IP Library Granted Patent US 12,686,935
Granted Patent B2
US 12,686,935 · App. 18/110,213 · Granted Jul 21, 2026

Systems and methods of ammonia synthesis

Inventors: Arne Ballantine (Incline Village, NV); Chockkalingam Karuppaiah (Fremont, CA)
Assignee: Ohmium International, Inc.
C25B15/083B01D53/326B01J8/0278C01C1/0405C01C1/0494C25B1/04C25B1/27C25B9/19C25B9/73
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Quick Facts
Patent No.
US 12,686,935
App. No.
18/110,213
Filed
Feb 15, 2023
Granted
Jul 21, 2026
Kind
B2
Art Unit
3746
USPC
422/148
Abstract

A system for synthesizing ammonia includes a reactor including an inlet portion, an outlet portion, and an energy source arranged to deliver energy to one or more reactants receivable through the inlet portion of the reactor, and the energy source activatable to reduce nitrogen to ammonia in the presence of hydrogen, at least one hydrogen pump in fluid communication with the outlet portion of the reactor, each hydrogen pump including at least one electrochemical cell, and a recirculation circuit in fluid communication between the at least one hydrogen pump and the inlet portion of the reactor and configured to direct a respective hydrogen stream from each hydrogen pump to the inlet portion of the reactor.

Claims (19)

1 . A system for synthesizing ammonia, comprising:

a reactor including

an inlet portion, and

an outlet portion, and an energy source arranged to deliver energy to one or more reactants receivable through the inlet portion of the reactor, and the energy source activatable to reduce nitrogen to ammonia in the presence of hydrogen, wherein the energy source includes a catalyst or a plasma source;

a nitrogen source that provides nitrogen to the reactor through fluid communication with the inlet portion of the reactor;

at least one hydrogen pump in fluid communication with the outlet portion of the reactor, each hydrogen pump comprising at least one electrochemical cell; and

a recirculation circuit in fluid communication between the at least one hydrogen pump and the inlet portion of the reactor configured to direct a respective hydrogen stream from each hydrogen pump to the inlet portion of the reactor.

2 . The system of claim 1 , wherein the at least one hydrogen pump comprises a plurality of electrochemical cells arranged in a cascading electrochemical stack.

3 . The system of claim 1 , wherein the nitrogen source comprises one or more of a pressure swing adsorber, a temperature swing adsorber, or a refrigeration unit.

4 . The system of claim 1 , wherein the nitrogen source is configured to separate nitrogen from air provided to the nitrogen source.

5 . The system of claim 1 , wherein the nitrogen source comprises an oxygen pump activatable to separate oxygen from nitrogen.

6 . The system of claim 1 , further comprising a hydrogen source in fluid communication with the inlet portion of the reactor.

7 . The system of claim 6 , wherein the hydrogen source comprises a proton exchange membrane (PEM) electrolyzer, and the at least one hydrogen pump uses less power than the PEM electrolyzer to deliver hydrogen to the inlet portion of the reactor.

8 . The system of claim 6 , wherein the hydrogen source comprises one or more of a hydrogen storage vessel, a reformer, a borax plant, or a catalytic hydrogen production plant.

9 . The system of claim 1 , wherein the reactants comprise nitrogen and hydrogen.

10 . The system of claim 1 , wherein the catalyst comprises a metal catalyst.

11 . The system of claim 10 , wherein the metal catalyst comprises a Fe catalyst.

12 . The system of claim 1 , further comprising a controller in electrical communication with one or more of the reactor, the at least one hydrogen pump, or the nitrogen source.

13 . The system of claim 1 , further comprising an adsorber in fluid communication with the at least one hydrogen pump.

Assignments (3)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 21, 2025
From: KARUPPAIAH, CHOCKKALINGAM; BALLANTINE, ARNE
To: OHMIUM, INC.
Reel/Frame 071177/0254 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 10, 2025
From: SCHUIJERS, ERIK GOSUINUS PETRUS; GALUCCI, ALESSIO
To: KONINKLIJKE PHILIPS N.V.
Reel/Frame 070456/0086 →
MERGER AND CHANGE OF NAME Recorded Mar 27, 2023
From: OHMIUM, INC.; OHMIUM INTERNATIONAL, INC.
To: OHMIUM INTERNATIONAL, INC.
Reel/Frame 063110/0533 →
Continuity (3)
Division 17101224 · Nov 23, 2020
Provisional Application 62938450 · Nov 21, 2019
Related Publication 20230203686A1 · Jun 29, 2023
References Cited (95)
US 4153673A · Becker · 1979 [cited by applicant]
US 4180553A · Null et al. · 1979 [cited by applicant]
US 6994929B2 · Barbir et al. · 2006 [cited by applicant]
US 7300642B1 · Pedersen · 2007 [cited by examiner]
US 8015808B2 · Keefer et al. · 2011 [cited by applicant]
US 8669499B2 · Conrad · 2014 [cited by applicant]
US 9634343B2 · Munier et al. · 2017 [cited by applicant]
US 10597301B2 · Kawasaki · 2020 [cited by examiner]
US 10683644B2 · Kim et al. · 2020 [cited by applicant]
US 10815442B2 · Yoon · 2020 [cited by applicant]
US 11603599B2 · Ballantine · 2023 [cited by examiner]
US 20040142215A1 · Barbir et al. · 2004 [cited by applicant]
US 20050034479A1 · Ji · 2005 [cited by examiner]
US 20100282689A1 · Ganzi et al. · 2010 [cited by applicant]
US 20120100062A1 · Nakamura et al. · 2012 [cited by applicant]
US 20120202279A1 · Murahara · 2012 [cited by applicant]
US 20130288143A1 · Lee · 2013 [cited by applicant]
US 20160193564A1 · Badwal · 2016 [cited by examiner]
US 20160288114A1 · Way · 2016 [cited by examiner]
US 20160369411A1 · Handagama et al. · 2016 [cited by applicant]
US 20170152149A1 · Malmali et al. · 2017 [cited by applicant]
US 20170233878A1 · Yakumaru et al. · 2017 [cited by applicant]
US 20170321329A1 · Spurgeon · 2017 [cited by applicant]
US 20180305828A1 · Takanami et al. · 2018 [cited by applicant]
US 20190092645A1 · Kawasaki et al. · 2019 [cited by applicant]
US 20190382903A1 · Johanning et al. · 2019 [cited by applicant]
US 20210155491A1 · Ballantine et al. · 2021 [cited by applicant]
US 20210340683A1 · Zhang et al. · 2021 [cited by applicant]
US 20210395902A1 · Tamura et al. · 2021 [cited by applicant]
US 20220032228A1 · Yen · 2022 [cited by applicant]
US 20220033984A1 · Light · 2022 [cited by applicant]
US 20220388855A1 · Dincer et al. · 2022 [cited by applicant]
US 20230010889A1 · Kajino et al. · 2023 [cited by applicant]
US 20230175144A1 · Ballantine · 2023 [cited by applicant]
US 20230191319A1 · Shrivastava et al. · 2023 [cited by applicant]
US 20230203682A1 · Yan et al. · 2023 [cited by applicant]
US 20230357941A1 · Ballantine et al. · 2023 [cited by applicant]
US 20240271291A1 · Ballantine et al. · 2024 [cited by applicant]
US 20250129487A1 · Kondo et al. · 2025 [cited by applicant]
US 20260054217A1 · Karuppaiah et al. · 2026 [cited by applicant]
CN 103237599A · 2013 [cited by applicant]
DE 102014217462A1 · 2016 [cited by applicant]
EP 4061771 · 2022 [cited by applicant]
EP 4519204 · 2025 [cited by applicant]
JP 2013209684 · 2013 [cited by applicant]
JP 2014162662 · 2014 [cited by applicant]
JP 2016209810 · 2016 [cited by applicant]
JP 2025515190 · 2025 [cited by applicant]
KR 1020200003736 · 2020 [cited by applicant]
TW 202128562A · 2021 [cited by applicant]
WO WO2007124390 · 2007 [cited by applicant]
WO 2008070714A1 · 2008 [cited by applicant]
WO 2009056888A1 · 2009 [cited by applicant]
WO 2011023865A1 · 2011 [cited by applicant]
WO 2013113631A1 · 2013 [cited by applicant]
WO 2018236649A1 · 2018 [cited by applicant]
WO WO2020000020 · 2020 [cited by applicant]
WO WO2021102400 · 2021 [cited by applicant]
WO 2022035792A1 · 2022 [cited by applicant]
WO WO2022026523 · 2022 [cited by applicant]
WO 2022207227A1 · 2022 [cited by applicant]
WO 2022253456A1 · 2022 [cited by applicant]
WO 2023001426A1 · 2023 [cited by applicant]
WO 2023215639A1 · 2023 [cited by applicant]
WO WO2024168349 · 2024 [cited by applicant]
WO 2026043717A1 · 2026 [cited by applicant]
PCT Application No. PCT/US2024/015419, International Preliminary Report on Patentability dated Aug. 21, 2025. [cited by applicant]
PCT Application No. PCT/US23/21382, International Search Report and Written Opinion mailed Sep. 13, 2023. [cited by applicant]
PCT Application No. PCT/US24/15419, International Search Report and Written Opinion mailed May 6, 2024. [cited by applicant]
PCT Application No. PCT/US23/21382, International Preliminary Report on Patentability dated Nov. 21, 2024. [cited by applicant]
U.S. Appl. No. 17/387,170, Final Office Action dated Oct. 31, 2024. [cited by applicant]
Notice of Decision in UAE Application No. P6000939/2022 dated Oct. 5, 2024. [cited by applicant]
Examination Report in IN Application No. 202217033806 dated Nov. 4, 2024. [cited by applicant]
Office Action in TW Application No. 109141026 dated Jul. 10, 2024. [cited by applicant]
Chisholm, G. et al., “3D printed flow plates for the electrolysis of water: an economic and adaptable approach to device manufacture,” Energy Environmental Science, vol. 7, pp. 3026-3032, Jul. 2014. [cited by applicant]
PCT Application No. PCT/US2020/061765, International Preliminary Report on Patentability dated May 17, 2022. [cited by applicant]
PCT Application No. PCT/US2020/061765, International Search Report and Written Opinion mailed Mar. 18, 2021. [cited by applicant]
PCT Application No. PCT/US2021/043410, International Preliminary Report on Patentability dated Jan. 31, 2023. [cited by applicant]
PCT Application No. PCT/US2021/043410, International Search Report and Written Opinion mailed Nov. 9, 2021. [cited by applicant]
Ginsberg et al., “Integrating Solar Energy, Desalination and Electrolysis,” accessed at https://www.osti.gov/servlets/purl/1976411, Nov. 3, 2021. [cited by applicant]
EP Application No. 208901330.0, Extended European Search Report dated Nov. 4, 2024. [cited by applicant]
U.S. Appl. No. 17/387,170, Office Action dated Jun. 7, 2024. [cited by applicant]
Liu et al., “Water and Metal-Organic Frameworks: From Interaction toward Utilization,” Chem. Rev. 2020, 120, 8303-8377. [cited by applicant]
Opekar et al., “Contactless Impedance Sensors and Their Application to Flow Measurements,” Sensors 2013, 13, 2786-2801. [cited by applicant]
U.S. Appl. No. 19/300,184, Chockkalingam Karuppaiah, Electrochemical Compression for Hydrogen Recovery and High Plant Yield in Ammonia Synthesis Processes, filed Aug. 14, 2025. [cited by applicant]
PCT/US25/42051, WO, Chockkalingam Karuppaiah, Electrochemical Compression for Hydrogen Recovery and High Plant Yield in Ammonia Synthesis Processes, Aug. 14, 2025. [cited by applicant]
PCT Application No. PCT/US2025/042051, International Search Report and Written Opinion dated Dec. 15, 2025. [cited by applicant]
Gao, J. et al., “Direct electrosynthesis and separation of ammonia and chlorine from waste streams via a stacked membrane-free electrolyzer,” Nature Communications, vol. 15, Sep. 30, 2024. DOI: https://doi.org/10.1038/s… [cited by applicant]
Hou, D. et al., “Nickel-Based Membrane Electrodes Enable High-Rate 2 Electrochemical Ammonia Recovery,” Environmental Science & Technology, vol. 52, No. 15, Jun. 25, 2018. DOI: https://doi.org/10.1021/acs.est.8b01349. [cited by applicant]
Komkova, M. A. et al., “Facilitated transport of ammonia in ultra-thin Prussian Blue membranes with potential-tuned selectivity,” Journal of Membrane Science, vol. 639, Dec. 1, 2021. DOI: https://doi.org/10.1016/j.memsc… [cited by applicant]
Nordio, M. et al., “Experimental and modelling study of an electrochemical hydrogen compressor,” Chemical Engineering Journal, vol. 369, Mar. 12, 2019, pp. 432-442. DOI: https://doi.org/10.1016/j.cej.2019.03.106. [cited by applicant]
U.S. Appl. No. 18/144,727, Non-Final Office Action dated Jan. 30, 2026. [cited by applicant]
EP Application No. 23800127.5, Extended European Search Report dated Apr. 22, 2026. [cited by applicant]
Rouwenhorst, K. et al., “Islanded ammonia power systems: Technology review & conceptual process design,” Renewable and Sustainable Energy Reviews, vol. 114, Aug. 23, 2019, 15 pages. [cited by applicant]
Kugler, K. et al., “Co-generation of Ammonia and H2 from H2O Vapor and N2 Using a Membrane Electrode Assembly,” Chemie Ingenieur Technik, vol. 92, No. 1-2, Dec. 10, 2019, pp. 62-69. [cited by applicant]