Optically clear adhesives containing a trialkyl borane complex initiator and photoacid

1. An optically clear adhesive composition comprising:

a free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a trialkyl borane-amine complex initiator, wherein the amine is decomplexed by reaction with a superacid to initiate polymerization of the free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a photoacid generator that generates a superacid upon exposure to actinic radiation; and

a photosensitizer wherein the photosensitizer absorbs light and transfers energy or an electron to the photoacid generator,

wherein the photosensitizer is a benzoin ether,

wherein a viscosity of the composition immediately after mixing and a viscosity of the composition about 24 hours after mixing changes by less than about 10%.

2. The optically clear adhesive composition of claim 1 , wherein the optically clear adhesive composition is one of a liquid optically clear adhesive and a post-UV curable optically clear adhesive film.

3. The optically clear adhesive composition of claim 1 , wherein the photoacid generator generates a superacid upon exposure to actinic radiation.

4. The optically clear adhesive composition of claim 1 , wherein the photoacid generator comprises one of diaryliodonium salts, triarylsulfonium salts, dialkylphenacylsulfonium salts, and dialkyl-4-hydroxyphenylsulfonium salts.

5. The optically clear adhesive composition of claim 1 , wherein the optically clear adhesive composition comprises between about 0.01 wt % and about 10 wt % trialkyl borane complex initiator.

6. The optically clear adhesive composition of claim 1 , wherein the optically clear adhesive composition comprises between about 0.01 wt % and about 10 wt % photoacid generator.

7. The optically clear adhesive composition of claim 1 , wherein the optically clear adhesive composition comprises between about 0.01 wt % and about 5 wt % photosensitizer.

8. The optically clear adhesive composition of claim 1 , wherein the optically clear adhesive composition is a one-part system.

9. The optically clear adhesive composition of claim 1 , wherein the composition comprises less than about 5% monomer.

10. The optically clear adhesive composition of claim 1 , wherein the composition comprises less than about 5% low molecular weight reactive species.

11. The optically clear adhesive composition of claim 1 , wherein when the optically clear adhesive composition is placed between two substrates and made into a laminate,

wherein at least one of the substrates is transparent, the laminate has a haze of less than about 5%, a transmission of greater than about 80%, and an optical clarity of greater than about 95% when cured.

12. A method of curing under an ink step, the method comprising:

positioning an optically clear adhesive composition at least partially beneath the ink step, wherein the optically clear adhesive composition comprises:

a free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a trialkyl borane-amine complex initiator, wherein the amine is decomplexed by reaction with a superacid to initiate polymerization of the free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a photoacid generator that generates a superacid upon exposure to actinic radiation; and

a photosensitizer wherein the photosensitizer absorbs light and transfers energy or an electron to the photoacid generator,

wherein the photosensitizer is a benzoin ether,

wherein a viscosity of the composition immediately after mixing and a viscosity of the composition about 24 hours after mixing changes by less than about 10%; and

exposing the optically clear adhesive composition to actinic radiation to cure the optically clear adhesive composition under the ink step.

13. The method of claim 12 , wherein exposing the optically clear adhesive composition to actinic radiation generates a superacid.

14. The method of claim 12 , wherein the photoacid generator comprises one of iodonium salts, diaryliodonium salts, triarylsulfonium salts, dialkylphenacylsulfonium salts, and dialkyl-4-hydroxyphenylsulfonium salts.

15. The method of claim 12 , wherein the composition is substantially free of monomer and low molecular weight reactive species.

16. A laminate comprising:

a first substrate;

a second substrate; and

an optically clear adhesive composition positioned between and in contact with the first substrate and the second substrate, wherein the optically clear adhesive layer is derived from precursors that comprise:

a free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a trialkyl borane-amine complex initiator, wherein the amine is decomplexed by reaction with a superacid to initiate polymerization of the free-radically polymerizable acrylate or meth(acrylate) functional acrylic oligomer;

a photoacid generator that generates a superacid upon exposure to actinic radiation; and

a photosensitizer wherein the photosensitizer absorbs light and transfers energy or an electron to the photoacid generator,

wherein the photosensitizer is a benzoin ether,

wherein a viscosity of the composition immediately after mixing and a viscosity of the composition about 24 hours after mixing changes by less than about 10%.

17. The laminate of claim 16 , wherein at least one of the first and second substrates is optically clear.

18. The laminate of claim 16 , wherein exposing the optically clear adhesive composition to actinic radiation generates a superacid.

19. The laminate of claim 16 , wherein the laminate has a haze of less than about 5%, a transmission of greater than about 80%, and optical clarity of greater than about 95% when cured.