IP Library › Granted Patent US 11,075,078
Granted Patent B1
US 11,075,078 · App. 16/810,957 · Granted Jul 27, 2021

Method for making a semiconductor device including a superlattice within a recessed etch

Inventors: Nyles Wynn Cody (Tempe, AZ); Keith Doran Weeks (Chandler, AZ); Robert John Stephenson (Duxford, GB); Richard Burton (Phoenix, AZ); Yi-Ann Chen (Campbell, CA); Dmitri Choutov (Sunnyvale, CA); Hideki Takeuchi (San Jose, CA); Yung-Hsuan Yang (San Jose, CA)
Assignee: ATOMERA INCORPORATED
H01L21/02507H01L21/02304H01L21/762H01L29/105H01L29/15H01L29/7842
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Quick Facts
Patent No.
US 11,075,078
App. No.
16/810,957
Granted
Jul 27, 2021
Kind
B1
Abstract

A method for making a semiconductor device may include forming an isolation region adjacent an active region in a semiconductor substrate, and selectively etching the active region so that an upper surface of the active region is below an adjacent surface of the isolation region and defining a stepped edge therewith. The method may further include forming a superlattice overlying the active region. The superlattice may include stacked groups of layers, with each group of layers comprising stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

Claims (34)

1. A method for making a semiconductor device comprising:

forming an isolation region adjacent an active region in a semiconductor substrate;

selectively etching the active region so that an upper surface of the active region is below an adjacent surface of the isolation region and defining a stepped edge therewith; and

forming a superlattice overlying the active region, the superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

2. The method of claim 1 wherein forming the superlattice comprises forming the superlattice to a height of the stepped edge.

3. The method of claim 1 wherein etching comprises in-situ etching with an HCl etchant.

4. The method of claim 1 wherein etching comprises etching for a period in a range of 10 to 250 seconds.

5. The method of claim 1 wherein etching comprises etching to a depth of less than or equal to 400 Å.

6. The method of claim 1 wherein etching comprises ex-situ etching with a wet etch comprising a photoresist developer.

7. The method of claim 6 wherein the photoresist developer comprises tetramethylammonium hydroxide (TMAH).

8. The method of claim 1 wherein etching comprises etching at a temperature in a range of 840-860° C.

9. The method of claim 1 further comprising forming spaced-apart source and drain regions on the semiconductor substrate with the superlattice defining a channel therebetween, and a gate overlying the superlattice.

10. The method of claim 1 wherein the base semiconductor monolayers comprise silicon monolayers.

11. The method of claim 1 wherein the at least one non-semiconductor monolayer comprises oxygen.

12. The method of claim 1 wherein the base semiconductor monolayers comprise germanium.

13. The method of claim 1 wherein the at least one non-semiconductor monolayer comprises at least one of oxygen, nitrogen, fluorine, carbon and carbon-oxygen.

14. A method for making a semiconductor device comprising:

forming an isolation region adjacent an active region in a semiconductor substrate;

selectively etching the active region so that an upper surface of the active region is below an adjacent surface of the isolation region and defining a stepped edge therewith; and

forming a superlattice overlying the active region to a height of the stepped edge, the superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions; and

forming spaced-apart source and drain regions on the substrate with the superlattice defining a channel therebetween, and a gate overlying the superlattice.

15. The method of claim 14 wherein etching comprises in-situ etching with an HCl etchant.

16. The method of claim 14 wherein etching comprises etching to a depth of less than or equal to 400 Å.

17. The method of claim 14 wherein etching comprises ex-situ etching with a wet etch comprising a photoresist developer.

18. The method of claim 14 wherein etching comprises etching at a temperature in a range of 840-860° C.

19. The method of claim 14 wherein the base semiconductor monolayers comprise silicon monolayers, and the at least one non-semiconductor monolayer comprises oxygen.

20. A method for making a semiconductor device comprising:

forming an isolation region adjacent an active region in a semiconductor substrate;

selectively etching the active region so that an upper surface of the active region is below an adjacent surface of the isolation region and defining a stepped edge therewith; and

forming a superlattice overlying the active region, the superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

21. The method of claim 20 wherein forming the superlattice comprises forming the superlattice to a height of the stepped edge.

22. The method of claim 20 wherein etching comprises in-situ etching with an HCl etchant.

23. The method of claim 20 wherein etching comprises etching to a depth of less than or equal to 400 Å.

24. The method of claim 20 wherein etching comprises ex-situ etching with a wet etch comprising a photoresist developer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2020
From: CODY, NYLES WYNN; WEEKS, KEITH DORAN; STEPHENSON, ROBERT JOHN; BURTON, RICHARD; CHEN, YI-ANN; CHOUTOV, DMITRI; TAKEUCHI, HIDEKI; YANG, YUNG-HSUAN
To: ATOMERA INCORPORATED
Reel/Frame 052149/0821 →
Cited By (13)
US 12,230,694 US 12,267,996 US 12,308,229 US 12,315,722 US 12,315,723 US 12,382,689 US 12,417,912 US 12,439,658 US 12,575,199 US 12,635,122 US 12,635,271 US 12,707,690 US 12,712,011