IP Library Granted Patent US 12,439,658
Granted Patent B2
US 12,439,658 · App. 17/663,852 · Granted Oct 7, 2025

Semiconductor device including a superlattice providing metal work function tuning

Inventors: Robert J. Mears (Wellesley, MA); Hideki Takeuchi (San Jose, CA)
Assignee: ATOMERA INCORPORATED
H10D62/118H10D30/031H10D30/6713H10D30/6735H10D30/6757H10D30/751H10D30/791H10D62/815H10D62/8171H10D84/0128H10D84/013H10D84/038
View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 12,439,658
App. No.
17/663,852
Granted
Oct 7, 2025
Kind
B2
Abstract

A semiconductor gate-all-around (GAA) device may include a semiconductor substrate, source and drain regions on the semiconductor substrate, a plurality of semiconductor nanostructures extending between the source and drain regions, a gate surrounding the plurality of semiconductor nanostructures in a gate-all-around arrangement, and a dopant diffusion liner adjacent at least one of the source and drain regions and comprising a first superlattice. The first superlattice may include a plurality of stacked groups of layers, with each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

Claims (37)

1. A semiconductor gate-all-around (GAA) device comprising:

a semiconductor substrate;

source and drain regions on the semiconductor substrate;

a plurality of semiconductor nanostructures extending between the source and drain regions;

a gate surrounding the plurality of semiconductor nanostructures in a gate-all-around arrangement; and

a dopant diffusion liner adjacent at least one of the source and drain regions and comprising a first superlattice, the first superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

2. The semiconductor device of claim 1 wherein the dopant diffusion liner comprises respective portions adjacent each of the source and drain regions.

3. The semiconductor device of claim 1 further comprising a second superlattice within at least one of the nanostructures, the second superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

4. The semiconductor device of claim 1 further comprising a third superlattice embedded in the semiconductor substrate extending between the source and drain regions, the third superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

5. The semiconductor device of claim 1 further comprising a fourth superlattice on the semiconductor substrate beneath the source region, the fourth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

6. The semiconductor device of claim 1 further comprising a fifth superlattice on the semiconductor substrate beneath the drain region, the fifth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

7. The semiconductor device of claim 1 wherein the gate comprises a metal.

8. The semiconductor device of claim 1 wherein the base semiconductor portion comprises silicon.

9. The semiconductor device of claim 1 wherein the at least one non-semiconductor monolayer comprises oxygen.

10. A semiconductor gate-all-around (GAA) device comprising:

a semiconductor substrate;

source and drain regions on the semiconductor substrate;

a plurality of semiconductor nanostructures extending between the source and drain regions;

a gate surrounding the plurality of semiconductor nanostructures in a gate-all-around arrangement;

source and drain dopant diffusion liners adjacent respective portions of the source and drain regions and each comprising a first superlattice, the first superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions; and

a second superlattice within at least one of the nanostructures, the second superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

11. The semiconductor device of claim 10 further comprising a third superlattice embedded in the semiconductor substrate extending between the source and drain regions, the third superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

12. The semiconductor device of claim 10 further comprising a fourth superlattice on the semiconductor substrate beneath the source region, the fourth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

13. The semiconductor device of claim 10 further comprising a fifth superlattice on the semiconductor substrate beneath the drain region, the fifth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base semiconductor monolayers defining a base semiconductor portion, and at least one non-semiconductor monolayer constrained within a crystal lattice of adjacent base semiconductor portions.

14. The semiconductor device of claim 10 wherein the gate comprises a metal.

15. A semiconductor gate-all-around (GAA) device comprising:

a semiconductor substrate;

source and drain regions on the semiconductor substrate;

a plurality of semiconductor nanostructures extending between the source and drain regions;

a gate surrounding the plurality of semiconductor nanostructures in a gate-all-around arrangement; and

a dopant diffusion liner adjacent at least one of the source and drain regions and comprising a first superlattice, the first superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

16. The semiconductor device of claim 15 wherein the dopant diffusion liner comprises respective portions adjacent each of the source and drain regions.

17. The semiconductor device of claim 15 further comprising a second superlattice within at least one of the nanostructures, the second superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base semiconductor portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

18. The semiconductor device of claim 15 further comprising a third superlattice embedded in the semiconductor substrate extending between the source and drain regions, the third superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

19. The semiconductor device of claim 15 further comprising a fourth superlattice on the semiconductor substrate beneath the source region, the fourth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

20. The semiconductor device of claim 15 further comprising a fifth superlattice on the semiconductor substrate beneath the drain region, the fifth superlattice comprising a plurality of stacked groups of layers, each group of layers comprising a plurality of stacked base silicon monolayers defining a base silicon portion, and at least one oxygen monolayer constrained within a crystal lattice of adjacent base silicon portions.

21. The semiconductor device of claim 15 wherein the gate comprises a metal.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 24, 2022
From: MEARS, ROBERT J.; TAKEUCHI, HIDEKI
To: ATOMERA INCORPORATED
Reel/Frame 059997/0939 →
Continuity (4)
Provisional Application 63212292 · Jun 18, 2021
Provisional Application 63211174 · Jun 16, 2021
Provisional Application 63189909 · May 18, 2021
Related Publication 20220376047A1 · Nov 24, 2022
References Cited (180)
US 4937204A · Ishibashi et al. · 1990 [cited by applicant]
US 5216262A · Tsu · 1993 [cited by applicant]
US 5357119A · Wang et al. · 1994 [cited by applicant]
US 5683934A · Candelaria · 1997 [cited by applicant]
US 5796119A · Seabaugh · 1998 [cited by applicant]
US 6141361A · Mears et al. · 2000 [cited by applicant]
US 6376337B1 · Wang et al. · 2002 [cited by applicant]
US 6447933B1 · Wang et al. · 2002 [cited by applicant]
US 6472685B2 · Takagi · 2002 [cited by applicant]
US 6741624B2 · Mears et al. · 2004 [cited by applicant]
US 6830964B1 · Mears et al. · 2004 [cited by applicant]
US 6833294B1 · Mears et al. · 2004 [cited by applicant]
US 6878576B1 · Mears et al. · 2005 [cited by applicant]
US 6891188B2 · Mears et al. · 2005 [cited by applicant]
US 6897472B2 · Mears et al. · 2005 [cited by applicant]
US 6927413B2 · Mears et al. · 2005 [cited by applicant]
US 6952018B2 · Mears et al. · 2005 [cited by applicant]
US 6958486B2 · Mears et al. · 2005 [cited by applicant]
US 6993222B2 · Mears et al. · 2006 [cited by applicant]
US 7018900B2 · Kreps · 2006 [cited by applicant]
US 7033437B2 · Mears et al. · 2006 [cited by applicant]
US 7034329B2 · Mears et al. · 2006 [cited by applicant]
US 7045377B2 · Mears et al. · 2006 [cited by applicant]
US 7045813B2 · Mears et al. · 2006 [cited by applicant]
US 7071119B2 · Mears et al. · 2006 [cited by applicant]
US 7105895B2 · Wang et al. · 2006 [cited by applicant]
US 7109052B2 · Mears et al. · 2006 [cited by applicant]
US 7123792B1 · Mears et al. · 2006 [cited by applicant]
US 7148712B1 · Prey, Jr. et al. · 2006 [cited by applicant]
US 7153763B2 · Hytha et al. · 2006 [cited by applicant]
US 7202494B2 · Blanchard et al. · 2007 [cited by applicant]
US 7227174B2 · Mears et al. · 2007 [cited by applicant]
US 7229902B2 · Mears et al. · 2007 [cited by applicant]
US 7265002B2 · Mears et al. · 2007 [cited by applicant]
US 7279699B2 · Mears et al. · 2007 [cited by applicant]
US 7279701B2 · Kreps · 2007 [cited by applicant]
US 7288457B2 · Kreps · 2007 [cited by applicant]
US 7303948B2 · Mears et al. · 2007 [cited by applicant]
US 7402512B2 · Derraa et al. · 2008 [cited by applicant]
US 7432524B2 · Mears et al. · 2008 [cited by applicant]
US 7435988B2 · Mears et al. · 2008 [cited by applicant]
US 7436026B2 · Kreps · 2008 [cited by applicant]
US 7446002B2 · Mears et al. · 2008 [cited by applicant]
US 7446334B2 · Mears et al. · 2008 [cited by applicant]
US 7491587B2 · Rao · 2009 [cited by applicant]
US 7514328B2 · Rao · 2009 [cited by applicant]
US 7517702B2 · Halilov et al. · 2009 [cited by applicant]
US 7531828B2 · Mears et al. · 2009 [cited by applicant]
US 7531829B2 · Blanchard · 2009 [cited by applicant]
US 7531850B2 · Blanchard · 2009 [cited by applicant]
US 7586116B2 · Kreps et al. · 2009 [cited by applicant]
US 7586165B2 · Blanchard · 2009 [cited by applicant]
US 7598515B2 · Mears et al. · 2009 [cited by applicant]
US 7612366B2 · Mears et al. · 2009 [cited by applicant]
US 7625767B2 · Huang et al. · 2009 [cited by applicant]
US 7659539B2 · Kreps et al. · 2010 [cited by applicant]
US 7700447B2 · Dukovski et al. · 2010 [cited by applicant]
US 7718996B2 · Dukovski et al. · 2010 [cited by applicant]
US 7781827B2 · Rao · 2010 [cited by applicant]
US 7812339B2 · Mears et al. · 2010 [cited by applicant]
US 7863066B2 · Mears et al. · 2011 [cited by applicant]
US 7880161B2 · Mears · 2011 [cited by examiner]
US 7928425B2 · Rao · 2011 [cited by applicant]
US 8389974B2 · Mears et al. · 2013 [cited by applicant]
US 9275996B2 · Mears et al. · 2016 [cited by applicant]
US 9406753B2 · Mears et al. · 2016 [cited by applicant]
US 9558939B1 · Stephenson et al. · 2017 [cited by applicant]
US 9716147B2 · Mears · 2017 [cited by applicant]
US 9721790B2 · Mears et al. · 2017 [cited by applicant]
US 9722046B2 · Mears et al. · 2017 [cited by applicant]
US 9899479B2 · Mears et al. · 2018 [cited by applicant]
US 9941359B2 · Mears et al. · 2018 [cited by applicant]
US 9972685B2 · Mears et al. · 2018 [cited by applicant]
US 10084045B2 · Mears et al. · 2018 [cited by applicant]
US 10107854B2 · Roy · 2018 [cited by applicant]
US 10109342B2 · Roy · 2018 [cited by applicant]
US 10109479B1 · Mears · 2018 [cited by examiner]
US 10170560B2 · Mears · 2019 [cited by applicant]
US 10170603B2 · Mears et al. · 2019 [cited by applicant]
US 10170604B2 · Mears et al. · 2019 [cited by applicant]
US 10191105B2 · Roy · 2019 [cited by applicant]
US 10249745B2 · Mears et al. · 2019 [cited by applicant]
US 10276625B1 · Mears et al. · 2019 [cited by applicant]
US 10304881B1 · Chen et al. · 2019 [cited by applicant]
US 10355151B2 · Chen et al. · 2019 [cited by applicant]
US 10361243B2 · Mears et al. · 2019 [cited by applicant]
US 10367028B2 · Chen et al. · 2019 [cited by applicant]
US 10367064B2 · Rao · 2019 [cited by applicant]
US 10381242B2 · Takeuchi · 2019 [cited by applicant]
US 10396223B2 · Chen et al. · 2019 [cited by applicant]
US 10410880B2 · Takeuchi · 2019 [cited by applicant]
US 10453945B2 · Mears et al. · 2019 [cited by applicant]
US 10461118B2 · Chen et al. · 2019 [cited by applicant]
US 10468245B2 · Weeks et al. · 2019 [cited by applicant]
US 10529757B2 · Chen et al. · 2020 [cited by applicant]
US 10529768B2 · Chen et al. · 2020 [cited by applicant]
US 10566191B1 · Weeks et al. · 2020 [cited by applicant]
US 10580866B1 · Takeuchi et al. · 2020 [cited by applicant]
US 10580867B1 · Takeuchi et al. · 2020 [cited by applicant]
US 10593761B1 · Takeuchi et al. · 2020 [cited by applicant]
US 10608027B2 · Chen et al. · 2020 [cited by applicant]
US 10608043B2 · Chen et al. · 2020 [cited by applicant]
US 10615209B2 · Chen et al. · 2020 [cited by applicant]
US 10636879B2 · Rao · 2020 [cited by applicant]
US 10727049B2 · Weeks et al. · 2020 [cited by applicant]
US 10741436B2 · Stephenson et al. · 2020 [cited by applicant]
US 10763370B2 · Stephenson · 2020 [cited by applicant]
US 10777451B2 · Stephenson et al. · 2020 [cited by applicant]
US 10811498B2 · Weeks et al. · 2020 [cited by applicant]
US 10818755B2 · Takeuchi et al. · 2020 [cited by applicant]
US 10825901B1 · Burton et al. · 2020 [cited by applicant]
US 10825902B1 · Burton et al. · 2020 [cited by applicant]
US 10840335B2 · Takeuchi et al. · 2020 [cited by applicant]
US 10840336B2 · Connelly et al. · 2020 [cited by applicant]
US 10840337B2 · Takeuchi et al. · 2020 [cited by applicant]
US 10840388B1 · Burton et al. · 2020 [cited by applicant]
US 10847618B2 · Takeuchi et al. · 2020 [cited by applicant]
US 10854717B2 · Takeuchi et al. · 2020 [cited by applicant]
US 10868120B1 · Burton et al. · 2020 [cited by applicant]
US 10879356B2 · Stephenson et al. · 2020 [cited by applicant]
US 10879357B1 · Burton et al. · 2020 [cited by applicant]
US 10884185B2 · Stephenson · 2021 [cited by applicant]
US 10937868B2 · Burton et al. · 2021 [cited by applicant]
US 10937888B2 · Burton et al. · 2021 [cited by applicant]
US 11075078B1 · Cody et al. · 2021 [cited by applicant]
US 11094818B2 · Takeuchi et al. · 2021 [cited by applicant]
US 11177351B2 · Weeks et al. · 2021 [cited by applicant]
US 11183565B2 · Burton et al. · 2021 [cited by applicant]
US 11302823B2 · Weeks et al. · 2022 [cited by applicant]
US 11329154B2 · Takeuchi et al. · 2022 [cited by applicant]
US 11355667B2 · Stephenson · 2022 [cited by applicant]
US 11362182B2 · Shin et al. · 2022 [cited by applicant]
US 11978771B2 · Weeks · 2024 [cited by examiner]
US 20030034529A1 · Fitzgerald et al. · 2003 [cited by applicant]
US 20030057416A1 · Currie et al. · 2003 [cited by applicant]
US 20050282330A1 · Mears et al. · 2005 [cited by applicant]
US 20060220118A1 · Stephenson et al. · 2006 [cited by applicant]
US 20060263980A1 · Kreps et al. · 2006 [cited by applicant]
US 20060267130A1 · Rao · 2006 [cited by applicant]
US 20060273299A1 · Stephenson et al. · 2006 [cited by applicant]
US 20060292765A1 · Blanchard et al. · 2006 [cited by applicant]
US 20070012910A1 · Mears et al. · 2007 [cited by applicant]
US 20070020833A1 · Mears et al. · 2007 [cited by applicant]
US 20080012004A1 · Huang et al. · 2008 [cited by applicant]
US 20100059737A1 · Bhuwalka et al. · 2010 [cited by applicant]
US 20110215299A1 · Rao · 2011 [cited by applicant]
US 20180175184A1 · Then et al. · 2018 [cited by applicant]
US 20190058059A1 · Stephenson et al. · 2019 [cited by applicant]
US 20190319135A1 · Stephenson · 2019 [cited by applicant]
US 20200135489A1 · Weeks et al. · 2020 [cited by applicant]
US 20200411645A1 · Weeks et al. · 2020 [cited by applicant]
US 20210126018A1 · Zhang et al. · 2021 [cited by applicant]
US 20210217875A1 · Burton · 2021 [cited by applicant]
US 20210217880A1 · Burton · 2021 [cited by applicant]
US 20210391426A1 · Takeuchi et al. · 2021 [cited by applicant]
US 20210391446A1 · Takeuchi et al. · 2021 [cited by applicant]
US 20220005706A1 · Weeks et al. · 2022 [cited by applicant]
US 20220005926A1 · Weeks et al. · 2022 [cited by applicant]
US 20220005927A1 · Weeks et al. · 2022 [cited by applicant]
US 20220278204A1 · Shin et al. · 2022 [cited by applicant]
EP 3648172 · 2020 [cited by applicant]
GB 2347520 · 2000 [cited by applicant]
U.S. Appl. No. 17/236,289, filed Apr. 21, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/236,329, filed Apr. 21, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/330,831, filed May 26, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/330,860, filed May 26, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/452,604, filed Oct. 28, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/452,610, filed Oct. 28, 2021 Hytha et al. [cited by applicant]
U.S. Appl. No. 17/653,305 , filed Mar. 3, 2022 Takeuchi et al. [cited by applicant]
U.S. Appl. No. 17/653,319 , filed Mar. 3, 2022 Takeuchi et al. [cited by applicant]
U.S. Appl. No. 17/663,849, filed May 18, 2022 Mears et al. [cited by applicant]
Luo et al., “Chemical Design of Direct-Gap Light-Emitting Silicon” published in Physical Review Letters, vol. 89, No. 7; Aug. 12, 2002; 4 pgs. [cited by applicant]
Maurizio Di Paolo Emilio “Quantum-Engineered Material Boosts Transistor Performance” https://www.eetimes.com/quantum-engineered-material-boosts-transistor-performance/#EE Times; retreived from internet Feb. 10, 2022; pp… [cited by applicant]
Mears et al. “Simultaneous Carrier Transport Enhancement and variability reduction in Si MOSFETs by insertion of partial Monolayers of oxygen” IEEE silicon Nanoelectronics Workshop (2012): (Date of conference Jun. 10-11… [cited by applicant]
Novikov et al. “Silicon-based Optoelectronics” 1999-2003, pp. 1-6. [cited by applicant]
R. Tsu “Phenomena in silicon nanostructure device” published online Sep. 6, 2000 by Applied Physics and Materials Science & Processing, pp. 391-402. [cited by applicant]
R. Tsu “Si Based Green ELD: Si-Oxygen Superlattice” ysiwyg://l/http://www3.interscience.wiley.com/cgi-bin/abstract/72512946/start: published online Jul. 21, 2000; 2 pgs. Abstract Only. [cited by applicant]
Xu et al. “Effectiveness of Quasi-confinement technology for improving P-chanel Si an Ge MOSSFET performance” Department of Electrical Engineering and Computer Science, University of California, Berkeley, 2012, pp. 2. m… [cited by applicant]
Xu et al. “Extension of planar bulk n-channel MOSFET scaling with oxygen insertion technology” IEEE Transactions on Electron devices, vol. 61, No. 9; Sep. 2014. pp. 3345. [cited by applicant]
Xu et al., “MOSFET performance and scalability enhancement by insertion of oxygen layers”, Department of Electrical Engineering and Computer Science, University of California, Published in International Electron Devices… [cited by applicant]