Method for precisely analyzing degree of impregnation of electrolyte of electrode in cell
The present invention relates to a method for analyzing a degree of impregnation of an electrolyte of an electrode in a battery cell, the method comprising: a battery cell manufacturing step (S 1 ) of preparing a battery cell by injecting an electrolyte into a battery cell including an electrode to be evaluated; a step of charging/discharging the battery cell several times and obtaining a capacity-voltage profile for each cycle (S 2 ); a step of obtaining a differential capacity (dV/dQ) curve obtained by differentiating the capacitance-voltage profile for each cycle with respect to the capacity (S 3 ); and a step of, in the differential capacity curve, determining a cycle at which behavior becomes the same as a time point when impregnation is sufficiently performed (S 4 ).
1. A method for analyzing an electrolyte impregnation degree of an electrode in a battery cell, the method comprising:
preparing a battery cell by injecting an electrolyte into the battery cell including an electrode to be evaluated;
Charging and discharging the battery cell more than one time and obtaining a capacity-voltage profile for each cycle; obtaining a differential capacity (dV/dQ) curve generated by differentiating the capacity-voltage profile for each cycle with respect to the capacity; and determining a cycle, at which a behavior of the capacity-voltage profile becomes the same as a behavior of the capacity-voltage profile of an immediately preceding cycle, as a time point when the impregnation has been sufficiently performed in the differential capacity curve.
2. The method of claim 1 , wherein the battery cell comprises at least one selected from the group consisting of a pouch cell, a cylindrical cell, a square cell and a coin cell.
3. The method of claim 1 , wherein the battery cell comprises a half cell.
4. The method of claim 1 , wherein the battery cell comprises a full cell.
5. The method of claim 1 , wherein the electrode is a negative electrode.
6. The method of claim 5 , wherein the negative electrode includes one or two active materials selected from the group consisting of artificial graphite and natural graphite.
7. The method of claim 1 , wherein the charging and discharging is performed under a condition of C-rate of 0.1C to 0.3C.
8. The method of claim 1 , wherein the charging and discharging is performed under a condition of C-rate of 0.15C to 0.25C.
9. The method of claim 1 , wherein a number of cycles is 1 to 10.
10. The method of claim 1 , wherein a number of cycles is 3 to 7.