Thermoset adhesive, automotive component using thermoset adhesive, and method of manufacturing same
A thermoset adhesive for bonding two materials having different linear expansion coefficients with reduced warping and without spaces being formed therebetween. The thermoset adhesive of the present invention comprises an epoxy resin, a core-shell rubber, thermally expansive microparticles, and a curing agent. The thermally expansive microparticles can have at least one or any combination of an average particle size of from 9 to 19 μm, an expansion initiation temperature of from 70 to 100° C., and a maximum expansion temperature of from 110 to 135° C.
1. A component comprising:
a first plate-shaped member,
a second plate-shaped member, and
a cured thermoset adhesive disposed between the first plate-shaped member and the second plate-shaped member and bonding together the first plate-shaped member and the second plate-shaped member,
wherein the first plate-shaped member has a linear expansion coefficient different from a linear expansion coefficient of the second plate-shaped member, and the thermoset adhesive comprises an epoxy resin, a core-shell rubber, thermally expansive microparticles, and a hardening agent, with the thermally expansive microparticles having an average particle size of from 9 to 19 μm, an expansion initiation temperature of from 70 to 100° C., and a maximum expansion temperature of from 110 to 135° C.
2. The component according to claim 1 , wherein the thermoset adhesive has a heat generation initiation temperature of 150° C. or less, and a maximum heat generation temperature of 155° C. or less, when differential scanning calorimetry is performed at a temperature gradient of 10° C./minute.
3. The component according to claim 2 , wherein the first plate-shaped member contains aluminum.
4. The component according to claim 3 , wherein the second plate-shaped member contains iron.
5. The component according to claim 2 , wherein the second plate-shaped member contains iron.
6. The component according to claim 1 , wherein the thermoset adhesive comprises an amount of thermally expansive microparticles equivalent to about 0.3 mass % or more of the thermoset adhesive.
7. The component according to claim 6 , wherein the thermoset adhesive comprises an amount of thermally expansive microparticles equivalent to about 20 mass % or less of the thermoset adhesive.
8. The component according to claim 6 , wherein the thermoset adhesive comprises an amount of thermally expansive microparticles equivalent to about 15 mass % or less of the thermoset adhesive.
9. The component according to claim 6 , wherein the thermoset adhesive comprises an amount of thermally expansive microparticles equivalent to about 12 mass % or less of the thermoset adhesive.
10. The component according to claim 1 , wherein the thermally expansive microparticles of the thermoset adhesive exhibit a volumetric expansion factor of about 2× or more.
11. The component according to claim 10 , wherein the thermally expansive microparticles of the thermoset adhesive exhibit a volumetric expansion factor of about 20× or less.
12. The component according to claim 10 , wherein the thermally expansive microparticles of the thermoset adhesive exhibit a volumetric expansion factor of about 15× or less.
13. The component according to claim 10 , wherein the thermally expansive microparticles of the thermoset adhesive exhibit a volumetric expansion factor of about 10× or less.
14. The component according to claim 1 , wherein the thermoset adhesive has a viscosity, measured at 25° C. and a shear rate of 15.5 s −1 using a rotational viscometer, in the range of from about generally roughly 10 Pa·s up to about 1,000 Pa s.
15. The component according to claim 1 , wherein the first plate-shaped member contains aluminum.
16. The component according to claim 15 , wherein the second plate-shaped member contains iron.
17. The component according to claim 1 , wherein the second plate-shaped member contains iron.
18. The component according to claim 1 , wherein said component is an automotive component.