IP Library Granted Patent US 10,597,301
Granted Patent B2
US 10,597,301 · App. 16/080,673 · Granted Mar 24, 2020

Ammonia production method

Inventors: Tsutomu Kawasaki (Kanagawa, JP); Yoshiyuki Watanabe (Kanagawa, JP)
Assignee: JGC CORPORATION
C01C1/0494B01D53/047B01D53/229C01C1/12C25B1/00H01M8/222B01D2253/102B01D2253/108B01D2257/406F02C3/04F05D2210/12
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Quick Facts
Patent No.
US 10,597,301
App. No.
16/080,673
Granted
Mar 24, 2020
Kind
B2
Abstract

A high-concentration ammonia production method includes: synthesizing ammonia through electrolysis using water and nitrogen as raw materials; subjecting a resultant generation gas to treatment using an ammonia separation membrane or an ammonia PSA to separate the generation gas into high-concentration ammonia and a residual gas; recycling the residual gas as a nitrogen gas raw material of an ammonia synthesis reactor, and liquefying the high-concentration ammonia recovered through the ammonia separation membrane or the ammonia PSA; and subjecting an unliquefied gas separated from liquefied ammonia to the treatment using the ammonia separation membrane or the ammonia PSA again. According to the present disclosure, ammonia is synthesized by adopting an electrolysis method in which the synthesized ammonia substantially does not contain hydrogen, in combination with ammonia separation and recovery treatment using membrane separation or PSA. With this, high-concentration ammonia can be synthesized and recovered with high efficiency through an entire process.

Claims (15)

1. A high-concentration ammonia production method, comprising:

subjecting a resultant generation gas to treatment using an ammonia separation membrane or an ammonia PSA to separate the generation gas into high-concentration ammonia and a residual gas;

recycling the residual gas as a nitrogen gas raw material of an ammonia synthesis reactor, and liquefying the high-concentration ammonia recovered through the ammonia separation membrane or the ammonia PSA; and

subjecting an unliquefied gas separated from liquefied ammonia to the treatment using the ammonia separation membrane or the ammonia PSA again.

2. The high-concentration ammonia production method according to claim 1 , further comprising:

discharging, as a purge gas, part of the residual gas to be recycled to an outside of a system to suppress condensation of argon; and

mixing at least part of the purge gas to be discharged in the high-concentration ammonia recovered through the ammonia separation membrane or the ammonia PSA.

3. A power generation method, comprising:

combusting high-concentration ammonia obtained by the method of claim 1 ; and

driving a gas turbine by using a resultant gas as a working medium to generate power.

4. A high-concentration ammonia use method, comprising introducing high-concentration ammonia obtained by the method of claim 1 as a fuel for an ammonia fuel cell.

5. A power generation method, comprising:

combusting high-concentration ammonia obtained by the method of claim 2 ; and

driving a gas turbine by using a resultant gas as a working medium to generate power.

6. A high-concentration ammonia use method, comprising introducing high-concentration ammonia obtained by the method of claim 2 as a fuel for an ammonia fuel cell.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 24, 2019
From: JGC HOLDINGS CORPORATION
To: JGC CORPORATION
Reel/Frame 051361/0222 →
CHANGE OF NAME Recorded Dec 16, 2019
From: JGC CORPORATION
To: JGC HOLDINGS CORPORATION
Reel/Frame 051300/0451 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 7, 2018
From: KAWASAKI, TSUTOMU; WATANABE, YOSHIYUKI
To: JGC CORPORATION
Reel/Frame 046809/0224 →
Continuity (1)
Related Publication 20190092645A1 · Mar 28, 2019
Cited By (2)
US 12,686,935 US 12,735,325