Lithium electrode and lithium secondary battery comprising same
A lithium electrode and a lithium secondary battery including the same. More particularly, in the preparation of the lithium electrode, a protective layer for protecting the lithium metal is formed on the substrate, lithium metal may be deposited on the protective layer and then transferred to at least one side of the current collector to form a lithium electrode having a thin and uniform thickness, and the energy density of the lithium secondary battery using the lithium electrode thus manufactured may be improved.
1. A lithium electrode comprising:
a current collector;
a SiO coating layer on each side of the current collector,
wherein each SiO coating layer has a thickness of 60 μm to 120 μm;
a lithium metal layer on each SiO coating layer; and
a protective layer on each lithium metal layer,
wherein each protective layer consists of at least one selected from the group consisting of poly vinylidene fluoride (PVDF), poly vinylidene fluoride-hexafluoroethylene copolymer (PVDF-HFP copolymer), cyclo olefin polymer, cyclo olefin copolymer and styrene butadiene rubber-carboxymethyl cellulose (SBR-CMC).
2. The lithium electrode according to claim 1 , wherein each SiO coating layer is a mixed coating layer comprising SiO and graphite.
3. The lithium electrode according to claim 2 , wherein the SiO and graphite are mixed in a weight ratio of 1:1 to 1:9.
4. The lithium electrode according to claim 1 , wherein the current collector is selected from the group consisting of copper; stainless steel; aluminum; nickel; titanium; sintered carbon; stainless steel whose surface is treated with carbon, nickel, titanium, or silver; and aluminum-cadmium alloy.
5. The lithium electrode according to claim 1 , wherein each lithium metal layer has a thickness of 1 to 50 μm.
6. The lithium electrode according to claim 1 , further comprising a substrate on each protective layer.
7. The lithium electrode according to claim 6 , further comprising a release layer on each substrate.
8. The lithium electrode according to claim 7 , wherein each release layer comprises at least one selected from the group consisting of a silicone-based resin, a melamine-based resin and a fluorine-based resin.
9. The lithium electrode according to claim 6 , wherein each substrate comprises at least one selected from the group consisting of polyethylene terephthalate (PET), polyimide (PI), poly(methylmethacrylate) (PMMA), cellulose tri-acetate (TAC), polypropylene, polyethylene and polycarbonate.
10. A lithium secondary battery comprising the lithium electrode according to claim 1 .
11. A method for preparing a lithium electrode comprising:
(S 1 ) forming a protective layer on at least one side of a substrate;
(S 2 ) forming a lithium metal layer on the protective layer,
wherein the protective layer comprises at least one selected from the group consisting of poly vinylidene fluoride (PVDF), poly vinylidene fluoride-hexafluoroethylene copolymer (PVDF-HFP copolymer), cyclo olefin polymer, cyclo olefin copolymer and styrene butadiene rubber-carboxymethyl cellulose (SBR-CMC); and
(S 3 ) transferring the product of (S 2 ) onto at least one side of a current collector with the lithium metal layer facing the current collector,
wherein a SiO coating layer is present on each side of the current collector, and wherein each SiO coating layer has a thickness of 60 μm to 120 μm.
12. The method according to claim 11 , further comprising removing the substrate after S 3 .
13. The lithium electrode according to claim 1 , wherein each protective layer has a thickness of 0.1 to 1 μm.