Electrolyte for lithium-sulfur battery and lithium-sulfur battery comprising same
Discussed is an electrolyte solution for a lithium-sulfur battery including a lithium salt, an organic solvent and an additive, and a lithium-sulfur battery including the same, wherein the additive includes a heterocyclic compound containing at least one double bond, and a heterocycle of the heterocyclic compound comprises an oxygen atom or a sulfur atom.
1. An electrolyte solution for a lithium-sulfur battery comprising:
a lithium salt;
an organic solvent; and
an additive,
wherein the additive comprises a heterocyclic compound containing at least one double bond, where the heterocycle further comprises an oxygen atom or a sulfur atom,
wherein the additive comprises a heterocyclic compound comprising at least one selected from the group consisting of furan, 2-methylfuran, 3-methylfuran, 2-ethylfuran, 2-propylfuran, 2-butylfuran, 2,3 dimethylfuran, 2,4-dimethylfuran, 2,5-dimethylfuran, pyran, 2-methylpyran, 3-methylpyran, 4-methylpyran, benzofuran, 2-(2-nitrovinyl)furan, thiophene, 2-methylthiophene, 2-ethylthiophene, 2-propylthiophene, 2-butylthiophene, 2,3-dimethylthiophene, 2,4-dimethylthiophene, and 2,5-dimethylthiophene, and
wherein the heterocyclic compound is present in an amount of 23.1 to 38% by weight relative to the total weight of the electrolyte solution for the lithium-sulfur battery.
2. The electrolyte solution for the lithium-sulfur battery according to claim 1 , wherein the heterocyclic compound is present in an amount of 23.1 to 30% by weight relative to the total weight of the electrolyte solution for the lithium-sulfur battery.
3. The electrolyte solution for the lithium-sulfur battery according to claim 1 , wherein when present in the lithium-sulfur battery, the additive forms a polymer protective film on a surface of a negative electrode by a ring-opening polymerization reaction.
4. The electrolyte solution for the lithium-sulfur battery according to claim 1 , wherein the lithium salt comprises at least one selected from the group consisting of LiCl, LiBr, LiI, LiClO 4 , LiBF 4 , LiB 10 Cl 10 , LiPF 6 , LiCF 3 SO 3 , LiCF 3 CO 2 , LiC 4 BO 8 , LiAsF 6 , LiSbF 6 , LiAlCl 4 , CH 3 SO 3 Li, CF 3 SO 3 Li, (CF 3 SO 2 ) 2 NLi, (C 2 F 5 SO 2 ) 2 NLi, (SO 2 F) 2 NLi, (CF 3 SO 2 ) 3 CLi, lithium chloroborane, lithium lower aliphatic carboxylate, lithium tetraphenyl borate and lithium imide.
5. The electrolyte solution for the lithium-sulfur battery according to claim 1 , wherein the lithium salt is present at a concentration of 0.1 M to 4 M.
6. A lithium-sulfur battery comprising a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; and an electrolyte solution, wherein the negative electrode comprises a lithium-based metal, and the electrolyte solution is the electrolyte solution of claim 1 .
7. The lithium-sulfur battery according to claim 6 , wherein a polymer protective film is formed on a surface of the lithium-based metal by a ring-opening polymerization reaction of the heterocyclic compound contained in the electrolyte solution in an initial discharging stage of the lithium-sulfur battery.