Polyethylene terephthalate depolymerization
The present invention relates to the depolymerization of polymers and the recovery of the starting materials used for the production of the polymer. The present invention also relates to the depolymerization of polyethylene terephthalate (PET) and the recovery of terephthalic acid and ethylene glycol.
1. A process for depolymerizing a polymer comprising an ester functionality, comprising admixing the polymer with a mixture comprising:
(i) a halogenated solvent selected from the group consisting of dichloromethane, dichloroethane, tetrachloroethane, chloroform, tetrachloromethane, and trichloroethane; and
(ii) a mixture of an alcohol and a hydroxide;
wherein the admixing is continued for a sufficient time to depolymerize at least a portion of the polymer; and
wherein the process is performed without applying external heat.
2. The process of claim 1 , wherein the mixture of the alcohol and the hydroxide is added to the polymer simultaneously with the halogenated solvent.
3. The process of claim 1 , wherein the ratio of the halogenated solvent to alcohol is about 1:10 to about 1:50 (v:v).
4. The process of claim 1 , wherein the polymer is admixed with the halogenated solvent, the hydroxide, and the alcohol for about 0 h to about 5 h.
5. The process of claim 4 , wherein the polymer is admixed with the halogenated solvent, the hydroxide, and the alcohol at atmospheric pressure.
6. The process of claim 1 , wherein the alcohol is a linear C 1 -C 4 alcohol.
7. The process of claim 1 , wherein the hydroxide is selected from the group consisting of an alkali metal hydroxide, an alkaline earth metal hydroxide, an ammonium hydroxide, and a combination thereof.
8. The process of claim 1 , wherein the polymer is in the form of waste material.
9. The process of claim 8 , wherein the waste material further comprises debris that do not include a polymer comprising an ester functionality.
10. The process of claim 9 , wherein the debris comprises at least one of bottle caps, glue, paper, residual liquid, and dirt.
11. The process of claim 1 , wherein the polymer comprising an ester functionality is depolymerized to form terephthalic acid or a salt thereof and ethylene glycol.
12. The process of claim 11 , wherein the terephthalic acid or salt thereof contains less than about 3% of an impurity (w/w).
13. The process of claim 12 , wherein the impurity comprises at least one of isophthalic acid, phthalic acid, 4-methylbenzoic acid, 4-formylbenzoic acid, and metals.
14. A process for depolymerizing of polymer comprising an ester functionality, comprising admixing the polymer with a mixture comprising:
(i) about 3 to about 5% (vol.) of a halogenated solvent selected from the group consisting of dichloromethane, dichloroethane, tetrachloroethane, chloroform, tetrachloromethane, and trichloroethane;
(ii) about 95 to about 97% (vol.) of a linear C 1 -C 4 alcohol; and
(iii) a hydroxide;
wherein the admixing is continued for about 1 h; and
wherein the process is performed without applying external heat.
15. The process of claim 14 , wherein the polymer comprising an ester functionality is depolymerized to form terephthalic acid or a salt thereof and ethylene glycol.
16. The process of claim 15 , wherein the terephthalic acid or salt thereof contains less than about 3% of an impurity (w/w).
17. The process of claim 16 , wherein the impurity comprises at least one of isophthalic acid, phthalic acid, 4-methylbenzoic acid, 4-formylbenzoic acid, and metals.
18. A process for depolymerizing polyethylene terephthalate comprising admixing polyethylene terephthalate with a mixture comprising:
(i) about 3 to about 5% (vol.) of a halogenated solvent selected from the group consisting of dichloromethane, dichloroethane, tetrachloroethane, chloroform, tetrachloromethane, and trichloroethane;
(ii) about 95 to about 97% (vol.) of a linear C 1 -C 4 alcohol; and
(iii) a hydroxide;
wherein the admixing is continued for about 1 h; and
wherein the process is performed at without applying external heat.