Positive electrode, secondary battery including the same, and method for manufacturing using dry mixing at high shear force
The present invention relates to a method for preparing a positive electrode, comprising preparing a mixture by dry mixing a positive electrode active material, a dry conductive material, and a dry binder, applying high shear force to the mixture, disposing the mixture on a current collector, and rolling the current collector on which the mixture is disposed, wherein the dry conductive material is at least any one of a carbon nanotube and a carbon fiber, and the high 10 shear force is 100 N to 500 N.
1. A positive electrode, comprising:
a current collector; and
a positive electrode active material layer disposed on the current collector, wherein the positive electrode active material layer comprises a positive electrode active material, a dry conductive material, and a dry binder, the positive electrode active material, the dry conductive material, and the dry binder have been subjected to a high shear force to form granules,
the dry conductive material comprises at least one of a carbon nanotube and a carbon fiber,
wherein the carbon nanotube has an average length from 5 μm to 80 μm,
wherein the carbon fiber has an average length from 5 μm to 10 μm,
the high shear force is 100 N to 500 N, and the positive electrode has a thickness deviation of 5 m or less.
2. The positive electrode of claim 1 , wherein the electrode adhesion of the positive electrode active material layer is 35 gf/20 mm to 200 gf/20 mm.
3. The positive electrode of claim 1 , wherein the dry conductive material is present in an amount of 1 wt % to 10 wt % based on a total weight of the positive electrode active material layer.
4. A secondary battery comprising:
the positive electrode of claim 1 ;
a negative electrode;
a separator disposed between the positive electrode and the negative electrode; and
an electrolyte.
5. The positive electrode of claim 1 , wherein the dry conductive material is in a form of a powder in which solvent is not present, and the dry binder is in a form of a powder in which solvent is not present.
6. A method for manufacturing a positive electrode, comprising:
preparing a mixture by dry mixing a positive electrode active material, a dry conductive material, and a dry binder;
applying high shear force to the mixture, wherein the positive electrode active material, the dry conductive material, and the dry binder are aggregated to form granules;
disposing the mixture on a current collector; and
rolling the current collector on which the mixture is disposed,
wherein
the dry conductive material is at least one of a carbon nanotube and a carbon fiber,
wherein the carbon nanotube has an average length from 5 μm to 80 μm,
wherein the carbon fiber has an average length from 5 μm to 10 μm, and
the high shear force is 100 N to 500 N.
7. The method of claim 6 , wherein the dry conductive material is carbon nanotube, which is a bundle shape carbon nanotube in which a plurality of carbon nanotube unit bodies are aggregated, and average diameters of the carbon nanotube unit bodies are 5 nm to 100 nm.
8. The method of claim 6 , wherein the dry conductive material is carbon fiber, and an average diameter of the carbon fiber is 5 nm to 500 nm.
9. The method of claim 6 , wherein the applying of high shear force to the mixture comprises shear-compressing the mixture to apply high shear force thereto.
10. The method of claim 6 , wherein the disposing of the mixture comprises disposing the mixture in a uniform thickness on the current collector by a scattering method.
11. The method of claim 6 , wherein the rolling of the current collector on which the mixture is disposed comprises placing the current collector on which the mixture is disposed on a belt, and rolling the current collector on which the mixture is disposed through a roll.
12. The method of claim 11 , wherein the placing of the current collector on which the mixture is disposed on a belt comprises pre-heating the belt to 50° C. to 100° C.
13. The method of claim 11 , wherein a temperature of the roll is 50° C. to 150° C. in the rolling of the current collector on which the mixture is disposed through a roll.
14. The method of claim 6 , wherein the dry binder is at least one of polyvinylidene fluoride-hexafluoropropylene and polytetrafluoroethylene.
15. The method of claim 6 , wherein the dry conductive material is in a form of a powder in which solvent is not present, and the dry binder is in a form of a powder in which solvent is not present.