IP Library › Granted Patent US 12,315,722
Granted Patent B2
US 12,315,722 · App. 18/604,620 · Granted May 27, 2025

Method for making a radio frequency silicon-on-insulator (RFSOI) wafer including a superlattice

Inventors: Nyles Wynn Cody (Tempe, AZ); Keith D. Weeks (Chandler, AZ); Robert Michael Vyne (Chandler, AZ); Robert J. Stephenson (Duxford, GB)
Assignee: ATOMERA INCORPORATED
H01L21/02488H01L21/0245H01L21/3065H01L21/324
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Quick Facts
Patent No.
US 12,315,722
App. No.
18/604,620
Granted
May 27, 2025
Kind
B2
Abstract

A method for making a semiconductor device may include, in an epitaxial deposition tool, performing an anneal on a semiconductor on insulator (SOI) substrate including a first semiconductor layer, an insulating layer on the first semiconductor layer, and a second semiconductor layer on the insulating layer, the second semiconductor layer having a first thickness. The method may also include, in the epitaxial deposition tool, performing an in-situ etch to reduce the second semiconductor layer to a second thickness less than the first thickness, and forming a superlattice layer on the second semiconductor layer. The superlattice layer may include a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

Claims (29)

1. A method for making a semiconductor device comprising:

in an epitaxial deposition tool,

performing an anneal on a semiconductor on insulator (SOI) substrate comprising a first semiconductor layer, an insulating layer on the first semiconductor layer, and a second semiconductor layer on the insulating layer, the second semiconductor layer having a first thickness,

performing an in-situ etch at a temperature in a range of 950° C. to 1050° C. to reduce the second semiconductor layer to a second thickness less than the first thickness and with a haze in a range of 0.235 to 0.5 PPM, and

forming a superlattice layer on the second semiconductor layer, the superlattice layer comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

2. The method of claim 1 wherein the first thickness is in a range of 30 nm to 90 nm.

3. The method of claim 1 wherein the second thickness is in a range of 10 nm to 20 nm.

4. The method of claim 1 wherein performing the anneal comprises annealing the SOI substrate at a temperature greater than 1000° C.

5. The method of claim 1 wherein performing the anneal comprises annealing the SOI substrate in a hydrogen environment.

6. The method of claim 1 wherein performing the in-situ etch comprises performing an in-situ HCl etch.

7. The method of claim 6 wherein performing the in-situ HCl etch comprises introducing an HCl gas flow in a range of 100-1000 sccm.

8. The method of claim 1 wherein performing the in-situ etch comprises performing the in-situ at an etch rate in a range of 5-200 nm per minute.

9. The method of claim 1 further comprising epitaxially forming a third semiconductor layer on the superlattice layer, and forming at least one semiconductor circuit in the third semiconductor layer.

10. The method of claim 1 wherein the base semiconductor monolayers comprise silicon.

11. The method of claim 1 wherein the non-semiconductor monolayers comprise oxygen.

12. A method for making a semiconductor device comprising:

in an epitaxial deposition tool,

performing an anneal on a semiconductor on insulator (SOI) substrate comprising a first semiconductor layer, an insulating layer on the first semiconductor layer, and a second semiconductor layer on the insulating layer, the second semiconductor layer having a first thickness,

performing an in-situ etch at a temperature in a range of 950° C. to 1050° C. to reduce the second semiconductor layer to a second thickness less than the first thickness and with a haze in a range of 0.235 to 0.5 PPM,

forming a superlattice layer on the second semiconductor layer, the superlattice layer comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions, and

epitaxially forming a third semiconductor layer on the superlattice layer; and

forming at least one semiconductor circuit in the third semiconductor layer.

13. The method of claim 12 wherein the first thickness is in a range of 30 nm to 90 nm.

14. The method of claim 12 wherein the second thickness is in a range of 10 nm to 20 nm.

15. The method of claim 12 wherein performing the anneal comprises annealing the SOI substrate at a temperature greater than 1000° C. in a hydrogen environment.

16. The method of claim 12 wherein performing the in-situ etch comprises performing an in-situ HCl etch.

17. The method of claim 16 wherein performing the in-situ HCl etch comprises introducing an HCl gas flow in a range of 100-1000 sccm.

18. The method of claim 12 wherein performing the in-situ etch comprises performing the in-situ etch at an etch rate in a range of 5-200 nm per minute.

19. The method of claim 12 further comprising forming a coating on the first semiconductor layer prior to performing the in-situ etch.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2024
From: CODY, NYLES WYNN; WEEKS, KEITH DORAN; VYNE, ROBERT MICHAEL; STEPHENSON, ROBERT J.
To: ATOMERA INCORPORATED
Reel/Frame 066966/0917 →
Continuity (2)
Provisional Application 63490119 · Mar 14, 2023
Related Publication 20240312781A1 · Sep 19, 2024
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