Biochar
The invention provides for methods, devices, and systems for pyrolyzing biomass. A pyrolysis unit can be used for the pyrolysis of biomass to form gas, liquid, and solid products. The biomass materials can be selected such that an enhanced biochar is formed after pyrolysis. The biomass can be pyrolyzed under specified conditions such that a selected biochar core is formed. The pyrolysis process can form a stable biochar core that is inert and/or resistant to degradation. The biochar or biochar core can be functionalized to form a functionalized biochar or functionalized biochar core. Functionalization can include post-pyrolysis treatments such as supplementation with microbes or physical transformations including annealing and/or activation.
1. A article of manufacture comprising:
a. a biochar core that is stable and has a degradation rate of less than 2.5% a year;
b. wherein said biochar core is produced from a biomass that is pyrolized at:
(i) a heating rate between about 0.1 C./second and 50.degree.C./second,
(ii) a temperature greater than 250.degree. C., and
(iii) a heating time greater than about 0.01 days.
2. The article of manufacture of claim 1 , wherein the rate of degradation of said biochar core is less than 0.5% per year.
3. The article of manufacture of claim 1 , wherein the rate of degradation of said biochar core is determined by measuring the loss of carbon.
4. The article of manufacture of claim 3 , wherein the carbon of said biochar core is organic carbon.
5. The article of manufacture of claim 1 , wherein the degradation of said biochar core is oxidative, chemical, biotic, or abiotic degradation.
6. The article of manufacture of claim 1 , wherein the rate of degradation of said biochar core is less than 2.5% per year over a ten year period.
7. The article of manufacture of claim 1 , wherein said biochar core has a surface area greater than about 300 m 2 per gram.
8. The article of manufacture of claim 1 , wherein a porosity of said biochar core is less than about nine-tenths of the total volume of said biochar core.
9. An article of manufacture comprising:
a. a biochar core that has a carbon content greater than about 75% of the dry weight of the biochar; and
b. wherein said biochar core is produced from a biomass that is pyrolized under:
i. a heating rate between about 0.1.degree Celsius a second and 50.degree. C./second:
ii. a temperature greater than 250.degree. Celsius; and
iii. a heating time greater than about 0.01 days; and combining the biochar core with a supplement to produce a functionalized biochar.
10. The article of manufacture of claim 9 , wherein said biochar core has a volatile compound concentration of less than about 15 wt %.
11. The article of manufacture of claim 9 , wherein the biomass has a biomass carbon content and the biochar core carbon content is greater than the biomass carbon content.
12. The article of manufacture of claim 9 , wherein the biochar core has a specified nitrogen, phosphorus, or potassium content.
13. The article of manufacture of claim 9 , wherein the biochar core comprises pores having a pore size range between about 5 to 50 microns.
14. The article of manufacture of claim 9 , wherein the biochar core comprises pores having an average pore size of about 25 microns.
15. The article of manufacture of claim 9 , wherein the biochar core that has a biochar core volatiles content less than about 30 wt % of the biochar.
16. The article of manufacture of claim 9 , further comprising supplementing said biomass with a feedstock having an ash content greater than about 5%.
17. The article of manufacture of claim 9 , further comprising subjecting said biomass to cutting, crushing, grinding, screening or breaking prior to providing said biomass to said pyrolysis unit.
18. The article of manufacture of claim 9 , wherein said temperature is greater than about 500.degree. C.
19. The article of manufacture of claim 9 , wherein the biochar core has a surface area greater than about 300 m 2 per gram.
20. The article of manufacture of claim 9 , wherein a porosity of the biochar core is less than about nine-tenths of the total volume of the stable biochar core.