Positive-electrode active material for non-aqueous electrolyte secondary battery and method of producing the same
A method of producing a positive-electrode active material for a non-aqueous electrolyte secondary battery is provided. The method includes obtaining a precipitate containing nickel and manganese from a solution containing nickel and manganese, heat-treating the resulting precipitate at a temperature of from 850° C. to less than 1100° C. to obtain a first heat-treated product, mixing the first heat-treated product and a lithium compound, and heat-treating the resulting lithium-containing mixture at a temperature of from 550° C. to 1000° C. to obtain a second heat-treated product. The second heat-treated product contains a group of lithium transition metal composite oxide particles having an average particle diameter D SEM of from 0.5 μm to less than 3 μm and D 50 /D SEM of 1 to 2.5. The lithium transition metal composite oxide particles have a spinel structure based on nickel and manganese.
1. A positive-electrode active material for a non-aqueous electrolyte secondary battery, comprising:
lithium transition metal composite oxide particles having an average particle diameter based on SEM observation D SEM that is from 0.5 μm to less than 3 μm, and a ratio D 50 /D SEM that is from 1.6 to 2.1 where D 50 is a particle diameter corresponding to 50% in its volume-based cumulative particle size distribution,
wherein the lithium transition metal composite oxide particles have a spinel structure based on nickel and manganese,
wherein the lithium transition metal composite oxide particles contain lithium transition metal composite oxide particles onto surfaces of which a substance containing niobium is adhered,
wherein the lithium transition metal composite oxide particles have a ratio D 95 /D 5 that is from 2.5 to 3.8, and
wherein the lithium transition metal composite oxide particles have a ratio D 90 /D 10 that is from 2.0 to 2.5.
2. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the lithium transition metal composite oxide particles comprises lithium transition metal composite oxide represented by the formula:
Li x Ni p Mn q M 1 r O 4
wherein x, p, q, and r satisfy 1≤x≤1.3, 0.3≤p≤0.6, 1.2≤q≤1.7, 0≤r≤0.2, and p+q+r≤2, and M 1 is at least one selected from the group consisting of Al, Mg, Si, Ti, Cr, Fe, Co, Cu, Zn, Ga, and Nb.
3. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the D SEM of the lithium transition metal composite oxide particles is from 0.7 μm to 2.5 μm.
4. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the D SEM of the lithium transition metal composite oxide particles is from 1 μm to 2 μm.
5. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the ratio D 90 /D 10 of the lithium transition metal composite oxide particles is from 2.0 to 2.3.
6. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the ratio D 95 /D 5 of the lithium transition metal composite oxide particles is from 2.5 to 3.
7. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 , wherein the D SEM of the lithium transition metal composite oxide particles is from 1 μm to less than 2 μm.
8. The positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 7 , wherein the lithium transition metal composite oxide particles comprises lithium transition metal composite oxide represented by the formula:
Li x Ni p Mn q M 1 r O 4
wherein x, p, q, and r satisfy 1≤x≤1.3, 0.3≤p≤0.6, 1.2≤q≤1.7, 0≤r≤0.2, and p+q+r≤2, and M 1 is at least one selected from the group consisting of Al, Mg, Si, Ti, Cr, Fe, Co, Cu, Zn, Ga, and Nb.
9. A electrode for a non-aqueous electrolyte secondary battery, comprising:
a current collector,
positive electrode active material layer containing the positive-electrode active material for a non-aqueous electrolyte secondary battery according to claim 1 on the current collector.
10. A non-aqueous electrolyte secondary battery, comprising:
the positive electrode for a non-aqueous electrolyte secondary battery according to claim 9 ,
a negative electrode for a non-aqueous electrolyte secondary battery,
a non-aqueous electrolyte, and
a separator.