IP Library Granted Patent US 10,998,516
Granted Patent B2
US 10,998,516 · App. 15/495,113 · Granted May 4, 2021

Light-emitting element, display device, electronic device, and lighting device

Inventors: Takahiro Ishisone (Kanagawa, JP); Satoshi Seo (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H01L51/5004C09K11/025C09K11/06H01L27/3262H01L51/5016H01L51/5028C09K2211/1007C09K2211/1044C09K2211/185H01L27/322H01L27/3244H01L51/006H01L51/0052H01L51/0054H01L51/0061H01L51/0067H01L51/0072H01L51/0074H01L51/0085H01L2251/552
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Quick Facts
Patent No.
US 10,998,516
App. No.
15/495,113
Granted
May 4, 2021
Kind
B2
Abstract

A light-emitting element having high luminous efficiency is provided. The light-emitting element includes a first organic compound, a second organic compound, and a third organic compound. The first organic compound and the second organic compound, in combination, are capable of forming an exciplex. The first organic compound is a phosphorescent compound and the third organic compound is a fluorescent compound. Light emitted from the light-emitting element includes light emitted from the third organic compound to which excitation energy is supplied from the exciplex formed by the first organic compound and the second organic compound.

Claims (86)

1. A light-emitting element comprising:

a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a third organic compound,

wherein a LUMO level of one of the first organic compound and the second organic compound is higher than or equal to a LUMO level of the other of the first organic compound and the second organic compound,

wherein a HOMO level of the one of the first organic compound and the second organic compound is higher than or equal to a HOMO level of the other of the first organic compound and the second organic compound,

wherein the first organic compound and the second organic compound, in combination, are capable of forming an exciplex,

wherein the first organic compound is capable of converting triplet excitation energy into light emission at room temperature,

wherein the third organic compound is capable of converting singlet excitation energy into light emission, and

wherein light emitted from the light-emitting layer comprises light emitted from the third organic compound.

2. The light-emitting element according to claim 1 ,

wherein a lowest triplet excitation energy level of the first organic compound is higher than or equal to a lowest triplet excitation energy level of the second organic compound.

3. The light-emitting element according to claim 1 ,

wherein the exciplex is capable of supplying excitation energy to the third organic compound.

4. The light-emitting element according to claim 3 ,

wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side in an absorption spectrum of the third organic compound.

5. The light-emitting element according to claim 1 ,

wherein the first organic compound comprises iridium.

6. The light-emitting element according to claim 5 ,

wherein the first organic compound comprises a ligand coordinated to iridium, and

wherein the ligand comprises a nitrogen-containing five-membered heterocyclic keleton.

7. The light-emitting element according to claim 1 ,

wherein the second organic compound comprises a 7 c -electron deficient heteroaromatic skeleton.

8. The light-emitting element according to claim 1 ,

wherein the first organic compound has a luminescence quantum yield higher than or equal to 0% and lower than or equal to 40% at room temperature.

9. The light-emitting element according to claim 1 ,

wherein luminous efficiency of light emitted from the exciplex is higher than luminous efficiency of light emitted from the first organic compound.

10. A display device comprising:

the light-emitting element according to claim 1 ; and

at least one of a color filter and a transistor.

11. A light-emitting element comprising:

a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a third organic compound,

wherein a LUMO level of one of the first organic compound and the second organic compound is higher than or equal to a LUMO level of the other of the first organic compound and the second organic compound,

wherein a HOMO level of the one of the first organic compound and the second organic compound is higher than or equal to a HOMO level of the other of the first organic compound and the second organic compound,

wherein the first organic compound and the second organic compound, in combination, are capable of forming an exciplex,

wherein the first organic compound is capable of emitting no fluorescence and emitting phosphorescence,

wherein the third organic compound is capable of emitting fluorescence, and

wherein light emitted from the light-emitting layer comprises light emitted from the third organic compound.

12. The light-emitting element according to claim 11 ,

wherein a lowest triplet excitation energy level of the first organic compound is higher than or equal to a lowest triplet excitation energy level of the second organic compound.

13. The light-emitting element according to claim 11 ,

wherein the exciplex is capable of supplying excitation energy to the third organic compound.

14. The light-emitting element according to claim 13 ,

wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side in an absorption spectrum of the third organic compound.

15. The light-emitting element according to claim 11 ,

wherein the first organic compound comprises iridium.

16. The light-emitting element according to claim 15 ,

wherein the first organic compound comprises a ligand coordinated to iridium, and

wherein the ligand comprises a nitrogen-containing five-membered heterocyclic skeleton.

17. The light-emitting element according to claim 11 ,

wherein the second organic compound comprises a 7 c -electron deficient heteroaromatic skeleton.

18. The light-emitting element according to claim 11 ,

wherein the first organic compound has a luminescence quantum yield higher than or equal to 0% and lower than or equal to 40% at room temperature.

19. The light-emitting element according to claim 11 ,

wherein luminous efficiency of light emitted from the exciplex is higher than luminous efficiency of light emitted from the first organic compound.

20. A display device comprising:

the light-emitting element according to claim 11 ; and

at least one of a color filter and a transistor.

21. A light-emitting element comprising:

a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a third organic compound,

wherein a LUMO level of the first organic compound is higher than or equal to a LUMO level of the second organic compound,

wherein a HOMO level of the first organic compound is higher than or equal to a HOMO level of the second organic compound,

wherein the first organic compound and the second organic compound, in combination, are capable of forming an exciplex,

wherein the first organic compound comprises Ru, Rh, Pd, Os, Ir, or Pt, and

wherein light emitted from the light-emitting layer comprises light emitted from the third organic compound.

22. The light-emitting element according to claim 21 ,

wherein a lowest triplet excitation energy level of the first organic compound is higher than or equal to a lowest triplet excitation energy level of the second organic compound.

23. The light-emitting element according to claim 21 ,

wherein the exciplex is capable of supplying excitation energy to the third organic compound.

24. The light-emitting element according to claim 23 ,

wherein an emission spectrum of the exciplex comprises a region overlapping with an absorption band on a longest wavelength side in an absorption spectrum of the third organic compound.

25. The light-emitting element according to claim 21 ,

wherein the first organic compound comprises iridium.

26. The light-emitting element according to claim 25 ,

wherein the first organic compound comprises a ligand coordinated to iridium, and

wherein the ligand comprises a nitrogen-containing five-membered heterocyclic skeleton.

27. The light-emitting element according to claim 21 ,

wherein the second organic compound comprises a 7 c -electron deficient heteroaromatic skeleton.

28. The light-emitting element according to claim 21 ,

wherein the first organic compound has a luminescence quantum yield higher than or equal to 0% and lower than or equal to 40% at room temperature.

29. The light-emitting element according to claim 21 ,

wherein luminous efficiency of light emitted from the exciplex is higher than luminous efficiency of light emitted from the first organic compound.

30. A display device comprising:

the light-emitting element according to claim 21 ; and

at least one of a color filter and a transistor.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2017
From: ISHISONE, TAKAHIRO; SEO, SATOSHI
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 042142/0576 →
Priority Claims (1)
JP JP2016-093152 · May 6, 2016 · national
Continuity (1)
Related Publication 20170324054A1 · Nov 9, 2017
Cited By (2)
US 12,256,630 US 12,495,662