IP Library Granted Patent US 11,894,530
Granted Patent B2
US 11,894,530 · App. 18/131,637 · Granted Feb 6, 2024

Methods and systems for scalable direct recycling of batteries

Inventors: David Young (Sudbury, MA); Zheng W. Li (Blacksburg, VA); Michael W. Ellis (Blacksburg, VA); Nolan D. Schmidt (Pembroke, VA); Xu Han (Merion Station, PA)
Assignee: Li Industries, Inc.
H01M10/54H01M10/0525
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Quick Facts
Patent No.
US 11,894,530
App. No.
18/131,637
Granted
Feb 6, 2024
Kind
B2
Abstract

A method includes processing at least one battery into a plurality of core sections. Each core section in the plurality of core sections includes an anode section, a cathode section including a cathode material, a separator section disposed between the anode section and the cathode section, and an electrolyte. The method also includes disposing the plurality of core sections into a solvent so as to produce a mixture of cathode materials from the plurality of core sections. The solvent and the electrolyte form an ionic conductive medium, and the mixture of the cathode materials is characterized by a substantially homogeneous distribution of an active element in the cathode material.

Claims (23)

1. A system, comprising:

a first device configured to process at least one battery into a plurality of core sections, each core section in the plurality of core sections comprising an anode section, a cathode section including a cathode material, a separator section disposed between the anode section and the cathode section; and an electrolyte; and

a second device configured to receive the plurality of core sections and dissolve the plurality of core sections in a solvent so as to produce a mixture of cathode materials from the plurality of core sections, wherein the solvent and the electrolyte form an ionic conductive medium, and the mixture of the cathode materials is characterized by a substantially homogeneous distribution of an active element in the cathode material.

2. The system of claim 1 , wherein the first device is configured to process a lithium ion battery, and the cathode material includes at least one of LiCoO 2 , LiMn 2 O 4 , LiFetM1-tPO4 (LFMP), or LiNiaMnbCocAdO2, where a+b+c+d=1, A=Al, Zr, or Mg.

3. The system of claim 1 , wherein the second device is configured to hold at least one of dimethylformamide (DMF), dimethyl sulfoxide (DMSO), N-methyl-2-pyrrolidone (NMP), or dimethylacetamide (DMAc).

4. The system of claim 1 , wherein the second device is configured to produce the mixture of the cathode materials without an electrochemical process.

5. The system of claim 1 , wherein the second device is configured to produce the mixture of the cathode materials including a lithium deficient compound of the active element in the cathode material.

6. The system of claim 1 , wherein the second device further comprises:

an ultrasonic transducer configured to deliver an ultrasonic wave into the solvent to facilitate production of the mixture of the cathode materials.

7. The system of claim 1 , further comprising a third device configured to heat the plurality of core sections to facilitate the production of the mixture of the cathode materials.

8. The system of claim 1 , further comprising:

a fourth device configured to receive the plurality of core sections, the fourth device comprising a solvent and an ultrasonic transducer configured to deliver an ultrasonic wave into the solvent to facilitate production of the mixture of the cathode materials.

9. The system of claim 1 , wherein the anode section in each core section includes an anode material, the mixture of cathode materials further includes anode materials from the plurality of core sections, and the system further comprises:

a third device configured to extract the cathode materials from the mixture of the cathode materials and the anode materials.

10. The system of claim 9 , wherein the third device is configured to perform a density-based separation process so as to extract the cathode materials from the mixture of the cathode materials and the anode materials.

11. The system of claim 9 , wherein the third device is configured to perform a hydrophobicity-based separation process so as to extract the cathode materials from the mixture of the cathode materials and the anode materials.

12. The system of claim 9 , wherein the third device is configured to perform a filtration separation process so as to extract the cathode materials from the mixture of the cathode materials and the anode materials.

13. The system of claim 9 , wherein the third device is configured to perform an eddy current separation process so as to extract the cathode materials from the mixture of the cathode materials and the anode materials.

14. The system of claim 1 , further comprising a fourth device configured for relithiating the cathode materials extracted from the mixture of the cathode materials and the anode materials to produce a battery-grade cathode material.

15. The system of claim 1 , further comprising: a discharger configured to deactivate the at least one battery before the first device is configured to process the at least one battery into the plurality of core sections.

16. The system of claim 1 , wherein the discharger includes a conductive powder to receive the at least one battery and discharge the at least one battery.

17. The system of claim 1 , wherein the conductive power includes at least one of a metal, a carbon, a conductive oxide, or a fluid.

18. The system of claim 1 , further comprising: a conductive needle configured to penetrate the at least one battery after deactivating the at least one battery to estimate a state of discharge of the at least one battery.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 23, 2023
From: YOUNG, DAVID; LI, ZHENG; ELLIS, MICHAEL W.; SCHMIDT, NOLAN D.; HAN, XU
To: LI INDUSTRIES, INC.
Reel/Frame 064044/0422 →
Continuity (3)
Division 17298276
Provisional Application 62772243 · Nov 28, 2018
Related Publication 20230246260A1 · Aug 3, 2023
Cited By (5)
US 12,266,772 US 12,278,353 US 12,431,553 US 12,456,768 US 12,494,523