Manufacturing method of composite oxide and manufacturing method of power storage device
An object is to reduce variation in shape of crystals that are to be formed. Solutions containing respective raw materials are made in an environment where an oxygen concentration is lower than that in air, the solutions containing the respective raw materials are mixed in an environment where an oxygen concentration is lower than that in air to form a mixture solution, and with use of the mixture solution, a composite oxide is formed by a hydrothermal method.
1. A production method comprising the steps of:
forming a first solution comprising Li in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising Li in a first water having an oxygen concentration lower than or equal to 4.5 ppm;
forming a second solution comprising P in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising P in a second water having an oxygen concentration lower than or equal to 4.5 ppm;
forming a third solution comprising one or more transition metal elements in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising the one or more transition metal elements in a third water having an oxygen concentration lower than or equal to 4.5 ppm;
mixing the first solution and the second solution in an atmosphere having an oxygen concentration lower than the oxygen concentration in air to form a first mixed solution comprising Li and P;
mixing the third solution and the first mixed solution in an atmosphere having an oxygen concentration lower than the oxygen concentration in air to form a second mixed solution; and
forming a compound represented by Formula LiMPO 4 from the second mixed solution by a hydrothermal method in an atmosphere having an oxygen concentration lower than the oxygen concentration in air,
wherein the one or more transition metal elements is one or more elements selected from the group consisting of Fe, Co, Ni and Mn, and
wherein M in LiMPO 4 denotes the one or more transition metal elements.
2. The production method according to claim 1 , wherein forming the compound represented by Formula LiMPO 4 is formed under a nitrogen atmosphere.
3. The production method according to claim 1 , wherein forming the compound represented by Formula LiMPO 4 is formed under a mixed atmosphere of nitrogen and hydrogen.
4. The production method according to claim 1 , wherein the compound represented by Formula LiMPO 4 has a crystal shape of a rectangular solid.
5. A method for manufacturing a power storage device, wherein a positive electrode of the power storage device is formed by applying, to a current collector of the positive electrode, a mixture comprising the compound formed by the production method according to claim 1 , a binder, and a solvent.
6. A production method comprising the steps of:
preparing a first water, a second water, and a third water by performing a nitrogen bubbling in water;
forming a first solution comprising Li in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising Li in the first water;
forming a second solution comprising P in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising P in the second water;
forming a third solution comprising one or more transition metal elements in an atmosphere having an oxygen concentration lower than the oxygen concentration in air by dissolving a compound comprising the one or more transition metal elements in the third water;
mixing the first solution and the second solution in an atmosphere having an oxygen concentration lower than the oxygen concentration in air to form a first mixed solution comprising Li and P;
mixing the third solution and the first mixed solution in an atmosphere having an oxygen concentration lower than the oxygen concentration in air to form a second mixed solution; and
forming a compound represented by Formula LiMPO 4 from the second mixed solution by a hydrothermal method in an atmosphere having an oxygen concentration lower than the oxygen concentration in air,
wherein the one or more transition metal elements is one or more elements selected from the group consisting of Fe, Co, Ni and Mn, and
wherein M in LiMPO 4 denotes the one or more transition metal elements.
7. The production method according to claim 6 , wherein each of the first water, the second water and the third water has an oxygen concentration lower than 4.5 ppm.
8. The production method according to claim 6 , wherein forming the compound represented by Formula LiMPO 4 is formed under a nitrogen atmosphere.
9. The production method according to claim 6 , wherein forming the compound represented by Formula LiMPO 4 is formed under a mixed atmosphere of nitrogen and hydrogen.
10. The production method according to claim 6 , wherein the compound represented by Formula LiMPO 4 has a crystal shape of a rectangular solid.
11. A method for manufacturing a power storage device, wherein a positive electrode of the power storage device is formed by applying, to a current collector of the positive electrode, a mixture comprising the compound formed by the production method according to claim 6 , a binder, and a solvent.