Pre-lithiation method for lithium secondary battery anode, anode intermediate, and lithium secondary battery comprising anode
Disclosed is a pre-lithiation method of a negative electrode for a lithium secondary battery, a negative electrode intermediate, and a lithium secondary battery including a negative electrode.
1 . A pre-lithiation method of a negative electrode for a lithium secondary battery, the pre-lithiation method comprising:
forming a negative electrode active material layer on one surface or both surfaces of a negative electrode current collector layer; and
transferring lithium metal onto the negative electrode active material layer,
wherein the transferring of the lithium metal comprises:
providing a base layer and pretreating one surface of the base layer in a form of a pattern,
forming a transfer laminate by sequentially laminating a release layer and a lithium metal on top of the pretreated one surface of the base layer,
laminating the transfer laminate on the negative electrode active material layer such that a surface of the lithium metal opposite to a surface of the lithium metal in contact with the release layer comes into contact with a surface of the negative electrode active material layer opposite to a surface in contact with the negative electrode current collector layer, and
removing the base layer,
wherein the lithium metal and the negative electrode active material layer satisfy Equation 1 below,
X
≤
X
1
,
[
Equation
1
]
in Equation 1,
X refers to a width of the lithium metal, and
X1 refers to a width of the negative electrode active material layer, and
wherein a width of the release layer satisfies Equation 2 below,
X
<
width
of
release
layer
<
Y
,
[
Equation
2
]
in Equation 2, X refers to the width of the lithium metal, and Y refers to a width of the negative electrode current collector layer.
2 . The pre-lithiation method of claim 1 , wherein the pretreating comprises performing corona or plasma treatment, and
wherein with respect to a surface where the base layer and the release layer are in contact, an adhesive force of the pretreated surface is 4B or greater in a cross-cut evaluation standard according to ASTM3359, and an adhesive force of the not-pretreated surface is 1B or lower in the cross-cut evaluation standard.
3 . The pre-lithiation method of claim 1 , wherein the forming of the negative electrode active material layer on one surface or both surfaces of the negative electrode current collector layer comprises coating a negative electrode slurry comprising a negative electrode active material layer composition on one surface or both surfaces of the negative electrode current collector layer, and
wherein the negative electrode active material layer composition comprises one or more selected from the group consisting of a silicon-containing active material, a negative electrode conductive material, and a negative electrode binder.
4 . The pre-lithiation method of claim 3 , wherein the silicon-containing active material comprises one or more selected from the group consisting of SiOx (x=0), SiOx (0<x<2), SiC, and a Si alloy.
5 . The pre-lithiation method of claim 3 , wherein the silicon-containing active material comprises one or more selected from the group consisting of SiOx (x=0) and SiOx (0<x<2), and comprises the SiOx (x=0) in an amount of 70 parts by weight or more on a basis of 100 parts by weight of the silicon-containing active material.
6 . The pre-lithiation method of claim 1 , wherein a thickness of the lithium metal is 1 μm or greater and 10 μm or less.
7 . The pre-lithiation method of claim 1 , wherein the release layer comprises one or more selected from the group consisting of silicon-modified polyester in which a silicon chain is graft-linked to a polyester main chain, an acrylic resin, Si, melamine, and fluorine.