Lithium secondary battery and method for preparing the same
A lithium secondary battery including a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode, wherein the negative electrode is lithiated by pre-lithiation, a total capacity of a negative electrode active material of the negative electrode is larger than a total capacity of a positive electrode active material of the positive electrode, and a charge capacity of the negative electrode is smaller than a charge capacity of the positive electrode by the pre-lithiation.
1. A lithium secondary battery comprising:
a positive electrode, a negative electrode, and a separator disposed between the positive electrode and the negative electrode,
wherein the negative electrode is lithiated by pre-lithiation,
wherein the pre-lithiation is performed by a process that allows lithium metal to be in contact with the negative electrode and the negative electrode and the lithium metal to be attached to each other by pressure in the range of 0.1 kgf per 1.5 cm 2 to 20 kgf per 1.5 cm 2 ,
a total capacity of a negative electrode active material of the negative electrode is larger than a total capacity of a positive electrode active material of the positive electrode, and
a charge capacity of the negative electrode is smaller than a charge capacity of the positive electrode due to the pre-lithiation of the negative electrode,
wherein the negative electrode comprises electroplated lithium, and
wherein the negative electrode has a lithiated capacity of 50% to 75% based on the total capacity of the negative electrode active material due to the pre-lithiation.
2. The lithium secondary battery of claim 1 , wherein lithium ions in an amount corresponding to a difference between the charge capacity of the positive electrode and the charge capacity of the negative electrode are electroplated to form the electroplated lithium.
3. The lithium secondary battery of claim 1 , wherein the electroplated lithium is configured to supply lithium ions to the positive electrode or the negative electrode during degradation of the lithium secondary battery.
4. The lithium secondary battery of claim 1 , wherein the charge capacity of the negative electrode is 10% or more to less than 100% of the charge capacity of the positive electrode.
5. A method of preparing the lithium secondary battery of claim 1 , the method comprising:
(1) performing pre-lithiation of a negative electrode in an amount greater than an irreversible capacity of the negative electrode by supplying lithium ions to the negative electrode to prepare a pre-lithiated negative electrode; and
(2) disposing a separator between the pre-lithiated negative electrode and a positive electrode,
wherein a charge capacity of the negative electrode is smaller than a charge capacity of the positive electrode due to the pre-lithiation of the negative electrode, and
wherein an amount of lithium corresponding to a capacity of 50% to 75% based on the total capacity of a negative electrode active material supplied through the pre-lithiation.
6. The method of claim 5 , wherein the pre-lithiation is performed such that an amount of lithium, which is greater than an amount of lithium to supplement an irreversible capacity loss of the negative electrode, is supplied to the negative electrode.
7. The method of claim 5 , wherein the charge capacity of the negative electrode is 10% or more to less than 100% of the charge capacity of the positive electrode.
8. The method of claim 5 , wherein a time for which lithium metal is in contact with the negative electrode during pre-lithiation is 40 minutes to 3 hours.
9. The method of claim 5 , further comprising performing lithium plating on the negative electrode by charging the lithium secondary battery.