IP Library Granted Patent US 11,600,621
Granted Patent B2
US 11,600,621 · App. 17/412,801 · Granted Mar 7, 2023

Semiconductor memory device and method of fabricating the same

Inventors: Kyooho Jung (Seoul, KR); Younsoo Kim (Yongin-si, KR); Young-lim Park (Anyang-si, KR); Jeong-Gyu Song (Seongnam-si, KR); Se Hyoung Ahn (Seoul, KR); Changmu An (Osan-si, KR)
Assignee: Samsung Electronics Co., Ltd.
H01L27/10814H01L21/02194H01L27/10823H01L27/10855H01L27/10876H01L28/60H01L21/02181H01L21/02186H01L21/02189
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Quick Facts
Patent No.
US 11,600,621
App. No.
17/412,801
Granted
Mar 7, 2023
Kind
B2
Abstract

Disclosed are semiconductor memory devices and methods of fabricating the same. The semiconductor memory device comprises a capacitor that includes a bottom electrode, a top electrode opposite to the bottom electrode across a dielectric layer, and an interface layer between the bottom electrode and the dielectric layer. The interface layer includes a combination of niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N), and further includes a constituent of the dielectric layer.

Claims (45)

1. A semiconductor memory device comprising:

a substrate;

a capacitor bottom electrode disposed over the substrate and including titanium nitride;

a first interface layer disposed on the capacitor bottom electrode;

a capacitor dielectric layer disposed on the first interface layer and including hafnium oxide; and

a capacitor top electrode disposed on the capacitor dielectric layer,

wherein the first interface layer includes a combination of hafnium (Hf), niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N).

2. The semiconductor memory device of claim 1 , wherein the first interface layer includes HfNbTiON.

3. The semiconductor memory device of claim 1 , further comprises a second interface layer that is disposed between the capacitor dielectric layer and the capacitor top electrode.

4. The semiconductor memory device of claim 3 , wherein the second interface layer includes a combination of titanium (Ti), oxygen (O), and nitrogen (N).

5. The semiconductor memory device of claim 3 , wherein the second interface layer includes a combination of niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N).

6. The semiconductor memory device of claim 5 , wherein niobium (Nb) contained in the second interface layer has an amount of about 5 at % or less, narrowly about 2 at % to about 3 at %.

7. The semiconductor memory device of claim 3 , wherein the second interface layer includes a combination of niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N), and a metallic constituent of the capacitor dielectric layer.

8. The semiconductor memory device of claim 1 , wherein niobium (Nb) contained in the first interface layer has an amount of about 5 at % or less, narrowly about 2 at % to about 3 at %.

9. The semiconductor memory device of claim 1 , wherein the capacitor top electrode includes titanium nitride.

10. The semiconductor memory device of claim 1 , wherein the capacitor dielectric layer includes zirconium oxide.

11. The semiconductor memory device of claim 1 , further comprises a support pattern that contacts a side surface of the capacitor bottom electrode, and

wherein the first interface layer is spaced apart from the side surface of the capacitor bottom electrode.

12. A semiconductor memory device comprising:

a substrate;

a capacitor bottom electrode disposed over the substrate and including titanium nitride;

a first interface layer disposed on the capacitor bottom electrode;

a capacitor dielectric layer disposed on the first interface layer and including hafnium oxide and zirconium oxide;

a second interface layer disposed on the capacitor dielectric layer; and

a capacitor top electrode disposed on the second interface layer and including titanium nitride,

wherein the first interface layer includes a combination of hafnium (Hf), niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N), and

the second interface layer includes a combination of titanium (Ti), oxygen (O), and nitrogen (N).

13. The semiconductor memory device of claim 12 , wherein the first interface layer includes HfNbTiON.

14. The semiconductor memory device of claim 12 , wherein niobium (Nb) contained in the first interface layer has an amount of about 5 at % or less, narrowly about 2 at % to about 3 at %.

15. The semiconductor memory device of claim 12 , further comprises a support pattern that contacts a side surface of the capacitor bottom electrode, and

wherein the first interface layer is spaced apart from the side surface of the capacitor bottom electrode.

16. A semiconductor memory device comprising:

a substrate;

a capacitor bottom electrode disposed over the substrate and including titanium nitride;

a first interface layer disposed on the capacitor bottom electrode;

a capacitor dielectric layer disposed on the first interface layer and including hafnium oxide and zirconium oxide;

a second interface layer disposed on the capacitor dielectric layer; and

a capacitor top electrode disposed on the second interface layer and including titanium nitride,

wherein the first interface layer includes a combination of hafnium (Hf), niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N), and

the second interface layer includes a combination of niobium (Nb), titanium (Ti), oxygen (O), and nitrogen (N).

17. The semiconductor memory device of claim 16 , wherein the first interface layer includes HfNbTiON.

18. The semiconductor memory device of claim 16 , wherein niobium (Nb) contained in the first interface layer has an amount of about 5 at % or less, narrowly about 2 at % to about 3 at %.

19. The semiconductor memory device of claim 16 , wherein niobium (Nb) contained in the second interface layer has an amount of about 5 at % or less, narrowly about 2 at % to about 3 at %.

20. The semiconductor memory device of claim 16 , further comprises a support pattern that contacts a side surface of the capacitor bottom electrode, and

wherein the first interface layer is spaced apart from the side surface of the capacitor bottom electrode.

Priority Claims (1)
KR 10-2019-0138586 · Nov 1, 2019 · national
Continuity (2)
Continuation 16897589 · Jun 10, 2020
Related Publication 20210391333A1 · Dec 16, 2021