Negative electrode for lithium secondary battery and manufacturing method thereof
A negative electrode for a lithium secondary battery, where the negative electrode includes a negative electrode current collector, a negative electrode active material layer, a lithium layer that is positioned between the negative electrode current collector and the negative electrode active material layer, and a primer layer that is positioned between the negative electrode current collector and the lithium layer, and a manufacturing method thereof. This results in a simple method and a negative electrode with high capacity characteristics.
1. A negative electrode for a lithium secondary battery, comprising:
a negative electrode current collector;
a negative electrode active material layer;
a lithium layer positioned between the negative electrode current collector and the negative electrode active material layer; and
a primer layer positioned between the negative electrode current collector and the lithium layer,
wherein the primer layer comprises graphene and an epoxy polymer, and
wherein a thickness of the primer layer is from 0.1 μm to 10 μm.
2. The negative electrode for the lithium secondary battery of claim 1 , wherein the negative electrode active material layer comprises one or more selected from the group consisting of Si, particles of silicon oxide (SiO x , 0<x≤2), and a Si-metal alloy.
3. The negative electrode for the lithium secondary battery of claim 1 , wherein the negative electrode active material layer is a free-standing negative electrode active material layer.
4. The negative electrode for the lithium secondary battery of claim 1 , wherein the lithium layer is a lithium metal foil or a lithium deposition layer.
5. The negative electrode for the lithium secondary battery of claim 1 , wherein the lithium layer has a thickness of 0.1 μm to 20 μm.
6. The negative electrode for the lithium secondary battery of claim 1 , wherein a width of the lithium layer is 1% to 100% of a width of the negative electrode current collector.
7. A negative electrode for a lithium secondary battery, comprising:
a negative electrode current collector;
a primer layer positioned on the negative electrode current collector; and
a negative electrode active material layer positioned on the primer layer,
wherein the negative electrode active material layer comprises a lithium ion diffused through pre-lithiation,
wherein the primer layer comprises graphene and an epoxy polymer, and
wherein a thickness of the primer layer is from 0.1 μm to 10 μm.
8. A lithium secondary battery, comprising the negative electrode for the lithium secondary battery according to claim 7 .
9. A method of manufacturing the negative electrode for the lithium secondary battery according to claim 1 , the method comprising:
(1) forming the a primer layer on the negative electrode current collector,
wherein the primer layer comprises graphene and an epoxy polymer;
(2) forming the lithium layer on the primer layer; and
(3) adhering the negative electrode active material layer on the lithium layer,
wherein the negative electrode active material layer is a free-standing negative electrode active material layer.
10. The method of claim 9 , wherein the free-standing negative electrode active material layer is formed by:
(a) dispersing a conductive material, a negative electrode active material, and a thermoplastic polymer to prepare a dispersed mixture;
(b) heating the dispersed mixture to a glass transition temperature (Tg) of the thermoplastic polymer; and
(c) passing the heated dispersed mixture between rollers heated to the glass transition temperature (Tg) of the thermoplastic polymer and then cooling to prepare the free-standing negative electrode active material layer as a film.
11. The method of claim 10 , wherein the thermoplastic polymer comprises one or more selected from the group consisting of ethyl vinyl acetate, nylon, polypropylene, polyethylene, polyethylene oxide, polytetrafluoroethylene (PTFE), and polyvinylidene fluoride (PVdF).
12. The method of claim 9 , wherein the free-standing negative electrode active material layer is formed by:
(a) dispersing a conductive material, a negative electrode active material, and a thermoplastic polymer to prepare a dispersed mixture;
(b) heating the dispersed mixture; and
(c) passing the heated dispersed mixture between heated rollers and then cooling to prepare the free-standing negative electrode active material layer as a film.
13. The negative electrode for the lithium secondary battery of claim 1 , wherein the thickness of the primer layer is from 2 μm to 6 μm.
14. The negative electrode for the lithium secondary battery of claim 7 , wherein the thickness of the primer layer is from 2 μm to 6 μm.