Shape-forming packaging material, and method for producing power storage device with surface printing
The shape-forming packaging material is a shape-forming packaging material including a heat resistant resin layer as an outer layer, a heat fusible resin layer as an inner layer, and a metal foil layer disposed between both the layers, and is configured such that a print improving resin layer is laminated on a further outer side of the heat resistant resin layer.
1. A shape-forming packaging material comprising:
a heat resistant resin layer as an outer layer;
a heat fusible resin layer as an inner layer; and
a metal foil layer disposed between the heat resistant resin layer and the heat fusible resin layer,
wherein a print improving resin layer is laminated on an outer side of the heat resistant resin layer opposite the metal foil layer, the print improving resin layer includes a formation amount of between 0.01 g/m 2 and 0.5 g/m 2 ,
wherein a lubricant is exuded to an outer surface of the heat fusible resin layer, the lubricant then is adhered without lamination to an outer surface of the print improving resin layer wherein an adhesion amount of the lubricant on the outer surface of the print improving resin layer is 0.1 mg/m 2 to 2.5 mg/m 2 and wherein the adhesion amount of lubricant on the outer surface of the printing improving resin layer is smaller than the adhesion amount of the lubricant on the outer surface of the heat-fusible resin layer, and
wherein the print improving resin layer is a single layer that is an outermost layer of the packaging material.
2. The shape-forming packaging material as recited in claim 1 , wherein
the print improving resin layer contains one or more resins selected from the group consisting of an epoxy resin, a urethane resin, an acrylic acid resin, a methacrylic acid resin, an acrylic acid ester resin, a methacrylic acid ester resin, a polyester resin, and a polyethyleneimine resin.
3. The shape-forming packaging material as recited in claim 1 , wherein
the print improving resin layer contains a urethane resin and an epoxy resin.
4. The shape-forming packaging material as recited in claim 3 , wherein
in the print improving resin layer, a content mass ratio of the urethane resin/the epoxy resin is in a range of 98/2 to 40/60.
5. The shape-forming packaging material as recited in claim 1 , wherein
the print improving resin layer contains one or more acrylic resins selected from the group consisting of an acrylic acid ester resin and a methacrylic acid ester resin, and an epoxy resin.
6. The shape-forming packaging material as recited in claim 5 , wherein
in the print improving resin layer, a content mass ratio of the acrylic resin/the epoxy resin is in a range of 98/2 to 40/60.
7. The shape-forming packaging material as recited in claim 1 , wherein
the heat resistant resin layer is composed of a biaxially stretched polyamide film, a biaxially stretched polyethylene naphthalate film, a biaxially stretched polyethylene terephthalate film, or a biaxially stretched polybutylene terephthalate film.
8. A method for producing a shaped case, comprising:
deep drawing or stretch forming the shape-forming packaging material as recited in claim 1 .
9. A method for producing a battery case, comprising:
deep drawing or stretch forming the shape-forming packaging material as recited in claim 1 .
10. A method for producing a power storage device with surface printing, comprising:
obtaining a roll body by rolling the shape-forming packaging material containing the lubricant in the heat fusible resin layer as recited in claim 1 in a manner such that the heat fusible resin layer and the print improving resin layer are in contact with each other;
obtaining a power storage device by unrolling the shape-forming packaging material from the roll body and packaging a power storage device main body with the unrolled shape-forming packaging material; and
printing on the outer surface of the print improving resin layer of the shape-forming packaging material in a state in which the power storage device is packaged.
11. The method for producing a power storage device with surface printing as recited in claim 10 , wherein
the lubricant is adhered to the outer surface of the print improving resin layer of the shape-forming packaging material unrolled from the roll body, and
the lubricant on the outer surface of the print improving resin layer is a lubricant presented on a surface of the heat fusible resin layer and transferred to the outer surface of the print improving resin layer when rolled, and
printing is performed on the outer surface of the print improving resin layer to which the lubricant is adhered.
12. A shape-forming packaging material comprising:
a heat resistant resin layer as an outer layer;
a heat fusible resin layer as an inner layer; and
a metal foil layer disposed between the heat resistant resin layer and the heat fusible resin layer,
a print improving resin layer is laminated on an outer side of the heat resistant resin layer, wherein the print improving resin layer is positioned opposite the metal foil layer, the print improving resin layer includes a formation amount of between 0.01 g/m 2 and 0.5 g/m 2 ; wherein
an adhesion amount of the lubricant on the outer surface of the print improving resin layer is 0.1 mg/m 2 to 2.5 mg/m 2
an adhesive layer applied to an inner side of the heat resistant resin layer; and
wherein the print improving resin layer is a single layer that is an outermost layer of the packaging material.
13. The shape-forming packaging material of claim 12 wherein the adhesion amount of lubricant on the outer surface of the printing improving resin layer is smaller than the adhesion amount of the lubricant on the outer surface of the heat-fusible resin layer.