Surfactant-assisted synthesis of surface-functionalized nanoparticle-polymer electrospun composites
A method is disclosed for synthesizing nanofilters for water treatment. The method includes: dispersing an active binding agent in an organic solvent solution to create a suspension of the active binding agent and the solution of the solvent; dissolving an organic polymer resin and an anionic surfactant in the suspension of the active binding agent and the solvent solution to create a sol gel; and electrospinning the sol gel to form electrospun nanofiber composites with embedded, surface-active nanoparticles.
1. A method for synthesizing nanofilters for water treatment, the method comprising:
dispersing amorphous Ferrihydrite (Fh) nanoparticles in an organic solvent solution to create a suspension of the amorphous Ferrihydrite (Fh) nanoparticles and the organic solvent solution;
dissolving an organic polymer resin and a quaternary ammonium surfactant in the suspension of the amorphous Ferrihydrite (Fh) nanoparticles and the organic solvent solution to create a sol gel, wherein the quaternary ammonium surfactant is cetyltrimethylammonium bromide (CTAB) or tetrabutylammonium bromide (TBAB); and
electrospinning the sol gel to form electrospun nanofiber composites with embedded, surface-active nanoparticles.
2. The method of claim 1 , wherein the organic solvent comprises dimethylformamide (DMF), and the organic polymer resin comprises poly-acrylonitrile (PAN).
3. A method for removing contaminants using the synthesized nanofilters for water treatment of claim 1 , the method further comprising:
removing lead (Pb), Copper (Cu), Cadmium (Cd), Chromium (Cr) and/or Arsenic (As) from a water source with the electrospun composite with surface-active nanoparticles.
4. A method for removing contaminants using the synthesized nanofilters for water treatment of claim 1 , further comprising:
inactivating viruses from a water source with the surface-active nanoparticles.
5. A method for removing contaminants using the synthesized nanofilters for water treatment of claim 1 , further comprising:
removing arsenate and chromate in a flow-through filtration system with the electrospun nanofiber composites with embedded, surface-active nanoparticles.
6. The method of claim 1 , wherein the electrospun nanofiber composites with surface-active nanoparticles forms nanoparticles having a diameter of approximately 100 nm.
7. The method of claim 1 , further comprising:
placing the electrospun nanofiber composites with surface-active nanoparticles in a flow-through filtration system for point-of-use (POU) water treatment.
8. The method of claim 1 , wherein the electrospinning of the sol gel further comprises:
a single-pot synthesis, wherein the electrospun nanofiber composites with embedded, surface-active nanoparticles do not undergo a post-processing step.
9. An electrospun polyacrylonitrile (PAN) nanofiber composite with embedded, surface-active nanoparticles that is prepared by the method of claim 2 .
10. An electrospun polyacrylonitrile (PAN) nanofiber composite with embedded, surface-active nanoparticles, the PAN nanofiber composite comprising:
Amorphous Ferrihydrite (Fh) nanoparticles;
dimethylformamide (DMF);
poly-acrylonitrile (PAN); and
cetyltrimethylammonium bromide (CTAB) or tetrabutylammonium bromide (TBAB).
11. The PAN nanofiber composite of claim 10 , that
the nanofilter is configured to remove lead (Pb), Copper (Cu), Cadmium (Cd), Chromium (Cr) and/or Arsenic (As) from a water source.
12. The PAN nanofiber composite of claim 10 , further comprising:
a flow-through filtration system configured to remove arsenate and/or chromate from a water source.
13. The PAN nanofiber composite of claim 10 , wherein the electrospun polyacrylonitrile (PAN) composite with surface-active nanoparticles forms nanoparticles having a diameter of approximately 100 nm.
14. The PAN nanofiber composite of claim 10 , further comprising:
a flow-through filtration system for point-of-use (POU) water treatment, and wherein the electrospun polyacrylonitrile (PAN) composite with surface-active nanoparticles are placed in the flow-through filtration system.
15. A method for removing metal contaminants from a source of water, the method comprising:
exposing a source of water to electrospun polyacrylonitrile (PAN) nanofiber composites with embedded, surface-active nanoparticles, wherein the electrospun polyacrylonitrile (PAN) nanofiber composites with embedded, surface-active nanoparticles comprise:
amorphous Ferrihydrite (Fh) nanoparticles, dimethylformamide (DMF), poly-acrylonitrile (PAN), and a quaternary ammonium surfactant selected from cetyltrimethylammonium bromide (CTAB) and tetrabutylammonium bromide (TBAB); and
removing the metal contaminants from the source of the water with the electrospun polyacrylonitrile (PAN) nanofiber composites with the embedded, surface-active nanoparticles.