3D printing using phase changing materials as support
A method or apparatus for three-dimensionally printing. The method may comprise causing a phase change in a region of the first material by applying focused energy to the region using a focused energy source, and displacing the first material with a second material. The apparatus may comprise a container configured to hold a first material, a focused energy source configured to cause a phase change in a region of the first material by applying focused energy to the region, and an injector configured to displace the first material with a second material. The first material may comprise a yield stress material, which is a material exhibiting Herschel-Bulkley behavior. The yield stress material may comprise a soft granular gel. The second material may comprise one or more cells.
1. A method for creating a three-dimensional structure within a first material, the method comprising:
causing a phase change in a region of the first material by applying focused energy to the region using a focused energy source; and
displacing the first material in the region with a second material,
wherein the first material is a Herschel-Bulkley material having a yield stress less than 100 Pascals, and
wherein the first material comprises a soft granular gel made from polymeric packed micro-particles.
2. The method of claim 1 , wherein the focused energy source is configured to cause a reverse phase change in the region of the first material.
3. The method of claim 1 , wherein the polymeric packed micro-particles are between 0.1 and 100 micrometers in diameter.
4. The method of claim 1 , wherein the polymeric packed micro-particles are at a concentration by weight in the soft granular gel of less than 2%.
5. The method of claim 1 , wherein the first material comprises a hydrogel.
6. The method of claim 5 , wherein the hydrogel comprises crosslinked polymers of acrylic acid.
7. The method of claim 5 , wherein the hydrogel comprises a polyelectrolytic microgel.
8. The method of claim 1 , wherein the first material comprises a silicone elastomer dispersion.
9. The method of claim 8 , wherein the silicone elastomer dispersion comprises a silicone elastomer dispersed in PDMS.
10. The method of claim 1 , wherein a shear stress of the first material is independent of shear rate at a shear rate of 10 −3 s −1 .
11. The method of claim 1 , wherein the yield stress of the first material is below a hydrostatic pressure of the first material.
12. The method of claim 1 , wherein the first material has a thixotropic time between 0.25 seconds and 2.5 seconds.
13. The method of claim 1 , wherein the first material has a thixotropic index between 4 and 7.
14. The method of claim 1 , wherein the first material and the second material are miscible.
15. The method of claim 1 , wherein the displacing comprises:
injecting, with an injector, the second material into the first material; and
over time, relatively displacing the first material with respect to the injector.
16. The method of claim 15 , wherein the relatively displacing the first material with respect to the injector comprises relative rotation of the first material with respect to the injector.
17. The method of claim 1 , wherein the displacing comprises, over time, relatively displacing a focus point of the focused energy source with respect to the first material.
18. The method of claim 17 , wherein:
the displacing further comprises injecting, with an injector, the second material into the first material and moving the injector over time; and
the relatively displacing comprises synchronizing motion of the injector with the relatively displacing of the focus point of the focused energy source.