IP Library › Granted Patent US 10,620,065
Granted Patent B2
US 10,620,065 · App. 15/807,950 · Granted Apr 14, 2020

Cement having stress-indicating properties

Inventors: Yarom Polsky (Oak Ridge, TN); Michael J. Lance (Oak Ridge, TN); Catherine H. Mattus (Oak Ridge, TN); James G. Hemrick (Oak Ridge, TN)
Assignee: UT-Battelle, LLC
G01L1/24C04B28/04C09K8/467E21B47/0005G01L1/241G01L1/26C04B7/02C04B7/32C04B2111/80C09K11/685C09K2103/00E21B49/006G01J3/0218
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Quick Facts
Patent No.
US 10,620,065
App. No.
15/807,950
Granted
Apr 14, 2020
Kind
B2
Abstract

A system and method measures subterranean stress. The system and method includes a cement mixture that is mixed with water to set as a solid and a stress measuring-medium having piezospectroscopic properties that directly reveals stress in situ within the cement mixture in response to a photo stimulation. The stress measuring-medium combines with the cement mixture as a dry blend before being combined with water.

Claims (34)

1. A stress sensor system that measures subterranean stress in situ comprising:

a cement mixture that is mixed with water to set as a solid material; and

a stress measuring-medium having piezospectroscopic properties that directly reveals stress in situ within the cement mixture in response to a photo stimulation by measuring an absorption of an incident light non-radiatively de-excited to about 14400 cm −1 ;

where the stress measuring-medium is combined with the cement mixture and water.

2. The system of claim 1 further comprising an expansive mineral additive combined with the stress measuring-medium.

3. The system of claim 2 further comprising a water-reducing admixture combined with the stress measuring-medium.

4. The system of claim 1 where the stress measuring-medium comprises an alpha-alumina material.

5. The system of claim 1 where the stress measuring-medium comprises an alpha-alumina material and a chromia material.

6. The system of claim 1 where the cement mixture comprises a Portland cement that forms a hydraulic seal with an alpha-alumina material.

7. The system of claim 1 where the cement mixture comprises a calcium sulfoaluminate cement added to a class H cement that forms a hydraulic seal with a alpha-alumina material.

8. A stress sensor that measures subterranean stress in situ comprising:

a cement mixture that is mixed with water to set as a solid material; and

a stress measuring-medium having piezospectroscopic properties that directly reveals stress in situ within the cement mixture in response to a photo stimulation;

where the stress measuring-medium is combined with the cement mixture and water; and

where the stress sensor renders a spectral resolution of 0.01 cm −1 at about 1443 cm −1 .

9. A method for measuring subterranean stress in situ comprising:

mixing a water reducing admixture with water to render a mixture;

dry blending a cement mixture, an expansive mineral additive, and a stress measuring-medium in a dry blend; and

mixing progressively the dry blend to obtain a homogeneous cement slurry; and

where the stress measuring medium comprises about a fifty-five percent dry blend by weight of a total weight of the cement mixture;

where the stress measuring medium renders a spectral resolution of about 0.01 cm −1 at about 1443 cm −1 .

10. The method of claim 9 where the stress measuring-medium comprises an alpha-alumina material.

11. The method of claim 9 where the stress measuring-medium comprises an alpha-alumina material and a chromia material.

12. The method of claim 9 where the cement mixture comprises a Portland cement that forms a hydraulic seal with an alpha-alumina material.

13. The method of claim 9 where the cement mixture comprises a calcium sulfoaluminate cement added to a class H cement that forms a hydraulic seal with an alpha-alumina material.

14. The method of claim 9 where the stress measuring medium comprises a processed alumina heated up and until 950° C.

15. A stress sensor system that measures subterranean stress in situ comprising:

a cement mixture that is mixed with water to set as a solid material; and

an alpha-alumina compound having piezospectroscopic properties that directly reveals stress in situ within the cement mixture in response to a photo stimulation;

where the alpha-alumina compound is combined with the cement mixture; and

where the stress sensor renders a spectral resolution between 0.0095 cm −1 and 0.01 cm −1 at between 14400 cm −1 and 1443 cm −1 .

16. The system of claim 15 further comprising an expansive mineral additive combined with the alpha-alumina compound.

17. The system of claim 16 further comprising a water-reducing admixture combined with the alpha-alumina compound.

18. The system of claim 15 where the alpha-alumina compound comprises an alpha-alumina material and a chromia material.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jan 9, 2018
From: POLSKY, YAROM; LANCE, MICHAEL J.; MATTUS, CATHERINE H.; HEMRICK, JAMES G.
To: UT-BATTELLE, LLC
Reel/Frame 044571/0902 →
Continuity (3)
Continuation In Part 15675473 · Aug 11, 2017
Provisional Application 62428569 · Dec 1, 2016
Related Publication 20180156677A1 · Jun 7, 2018
Cited By (1)
US 12,595,729