Processes for preparing a diazabicyclooctane compound
A process for preparing a diazabicyclooctane compound represented by the following formula (I): wherein A represents RcO—; B represents NH or NC 1-6 alkyl; C represents a benzyl group; Rc represents a C 1-6 alkyl group; A is substituted with one substituent Fn1, wherein Fn1 represents an azetidine group; the process including: (a) silylating the compound represented by the following formula (IV-c): wherein in the formula (IV-c), OBn represents benzyloxy, and (b) carrying out an intramolecular urea formation reaction.
1. A compound of a formula selected from the group consisting of
wherein in the above formulae, TFA represents a trifluoroacetyl group, OMe represents a methoxy group, Boc represents a tert-butoxycarbonyl group, Teoc represents a 2-trimethylsilylethoxycarbonyl group, OBn represents a benzyloxy group, and Cbz represents a benzyloxycarbonyl group.
2. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group and TFA represents a trifluoroacetyl group.
3. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group and Boc represents a tert-butoxycarbonyl group.
4. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group and Teoc represents a 2-trimethylsilylethoxycarbonyl group.
5. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group, Boc represents a tert-butoxycarbonyl group and Teoc represents a 2-trimethylsilylethoxycarbonyl group.
6. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group, Boc represents a tert-butoxycarbonyl group and Cbz represents a benzyloxycarbonyl group.
7. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group, Boc represents a tert-butoxycarbonyl group and Teoc represents a 2-trimethylsilylethoxycarbonyl group.
8. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group and Boc represents a tert-butoxycarbonyl group.
9. The compound of claim 1 , which has the formula
wherein OBn represents a benzyloxy group and Cbz represents a benzyloxycarbonyl group.