Pre-treatment approach to improve continuity of ultra-thin amorphous silicon film on silicon oxide
In one implementation, a method of forming an amorphous silicon layer on a substrate in a processing chamber is provided. The method comprises depositing a predetermined thickness of a sacrificial dielectric layer over a substrate. The method further comprises forming patterned features on the substrate by removing portions of the sacrificial dielectric layer to expose an upper surface of the substrate. The method further comprises performing a plasma treatment to the patterned features. The method further comprises depositing an amorphous silicon layer on the patterned features and the exposed upper surface of the substrate. The method further comprises selectively removing the amorphous silicon layer from an upper surface of the patterned features and the upper surface of the substrate using an anisotropic etching process to provide the patterned features filled within sidewall spacers formed from the amorphous silicon layer.
1. A method of forming an amorphous silicon layer, comprising:
depositing a predetermined thickness of a sacrificial oxide-containing dielectric layer over a substrate positioned in a processing volume;
forming patterned features on the substrate by removing portions of the sacrificial oxide-containing dielectric layer to expose an upper surface of the substrate;
performing a plasma treatment to the patterned features, comprising:
flowing a treatment gas into the processing volume, wherein the treatment gas comprises ammonia, nitrous oxide, or a combination thereof; and
generating a plasma in the processing volume to treat the patterned features of the substrate;
depositing an amorphous silicon layer on the patterned features and the exposed upper surface of the substrate, wherein the amorphous silicon layer has a thickness in a range from about 10 angstroms to about 100 angstroms; and
selectively removing the amorphous silicon layer from an upper surface of the patterned features and the upper surface of the substrate using an anisotropic etching process to provide the patterned features filled within sidewall spacers formed from the amorphous silicon layer.
2. The method of claim 1 , wherein the treatment gas further comprises argon.
3. The method of claim 1 , wherein the treatment gas further comprises hydrogen.
4. The method of claim 1 , wherein performing the plasma treatment to the patterned features is performed in a processing chamber and depositing the amorphous silicon layer on the patterned features and the exposed upper surface of the substrate is performed in the same processing chamber.
5. The method of claim 1 , wherein the sacrificial oxide-containing dielectric layer comprises silicon oxide.
6. The method of claim 1 , wherein depositing the amorphous silicon layer on the patterned features and the exposed upper surface of the substrate comprises exposing the patterned features to a silicon precursor to form the amorphous silicon layer having an outgassable species comprising hydrogen.
7. The method of claim 6 , further comprising exposing the amorphous silicon layer to an inert degas environment to remove the outgassable species from the amorphous silicon layer to form a degassed amorphous silicon layer.
8. The method of claim 7 , wherein the inert degas environment consists essentially of an inert gas.
9. The method of claim 7 , wherein the silicon precursor comprises one or more of disilane, trisilane, tetrasilane, isotetrasilane, neopentasilane, cyclopentasilane, hexasilane, cyclohexasilane, and combinations thereof.
10. The method of claim 9 , wherein the silicon precursor is disilane.
11. The method of claim 1 , wherein the plasma is a capacitively coupled plasma (CCP), an inductively coupled plasma (ICP), or a combination of CCP and ICP.
12. A method of forming an amorphous silicon layer on a substrate in a processing chamber, comprising:
depositing a predetermined thickness of a sacrificial dielectric layer over a substrate positioned in a processing volume;
forming patterned features on the substrate by removing portions of the sacrificial dielectric layer to expose an upper surface of the substrate;
forming a self-assembled monolayer (“SAM”) on the patterned features, wherein the SAM is formed from SAM precursors selected from the group comprising bis(diethylamino)silane (“BDEAS”), hexachlorodisilane (HCDS), (3-Aminopropyl)triethoxysilane (“APTES”), and octadecyltrichlorosilane (“ODTS”);
depositing an amorphous silicon layer on the SAM and the exposed upper surface of the substrate; and
selectively removing the amorphous silicon layer from an upper surface of the patterned features and the upper surface of the substrate using an anisotropic etching process to provide the patterned features filled within sidewall spacers formed from the amorphous silicon layer.
13. The method of claim 12 , wherein depositing the amorphous silicon layer on the SAM and the patterned features and the exposed upper surface of the substrate comprises exposing the patterned features to a silicon precursor to form the amorphous silicon layer having an outgassable species comprising hydrogen.
14. The method of claim 13 , further comprising exposing the amorphous silicon layer to an inert degas environment to remove the outgassable species from the amorphous silicon layer to form a degassed amorphous silicon layer.
15. The method of claim 12 , wherein the amorphous silicon layer has a thickness in a range from about 10 angstroms to about 100 angstroms.
16. A method of forming an amorphous silicon layer on a substrate in a processing chamber, comprising:
depositing a predetermined thickness of a sacrificial dielectric layer over a substrate positioned in a processing volume;
forming patterned features on the substrate by removing portions of the sacrificial dielectric layer to expose an upper surface of the substrate;
performing a plasma treatment to the patterned features;
forming a self-assembled monolayer (“SAM”) on the plasma treated patterned features, wherein the SAM is formed from SAM precursors that are selected from the group comprising bis(diethylamino)silane (“BDEAS”), hexachlorodisilane (HCDS), (3-Aminopropyl)triethoxysilane (“APTES”), and octadecyltrichlorosilane (“ODTS”);
depositing an amorphous silicon layer on the SAM and the exposed upper surface of the substrate; and
selectively removing the amorphous silicon layer from an upper surface of the patterned features and the upper surface of the substrate using an anisotropic etching process to provide the patterned features filled within sidewall spacers formed from the amorphous silicon layer.
17. The method of claim 16 , wherein depositing the amorphous silicon layer on the SAM and the patterned features and the exposed upper surface of the substrate comprises exposing the patterned features to a silicon precursor to form the amorphous silicon layer having an outgassable species comprising hydrogen.
18. The method of claim 17 , further comprising exposing the amorphous silicon layer to an inert degas environment to remove the outgassable species from the amorphous silicon layer to form a degassed amorphous silicon layer.
19. The method of claim 18 , wherein the silicon precursor comprises one or more of disilane, trisilane, tetrasilane, isotetrasilane, neopentasilane, cyclopentasilane, hexasilane, cyclohexasilane, and combinations thereof.
20. The method of claim 16 , wherein the amorphous silicon layer has a thickness in a range from about 10 angstroms to about 100 angstroms.