Fluids containing cellulose fibers and cellulose nanoparticles for oilfield applications
A fluid for treating a subterranean formation includes a solvent, a rheology modifier, and a composition that includes a mixture of cellulose fibers and cellulose nanoparticles. The cellulose nanoparticles have a positive zeta potential in a range of about +100 mV to about +10 mV, and a length in a range of from about 50 nm to about 500 nm, and the cellulose fibers have a length from about 50 microns to about 500 microns.
1. A fluid for treating a subterranean formation comprising:
a solvent;
a rheology modifier; and
a composition comprising a mixture of cellulose fibers and cellulose nanoparticles, wherein the cellulose nanoparticles have a positive zeta potential in a range of about +100 mV to about +10 mV, and a length in a range of from about 50 nm to about 500 nm, and wherein the cellulose fibers have a length of from about 50 microns to about 500 microns.
2. The fluid for treating the subterranean formation of claim 1 , wherein about 0.1 to about 2% by weight based on the total weight of the treatment fluid is the mixture of cellulose nanoparticles and cellulose fibers.
3. The fluid for treating the subterranean formation of claim 1 , wherein the cellulose fibers are present in an amount of from about 25% to about 50% by weight based on the total weight of the mixture of cellulose nanoparticles and cellulose fibers.
4. The fluid for treating the subterranean formation of claim 1 , wherein the cellulose nanoparticles are present in an amount of from about 50% to about 75% by weight based on the total weight of the mixture of cellulose nanoparticles and cellulose fibers.
5. The fluid for treating the subterranean formation of claim 1 , wherein at least a portion of the cellulose nanoparticles have a negative zeta potential.
6. The fluid for treating the subterranean formation of claim 5 , wherein the negative zeta potential is imparted by an anionic functional group that is present on the surface of the cellulose nanoparticles.
7. The fluid for treating the subterranean formation of claim 5 , wherein the negative zeta potential is in a range of from about −100 mV to about −10 mV.
8. The fluid for treating the subterranean formation of claim 1 , wherein each of the cellulose nanoparticles have an outer surface having a percent surface functionalization of from about 5 to about 90 percent.
9. The fluid for treating the subterranean formation of claim 8 , wherein the outer surface of each of cellulose nanoparticles comprises one or more member selected from the group consisting of sulfates, phosphates, amines, and carboxylates.
10. The fluid for treating the subterranean formation of claim 1 , wherein at least a portion of cellulose nanoparticles are a rod-like nanocrystalline cellulose particle (NCC particle) having a crystalline structure.
11. The fluid for treating the subterranean formation of claim 1 , wherein the solvent is water or brine.
12. The fluid for treating the subterranean formation of claim 1 , wherein the rheology modifier is a polymer.
13. The fluid for treating the subterranean formation of claim 1 , wherein the rheology modifier is a viscoelastic surfactant.
14. The fluid for treating the subterranean formation of claim 1 , wherein the fluid is selected from the group consisting of a fracturing fluid, well control fluid, well kill fluid, well cementing fluid, acid fracturing fluid, acid diverting fluid, a stimulation fluid, a sand control fluid, a completion fluid, a wellbore consolidation fluid, a remediation treatment fluid, a drilling fluid, a spacer fluid, a frac-packing fluid, water conformance fluid and gravel packing fluid.