  (1)

( A 2/ AV )≥1.50  (2)

where Bl is the luminance giving V, A 1 is the total number of pixels in a luminance range from 0 to (Bl−30), AV is the total number of pixels in a luminance range from (Bl−29) to (B1+29), and A 2 is the total number of pixels in a luminance range from (Bl+30) to 255.

2. The toner according to claim 1 , wherein

the organosilicon polymer forms a network structure on the toner particle surface;

when the total pixels in the backscattered electron image are divided into a pixel group A for the luminance range from 0 to (Bl−30) and a pixel group B for the luminance range from (Bl−29) to 255, a network structure due to the pixel group B is observed, with the pixel group A being net openings; and

for the domains formed by the pixel group A:

(i) a number-average value for an area is from 2.00×10 3 nm 2 to 1.00×10 4 nm 2 , and

(ii) a number-average value for a particle Feret diameter is from 60 nm to 200 nm.

3. The toner according to claim 1 , wherein the organosilicon polymer is a polymer having a structure represented by formula (RaT3) below:

in the formula, Ra represents a hydrocarbon group having from 1 to 6 carbons or represents a vinyl polymer segment that contains a substructure represented by formula (i) or formula (ii), where * in formulas (i) and (ii) represents a binding segment with an element Si in the structure represented by formula (RaT3), and L in formula (ii) represents an alkylene group or an arylene group.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 1, 2018
From: YOSHIDA, SARA; MOCHIZUKI, SHINSUKE; TOMINAGA, TSUNEYOSHI; KAMIKURA, KENTA; SHIMANO, TSUTOMU; YAMAWAKI, KENTARO; MASUMOTO, AKANE; MATSUNAGA, TOMONORI; NAKAMURA, KUNIHIKO; KATAKURA, TOSHIHIKO; KUROKI, SHIRO
To: CANON KABUSHIKI KAISHA
Reel/Frame 046682/0539 →
Priority Claims (3)
JP 2017-096504 · May 15, 2017 · national
JP 2017-096534 · May 15, 2017 · national
JP 2017-096544 · May 15, 2017 · national
Continuity (1)
Related Publication 20180329320A1 · Nov 15, 2018
Cited By (21)
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