IP Library › Granted Patent US 11,535,773
Granted Patent B2
US 11,535,773 · App. 16/258,568 · Granted Dec 27, 2022

Coatings containing polymer modified enzyme for stable self-cleaning of organic stains

Inventors: Hongfei Jia (Ann Arbor, MI); Ping Wang (North Oaks, MN); Liting Zhang (St. Paul, MN); Andreas Buthe (Steinfurt, DE); Xueyan Zhao (Circle Pines, MN); Songtao Wu (Ann Arbor, MI); Masahiko Ishii (Okazaki, JP); Minjuan Zhang (Ann Arbor, MI)
Assignee: REGENTS OF THE UNIVERSITY OF MINNESOTA
C09D189/00A61K47/60C08G65/33337C09D5/024C09D5/16C09D7/40C09D175/16C12N9/14C12N9/20C12N9/2408C12N9/2411C12N9/54C12N9/96C12N11/06C12N11/089C08L2203/02C08L2205/02
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Quick Facts
Patent No.
US 11,535,773
App. No.
16/258,568
Granted
Dec 27, 2022
Kind
B2
Abstract

Bioactive coatings suitable for facilitating removal of a fingerprint when contacting the coating are provided including a base associated with a chemically modified enzyme, and, optionally a first polyoxyethylene present in the base and independent of the enzyme. The coatings are optionally overlayered onto a substrate. Also provided are processes of facilitating fingerprint removal.

Claims (12)

1. A process of facilitating removal of a fingerprint from a substrate or a coating comprising:

providing a base, the base comprising a first polyoxyethylene, said first polyoxyethylene independent of an enzyme, said base in the form of a continuous film, the base a two component solvent borne composition;

associating one or more polymeric moieties of a second polyoxyethylene with an enzyme to form a chemically modified enzyme;

dispersing said chemically modified enzyme in a base to form a water-stabilized active coating material, wherein said dispersing results in protein particles with an average particle diameter of less than 5 micrometers; and

facilitating removal of a fingerprint from said substrate or said coating when contacted by a fingerprint.

2. The process of claim 1 further comprising coating a substrate with said active coating material such that said enzyme is capable of enzymatically degrading a component of a fingerprint in contact with said active coating material.

3. The process of claim 1 wherein said enzyme is a lipase.

4. The process of claim 1 wherein said first polyoxyethylene has a molecular weight between 1,000 and 15,000 Daltons.

5. The process of claim 1 wherein said second polyoxyethylene has a molecular weightfrom 10,000 Daltons to 100,000 Daltons.

6. The process of claim 1 wherein said second polyoxyethylene has a molecular weight from 12,000 Daltons to 100,000 Daltons.

7. The process of claim 1 wherein the second polyoxyethylene is a branched polyoxyethylene.

8. The process of claim 7 wherein the second polyoxyethylene is an 8 - arm branched polyoxyethylene.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 18, 2020
From: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC.
To: TOYOTA MOTOR CORPORATION
Reel/Frame 052156/0494 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2019
From: JIA, HONGFEI; WU, SONGTAO; ZHANG, MINJUAN
To: TOYOTA MOTOR ENGINEERING & MANUFACTURING NORTH AMERICA, INC.
Reel/Frame 048753/0275 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2019
From: ISHII, MASAHIKO
To: TOYOTA MOTOR CORPORATION
Reel/Frame 048753/0324 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 1, 2019
From: WANG, PING; ZHANG, LITING; BUTHE, ANDREAS; ZHAO, XUEYAN
To: REGENTS OF THE UNIVERSITY OF MINNESOTA
Reel/Frame 048753/0378 →
Continuity (3)
Continuation 14812087 · Jul 29, 2015
Continuation 13229277 · Sep 9, 2011
Related Publication 20190144711A1 · May 16, 2019
Cited By (1)
US 12,221,593