Insulated wire
The present invention aims to provide and insulated wire having an insulation layer which is excellent in insulation properties and has a low dielectric constant. The insulated wire of the present invention includes a conductor (A) and an insulation layer (B) formed around the periphery of the conductor (A). The insulation layer (B) is formed from a resin composition containing an aromatic polyether ketone resin (I) and a fluororesin (II). The fluororesin (II) is a copolymer of tetrafluoroethylene and a perfluoroethylenic unsaturated compound represented by the following formula (1): CF 2 ═CF—Rf 1 (1) wherein Rf 1 represents —CF 3 or —ORf 2 , and Rf 2 is a C1-C5 perfluoroalkyl group. The aromatic polyether ketone resin (I) and the fluororesin (II) satisfy a melt viscosity ratio (I)/(II) of 0.3 to 5.0.
1. An insulated wire, comprising:
a conductor (A); and
an insulation layer (B) formed around the periphery of the conductor (A),
the insulation layer (B) being formed from a resin composition comprising an aromatic polyether ketone resin (I) and a fluororesin (II),
the fluororesin (II) being a copolymer of tetrafluoroethylene and a perfluoroethylenic unsaturated compound represented by the following formula (1):
CF 2 ═CF—Rf 1 (1)
wherein Rf 1 represents —CF 3 ,
the aromatic polyether ketone resin (I) and the fluororesin (II) satisfying a melt viscosity ratio (I)/(II) of 0.5 to 2.5,
wherein the aromatic polyether ketone resin (I) is polyether ether ketone and has a melt viscosity of 0.25 to 1.30 kNsm −2 at 60 sec −1 and 390° C., and
the fluororesin (II) comprises 85 to 95 mol % of tetrafluoroethylene and 5 to 15 mol % of the perfluoroethylenic unsaturated compound represented by the formula (1), and has a melt viscosity of 0.55 to 2.23 kNsm −2 at 60 sec −1 and 390° C.
2. The insulated wire according to claim 1 ,
wherein the insulation layer (B) satisfies that the fluororesin (II) is dispersed as particles in the aromatic polyether ketone resin (I), and
the fluororesin (II) has an average dispersed particle size of not larger than 0.5 μm.
3. The insulated wire according to claim 1 ,
wherein the insulation layer (B) satisfies that the fluororesin (II) is dispersed as particles in the aromatic polyether ketone resin (I), and the fluororesin (II) has a maximum dispersed particle size of not larger than 1.0 μm.
4. The insulated wire according to claim 1 ,
wherein the insulation layer (B) satisfies that a ratio (I):(II) by mass between the aromatic polyether ketone resin (I) and the fluororesin (II) is 95:5 to 50:50.
5. The insulated wire according to claim 1 ,
wherein the fluororesin (II) has a melt flow rate of 0.1 to 100 g/10 min.