Granted Patent B2

US 12,495,662 · App. 17/980,869 · Granted Dec 9, 2025

Inventors: Satoshi Seo (Kanagawa, JP); Nobuharu Ohsawa (Kanagawa, JP); Takeyoshi Watabe (Kanagawa, JP)

Assignee: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.

H10K50/11H10K50/121H10K50/19H10K59/32H10K85/622H10K85/626H10K85/633H10K85/654H10K85/6572H10K85/6576H10K2101/10H10K2101/27H10K2101/40H10K2101/90

Abstract

Claims (62)

1 . A light-emitting element comprising:

a pair of electrodes; and

an EL layer between the pair of electrodes,

wherein the EL layer comprises a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a guest material,

wherein the first organic compound emits a thermally activated delayed fluorescence at room temperature,

wherein the guest material emits fluorescence,

wherein emission energy of the first organic compound is higher than phosphorescence emission energy of the guest material,

wherein a triplet excitation energy level of the second organic compound is higher than a triplet excitation energy level of the guest material, and

wherein a singlet excitation energy level of the second organic compound is higher than a singlet excitation energy level of the guest material.

2 . The light-emitting element according to claim 1 , wherein a difference between a singlet excitation energy level of the first organic compound and a triplet excitation energy level of the first organic compound is larger than 0 eV and smaller than or equal to 0.2 eV.

3 . The light-emitting element according to claim 1 , wherein the guest material emits light.

4 . The light-emitting element according to claim 1 ,

wherein the first organic compound comprises a first π-electron deficient heteroaromatic skeleton and a first π-electron rich heteroaromatic skeleton, and

wherein the second organic compound comprises a second π-electron deficient heteroaromatic skeleton and a second π-electron rich heteroaromatic skeleton.

5 . The light-emitting element according to claim 4 ,

wherein the first π-electron deficient heteroaromatic skeleton comprises a diazine skeleton or a triazine skeleton,

wherein the first π-electron rich heteroaromatic skeleton comprises any one or more of an acridine skeleton, a phenoxazine skeleton, or a 3-(9-phenyl-9H-carbazole-3-yl)-9H-carbazole skeleton,

wherein the second π-electron deficient heteroaromatic skeleton comprises a pyridine skeleton or a diazine skeleton, and

wherein the second π-electron rich heteroaromatic skeleton comprises any one or more of a furan skeleton, a thiophene skeleton, a fluorine skeleton, and a pyrrole skeleton.

6 . The light-emitting element according to claim 1 ,

wherein a weight ratio of the second organic compound to the first organic compound is from 1:0.05 to 1:0.5, and

wherein a weight ratio of the second organic compound to the guest material is from 1:0.001 to 1:0.01.

7 . A display device comprising:

the light-emitting element according to claim 1 ; and

a color filter, a sealant, or a transistor.

8 . The light-emitting element according to claim 1 ,

wherein a HOMO level of the first organic compound is higher than or equal to a HOMO level of the second organic compound, and

wherein a LUMO level of the first organic compound is lower than or equal to a LUMO level of the second organic compound.

9 . A light-emitting element comprising:

a pair of electrodes; and

an EL layer between the pair of electrodes,

wherein the EL layer comprises a light-emitting layer,

wherein the light-emitting layer comprises a first organic compound, a second organic compound, and a guest material,

wherein the first organic compound emits a thermally activated delayed fluorescence at room temperature,

wherein the guest material emits fluorescence,

wherein emission energy of the first organic compound is higher than phosphorescence emission energy of the guest material,

wherein a triplet excitation energy level of the second organic compound is higher than a triplet excitation energy level of the guest material, and

wherein a difference between a singlet excitation energy level of the second organic compound and the triplet excitation energy level of the second organic compound is larger than a difference between a singlet excitation energy level of the first organic compound and a triplet excitation energy level of the first organic compound.

10 . The light-emitting element according to claim 9 , wherein a difference between the singlet excitation energy level of the first organic compound and the triplet excitation energy level of the first organic compound is larger than 0 eV and smaller than or equal to 0.2 eV.

11 . The light-emitting element according to claim 9 , wherein the guest material emits light.

12 . The light-emitting element according to claim 9 ,

wherein the first organic compound comprises a first π-electron deficient heteroaromatic skeleton and a first π-electron rich heteroaromatic skeleton, and

wherein the second organic compound comprises a second π-electron deficient heteroaromatic skeleton and a second π-electron rich heteroaromatic skeleton.

13 . The light-emitting element according to claim 12 ,

wherein the first π-electron deficient heteroaromatic skeleton comprises a diazine skeleton or a triazine skeleton,

wherein the first π-electron rich heteroaromatic skeleton comprises any one or more of an acridine skeleton, a phenoxazine skeleton, or a 3-(9-phenyl-9H-carbazole-3-yl)-9H-carbazole skeleton,

wherein the second π-electron deficient heteroaromatic skeleton comprises a pyridine skeleton or a diazine skeleton, and

wherein the second π-electron rich heteroaromatic skeleton comprises any one or more of a furan skeleton, a thiophene skeleton, a fluorine skeleton, and a pyrrole skeleton.

14 . The light-emitting element according to claim 9 ,

wherein a weight ratio of the second organic compound to the first organic compound is from 1:0.05 to 1:0.5, and

wherein a weight ratio of the second organic compound to the guest material is from 1:0.001 to 1:0.01.

15 . A display device comprising:

the light-emitting element according to claim 9 ; and

a color filter, a sealant, or a transistor.

16 . The light-emitting element according to claim 9 ,

wherein a HOMO level of the first organic compound is higher than or equal to a HOMO level of the second organic compound, and

wherein a LUMO level of the first organic compound is lower than or equal to a LUMO level of the second organic compound.

17 . The light-emitting element according to claim 1 ,

wherein the singlet excitation energy level of the second organic compound is higher than a singlet excitation energy level of the first organic compound.

18 . The light-emitting element according to claim 9 ,

wherein the singlet excitation energy level of the second organic compound is higher than the singlet excitation energy level of the first organic compound.

Priority Claims (1)

Continuity (4)

References Cited (215)