Method and carrier complexes for delivering molecules to cells
The invention relates to carrier complexes and methods for delivering molecules to cells. The carrier complexes comprises a molecule and an aromatic cationic peptide in accordance with the invention. In one embodiment, the method for delivering a molecule to a cell comprises contacting the cell with a carrier complex. In another embodiment, the method for delivering a molecule to a cell comprises contacting the cell with a molecule and an aromatic cationic peptide.
1. A carrier complex comprising a molecule conjugated to an aromatic cationic peptide, wherein the aromatic cationic peptide is selected from the group consisting of Tyr-D-Arg-Phe-Lys-NH 2 (DALDA), 2′,6′-Dmt-D-Arg-Phe-Lys-NH 2 (Dmt 1 -DALDA), Phe-D-Arg-Phe-Lys-NH 2 (Phe 1 -DALDA), D-Arg-2′,6′-Dmt-Lys-Phe-NH 2 and 2′,6′-Dmp-D-Arg-Phe-Lys-NH 2 (Dmp 1 -DALDA); and wherein the molecule is a peptide nucleic acid.
2. The carrier complex according to claim 1 , wherein the peptide has the formula Tyr-D-Arg-Phe-Lys-NH 2 (DALDA).
3. The carrier complex according to claim 1 , wherein the peptide has the formula 2′,6′-Dmt-D-Arg-Phe-Lys-NH 2 (Dmt 1 -DALDA).
4. The carrier complex according to claim 1 , wherein the peptide has the formula Phe-D-Arg-Phe-Lys-NH 2 (Phe 1 -DALDA).
5. The carrier complex according to claim 1 , wherein the peptide has the formula D-Arg-2′,6′-Dmt-Lys-Phe-NH 2 .
6. The carrier complex according to claim 1 , wherein the peptide has the formula 2′,6′-Dmp-D-Arg-Phe-Lys-NH 2 (Dmp 1 -DALDA).
7. The carrier complex according to claim 1 , wherein the aromatic cationic peptide comprises a linker.
8. The carrier complex according to claim 1 , wherein the molecule comprises a linker.
9. The carrier complex according to claim 1 , wherein the molecule and aromatic cationic peptide are chemically bonded.
10. The carrier complex according to claim 1 , wherein the molecule and aromatic cationic peptide are physically bonded.
11. A method for delivering a molecule to a cell, the method comprising contacting the cell with a carrier complex, wherein the carrier complex comprises the molecule conjugated to an aromatic cationic peptide, wherein the aromatic cationic peptide is selected from the group consisting of Tyr-D-Arg-Phe-Lys-NH 2 (DALDA), 2′,6′-Dmt-D-Arg-Phe Lys-NH 2 (Dmt 1 -DALDA), Phe-D-Arg-Phe-Lys-NH 2 (Phe 1 -DALDA), D-Arg-2′,6′-Dmt-Lys-Phe-NH 2 , and 2′,6′-Dmp-D-Arg-Phe-Lys-NH 2 (Dmp 1 -DALDA); and wherein the molecule is a peptide nucleic acid.
12. The method according to claim 11 , wherein the peptide has the formula Tyr-D-Arg-Phe-Lys-NH 2 (DALDA).
13. The method according to claim 11 , wherein the peptide has the formula 2′,6′-Dmt-D-Arg-Phe-Lys-NH 2 (Dmt 1 -DALDA).
14. The method according to claim 11 , wherein the peptide has the formula Phe-D-Arg-Phe-Lys-NH 2 (Phe 1 -DALDA).
15. The method according to claim 11 , wherein the peptide has the formula D-Arg-2′6′-Dmt-Lys-Phe-NH 2 .
16. The method according to claim 11 , wherein the peptide has the formula 2,6′-Dmp-D-Arg-Phe-Lys-NH 2 (Dmp 1 -DALDA).
17. The method according to claim 11 , wherein the cell is a bacterial cell.
18. The method according to claim 11 , wherein the cell is an animal cell.
19. The method according to claim 18 , wherein the animal cell is a mammalian cell.
20. The method according to claim 18 , wherein the cell is a neuronal cell.
21. The method according to claim 18 , wherein the cell is a renal epithelial cell.
22. The method according to claim 18 , wherein the cell is an intestinal epithelial cell.
23. The method according to claim 18 , wherein the cell is a vascular endothelial cell.
24. The method according to claim 18 , wherein the endothelial cell is a blood-brain barrier endothelial cell.
25. The method according to claim 18 , wherein the cell is a glial cell.
26. The method according to claim 18 , wherein the cell is a hepatocyte.
27. The method according to claim 11 , wherein the aromatic cationic peptide comprises a linker.
28. The method according to claim 11 , wherein the molecule comprises a linker.
29. The method according to claim 11 , wherein the molecule and aromatic cationic peptide are chemically bonded.
30. The method according to claim 11 , wherein the molecule and aromatic cationic peptide are chemically bonded.