IP Library › Granted Patent US 12,492,326
Granted Patent B2
US 12,492,326 · App. 17/759,895 · Granted Dec 9, 2025

Thermally expandable and thermosetting adhesive sheet

Inventors: Tomoaki Uchiya (Tokyo, JP); Guanqiao Li (Sagamihara, JP)
Assignee: 3M INNOVATIVE PROPERTIES COMPANY
C09J7/35B32B5/022B32B7/12B32B27/12B32B27/36C08K7/18B32B2250/02B32B2255/10B32B2255/26B32B2260/021B32B2260/046B32B2307/542B32B2405/00C08K2201/003C09J2301/1242C09J2301/408C09J2301/412
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Quick Facts
Patent No.
US 12,492,326
App. No.
17/759,895
Granted
Dec 9, 2025
Kind
B2
Abstract

An adhesive sheet is a thermally expandable and thermosetting adhesive sheet including a substrate and a first layer provided on at least one surface of the substrate. The first layer contains an adhesive portion having an adhesive composition and thermally expandable first particles contained within the adhesive composition, and second particles provided in the adhesive portion and having different materials from those of the first particles, and each of the second particles is larger than each of the first particles.

Claims (29)

1 . An adhesive sheet being thermally expandable and thermosetting, the adhesive sheet comprising:

an insulative substrate;

a first layer provided on a first side of the substrate, wherein the first layer contains

a first adhesive portion having

first particles being thermally expandable, and

second particles each comprising a non-thermally expandable, heat-resistant material that is a different material from that of the first particles, wherein each of the second particles is larger than each of the first particles, wherein at least some of the second particles are larger than a thickness of the first adhesive portion; and

a second layer provided on a second, opposite side of the substrate, wherein the second layer comprises

a second adhesive portion comprising a plurality of the first particles and

an adhesive permeable layer, formed from a non-woven fabric, provided on a surface of the adhesive second portion and capable of permeating an adhesive composition upon thermal expansion of the first particle, and wherein the adhesive sheet is in a tack-free state prior to thermal expansion of the adhesives in the first and second layers.

2 . The adhesive sheet according to claim 1 , wherein the second particle has a spherical shape.

3 . The adhesive sheet according to claim 1 , wherein a particle diameter of the first particle is smaller than 50 μm.

4 . The adhesive sheet according to claim 1 , wherein a particle diameter of the second particle is larger than 10 μm.

5 . The adhesive sheet according to claim 1 , wherein a one or more second particles protrude from about 6 μm to about 60 μm from a top surface of the first layer.

6 . A method of adhering two surfaces using a thermally expandable adhesive sheet, the method comprising:

selecting a thermally expandable adhesive sheet comprising:

an insulative substrate;

a first layer provided on a first side of the substrate, wherein the first layer contains

a first adhesive portion having

first particles being thermally expandable, and

second particles each comprising a non-thermally expandable, heat-resistant material that is a different material from that of the first particles, wherein each of the second particles is larger than each of the first particles, wherein at least some of the second particles are larger than a thickness of the first adhesive portion; and

a second layer provided on a second, opposite side of the substrate, wherein the second layer comprises

a second adhesive portion comprising a plurality of the first particles and

an adhesive permeable layer, formed from a non-woven fabric, provided on a surface of the adhesive second portion and capable of permeating an adhesive composition upon thermal expansion of the first particle, and wherein the adhesive sheet is in a tack-free state prior to thermal expansion of the adhesives in the first and second layers;

positioning the thermally expandable adhesive sheet in a tack-free state between two surfaces to be adhered, wherein the thermally expandable adhesive sheet is narrower than a gap between the surfaces;

applying heat to the thermally expandable adhesive sheet to initiate thermal expansion of the first particles; and

allowing the adhesive composition to cure, thereby bonding the two surfaces together.

7 . The method according to claim 6 , further comprising the step of adjusting the thickness of the substrate to match the gap between the surfaces to be adhered.

8 . The method according to claim 6 , wherein the second particles protrude from the adhesive portion before heating, maintaining separation between the adhesive portion and the surface to be adhered.

9 . The method according to claim 6 , wherein the thermally expandable adhesive sheet provides electrical insulation between in a motor assembly, wherein a first surface to be adhered to is a stator body surface and a second surface to be adhered to is a coil.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 1, 2022
From: UCHIYA, TOMOAKI; LI, GUANQIAO
To: 3M INNOVATIVE PROPERTIES COMPANY
Reel/Frame 060688/0316 →
Priority Claims (1)
JP 2020-021585 · Feb 12, 2020 · national
Continuity (1)
Related Publication 20230131701A1 · Apr 27, 2023
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