IP Library › Granted Patent US 11,161,768
Granted Patent B2
US 11,161,768 · App. 16/318,559 · Granted Nov 2, 2021

Glass sheet having a high IR and visible transmission with a pleasing slight colour to neutral colour

Inventors: Thomas Lambricht (Perwez, BE); Audrey Dogimont (Sart-Dames-Avelines, BE); Aline Degand (Bleret, BE); Michel Bogaerts (Braine-le-Chateau, BE)
Assignee: AGC GLASS EUROPE
C03C3/087C03C4/0092C03C4/02C03C4/10
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Quick Facts
Patent No.
US 11,161,768
App. No.
16/318,559
Granted
Nov 2, 2021
Kind
B2
Abstract

A glass sheet having a composition which comprises total iron (expressed in terms of Fe 2 O 3 ) from 0.002-0.06 wt %; chromium (expressed as Cr 2 O 3 ) from 3-75 ppm; and manganese (expressed as MnO) from 50-1,000 ppm. The glass sheet has a LTD4 higher than 70%. Such a glass sheet exhibits at once a high luminous transmission, an increased transmission of infrared (IR) radiation and a pleasing slight color or an almost neutral to neutral color.

Claims (52)

1. A glass sheet having a composition comprising the following in weight percentage, expressed with respect to the total weight of the glass:

SiO 2 40-78%;

Al 2 O 3 0-18%;

B 2 O 3 0-18%;

Na 2 O 0-20%;

CaO 0-15%;

MgO 0-12%;

K 2 O 0-12%;

BaO 0-5%;

total iron (expressed in terms of Fe 2 O 3 ) 0.002-0.06 wt-%;

chromium (expressed as Cr 2 O 3 ) 3-75 ppm; and

manganese (expressed as MnO) 50-1,000 ppm,

wherein the glass sheet has a LTD4 higher than 70% and has a coefficient of absorption at a wavelength of 1,050 nm of less than 5 m −1 .

2. The glass sheet according to claim 1 , wherein the composition comprises: total iron 0.002-0.04 wt %.

3. The glass sheet according to claim 1 , wherein the composition comprises: total iron 0.002-0.02 wt %.

4. The glass sheet according to claim 1 , wherein the composition comprises an Fe 2+ content (expressed in the form of FeO) of less than 20 ppm.

5. The glass sheet according to claim 1 , wherein the composition comprises an Fe 2+ content (expressed in the form of FeO) of less than 5 ppm.

6. The glass sheet according to claim 1 , wherein the composition comprises: MnO≤800 ppm.

7. The glass sheet according to claim 1 , wherein the composition comprises: Cr 2 O 3 =−0.02*MnO+(Fe 2 O 3 /100)*x; x being between 15 and 30 and Cr 2 O 3 , MnO and Fe 2 O 3 being expressed in ppm.

8. The glass sheet according to claim 1 , wherein the composition comprises: Cr 2 O 3 =0.02*MnO+(Fe 2 O 3 /100)*x; x being between 15 and 30 and Cr 2 O 3 , MnO and Fe 2 O 3 being expressed in ppm.

9. The glass sheet according to claim 1 , wherein the glass sheet has a LTD4 higher than 80%.

10. The glass sheet according to claim 1 , wherein the glass sheet has a LTD4 higher than 85%.

11. The glass sheet according to claim 1 , wherein the glass sheet has a coefficient of absorption at the wavelength of 1,050 nm of less than 2 m −1 .

12. The glass sheet according to claim 1 , wherein the glass sheet has a Q factor value of Q≤5.

13. The glass sheet according to claim 1 , wherein the glass sheet has a Q factor value of Q≤4.

14. The glass sheet according to claim 1 , wherein the glass sheet has a Q factor value of Q≤3.

15. A glass sheet having a composition comprising the following in weight percentage, expressed with respect to the total weight of the glass:

SiO 2 40-78%;

Al 2 O 3 0-18%;

B 2 O 3 0-18%;

Na 2 O 0-20%;

CaO 0-15%;

MgO 0-12%;

K 2 O 0-12%;

BaO 0-5%;

total iron (expressed in terms of Fe 2 O 3 ) 0.002-0.06 wt-%;

chromium (expressed as Cr 2 O 3 ) 3-75 ppm; and

manganese (expressed as MnO) 50-1,000 ppm,

wherein the glass sheet has a LTD4 higher than 70% and has a coefficient of absorption at a wavelength of 950 nm of less than 5 m −1 .

16. A glass sheet having a composition comprising the following in weight percentage, expressed with respect to the total weight of the glass:

SiO 2 40-78%;

Al 2 O 3 0-18%;

B 2 O 3 0-18%;

Na 2 O 0-20%;

CaO 0-15;

MgO 0-12%;

K 2 O 0-12%;

BaO 0-5%;

total iron (expressed in terms of Fe 2 O 3 ) 0.002-0.06 wt-%;

chromium (expressed as Cr 2 O 3 ) 3-75 ppm; and

manganese (expressed as MnO) 50-1,000 ppm,

wherein the glass sheet has a LTD4 higher than 70% and has a coefficient of absorption at a wavelength of 850 nm of less than 5 m −1 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2019
From: LAMBRICHT, THOMAS; DOGIMONT, AUDREY; DEGAND, ALINE; BOGAERTS, MICHEL
To: AGC GLASS EUROPE
Reel/Frame 050778/0565 →
Priority Claims (1)
EP 16180331 · Jul 20, 2016 · regional
Continuity (1)
Related Publication 20190284087A1 · Sep 19, 2019
Cited By (4)
US 12,240,782 US 12,304,858 US 12,378,152 US 12,454,479