IP Library › Granted Patent US 11,871,592
Granted Patent B2
US 11,871,592 · App. 17/221,969 · Granted Jan 9, 2024

Light-emitting element

Inventors: Satoshi Seo (Kanagawa, JP); Satoko Shitagaki (Kanagawa, JP); Nobuharu Ohsawa (Kanagawa, JP); Hideko Inoue (Kanagawa, JP); Kunihiko Suzuki (Kanagawa, JP)
Assignee: Semiconductor Energy Laboratory Co., Ltd.
H10K50/121C07D409/10C09K11/06H05B33/14H10K50/11H10K85/6572H10K85/6576C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1044C09K2211/1088C09K2211/1092C09K2211/185H10K85/342H10K85/624H10K85/626H10K85/631H10K85/633H10K85/636H10K2101/10
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Quick Facts
Patent No.
US 11,871,592
App. No.
17/221,969
Granted
Jan 9, 2024
Kind
B2
Abstract

Provided is a light-emitting element which includes a light-emitting layer containing a phosphorescent compound, a first organic compound, and a second organic compound between a pair of electrodes. A combination of the first organic compound and the second organic compound forms an exciplex (excited complex). An emission spectrum of the exciplex overlaps with an absorption band located on the longest wavelength side of an absorption spectrum of the phosphorescent compound. A peak wavelength of the emission spectrum of the exciplex is longer than or equal to a peak wavelength of the absorption band located on the longest wavelength side of the absorption spectrum of the phosphorescent compound.

Claims (44)

1. A light-emitting element comprising:

a pair of electrodes,

a light-emitting layer between the pair of electrodes,

wherein the light-emitting layer comprises an iridium complex, a first organic compound, and a second organic compound,

wherein the first organic compound is a heteroaromatic compound,

wherein the second organic compound is an aromatic amine compound or a carbazole compound,

wherein the first organic compound and the second organic compound form an exciplex,

wherein an emission spectrum of the exciplex overlaps with an absorption band on the longest wavelength side of an absorption spectrum of the iridium complex, and

wherein an emission peak wavelength of the exciplex is longer than or equal to the peak wavelength of the absorption band on a longest wavelength side of the absorption spectrum of the iridium complex.

2. The light-emitting element according to claim 1 , wherein a difference between the emission peak wavelength of the exciplex and an emission peak wave-length of the iridium complex is 30 nm or less.

3. The light-emitting element according to claim 1 , wherein the absorption band corresponds to a direct transition from a singlet ground state to a triplet excitation state of the iridium complex.

4. The light-emitting element according to claim 1 , wherein the absorption band includes an absorption on the basis of a triplet MLCT transition of the iridium complex.

5. The light-emitting element according to claim 1 , wherein a triplet excitation energy level of each of the first and second organic compounds is higher than a triplet excitation energy level of the iridium complex.

6. The light-emitting element according to claim 1 , wherein the first organic compound and the second organic compound are fluorescent compounds.

7. A light-emitting device comprising the light-emitting element according to claim 1 .

8. A light-emitting element comprising:

a pair of electrodes,

a light-emitting layer between the pair of electrodes,

wherein the light-emitting layer comprises an iridium complex, a first organic compound, and a second organic compound,

wherein the first organic compound is a heteroaromatic compound,

wherein the second organic compound is an aromatic amine compound or a carbazole compound,

wherein the first organic compound and the second organic compound form an exciplex,

wherein an emission spectrum of the exciplex overlaps with an absorption band on a longest wavelength side of an absorption spectrum of the iridium complex, and

wherein a difference between an emission peak wavelength of the exciplex and an emission peak wavelength of the iridium complex is 30 nm or less.

9. The light-emitting element according to claim 8 , wherein the absorption band corresponds to a direct transition from a singlet ground state to a triplet excitation state of the iridium complex.

10. The light-emitting element according to claim 8 , wherein the absorption band includes an absorption on the basis of a triplet MLCT transition of the iridium complex.

11. The light-emitting element according to claim 8 , wherein a triplet excitation energy level of each of the first and second organic compounds is higher than a triplet excitation energy level of the iridium complex.

12. The light-emitting element according to claim 8 , wherein the first organic compound and the second organic compound are fluorescent compounds.

13. A light-emitting device comprising the light-emitting element according to claim 8 .

14. A light-emitting element comprising:

a pair of electrodes,

a light-emitting layer between the pair of electrodes,

wherein the light-emitting layer comprises an iridium complex, a first organic compound, and a second organic compound,

wherein the first organic compound is a heteroaromatic compound,

wherein the second organic compound is an aromatic amine compound or a carbazole compound,

wherein the first organic compound and the second organic compound form an exciplex,

wherein an emission spectrum of the exciplex overlaps with an absorption band on a longest wavelength side of an absorption spectrum of the iridium complex, and

wherein an emission peak wavelength of the exciplex is longer than or equal to the peak wavelength of the absorption band on the longest wavelength side of the absorption spectrum of the iridium complex and shorter than or equal to an emission peak wavelength of the iridium complex.

15. The light-emitting element according to claim 14 , wherein a difference between the emission peak wavelength of the exciplex and the emission peak wavelength of the iridium complex is 30 nm or less.

16. The light-emitting element according to claim 14 , wherein the absorption band corresponds to a direct transition from a singlet ground state to a triplet excitation state of the iridium complex.

17. The light-emitting element according to claim 14 , wherein the absorption band includes an absorption on the basis of a triplet MLCT transition of the iridium complex.

18. The light-emitting element according to claim 14 , wherein a triplet excitation energy level of each of the first and second organic compounds is higher than a triplet excitation energy level of the iridium complex.

19. The light-emitting element according to claim 14 , wherein the first organic compound and the second organic compound are fluorescent compounds.

20. A light-emitting device comprising the light-emitting element according to claim 14 .

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 5, 2021
From: SEO, SATOSHI; SHITAGAKI, SATOKO; OHSAWA, NOBUHARU; INOUE, HIDEKO; SUZUKI, KUNIHIKO
To: SEMICONDUCTOR ENERGY LABORATORY CO., LTD.
Reel/Frame 055821/0023 →
Priority Claims (1)
JP 2011-064553 · Mar 23, 2011 · national
Continuity (5)
Continuation 16271945 · Feb 11, 2019
Continuation 15492439 · Apr 20, 2017
Continuation 14924054 · Oct 27, 2015
Continuation 13419892 · Mar 14, 2012
Related Publication 20210226146A1 · Jul 22, 2021
Cited By (1)
US 12,672,453