IP Library › Granted Patent US 11,898,095
Granted Patent B2
US 11,898,095 · App. 17/818,129 · Granted Feb 13, 2024

Crosslinking of cellulose fibers

Inventors: Giselle Refunjol (Houston, TX); Jazmin Godoy-Vargas (Missouri City, TX); Mohan Kanaka Raju Panga (Sugar Land, TX)
Assignee: SCHLUMBERGER TECHNOLOGY CORPORATION
C09K8/685C09K2208/08
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Quick Facts
Patent No.
US 11,898,095
App. No.
17/818,129
Granted
Feb 13, 2024
Kind
B2
Abstract

Methods of treating a subterranean formation include forming a treatment fluid including a hydrophilic fiber coated with a water soluble polymer and a crosslinking agent.

Claims (31)

1. A method of treating a subterranean formation, the method comprising:

forming a treatment fluid, comprising:

at least one hydrophilic, pulp cellulose-based fiber, wherein an outer wall of the at least one hydrophilic, pulp cellulose-based fiber is coated with a water soluble polymer comprising carboxymethylcellulose, and the at least one hydrophilic, pulp cellulose-based fiber is dried after being coated with the water soluble polymer; and

at least one crosslinking agent tetraethylenepentamine; and

placing the treatment fluid in the subterranean formation.

2. The method of claim 1 , wherein the at least one hydrophilic, pulp cellulose-based fiber comprises a pulp cellulose fiber, a powdered cellulose fiber, a microfibrillated cellulose fiber, a nanofibrillated cellulose fiber, a nanocrystalline cellulose fiber, or a combination thereof.

3. The method of claim 1 , wherein a ratio between a length of the at least one hydrophilic, pulp cellulose-based fiber and a width of the at least one hydrophilic, pulp cellulose-based fiber is between about 5 and about 1000.

4. The method of claim 1 , wherein the water soluble polymer comprises a polysaccharide, a polyelectrolyte, a non-charged polymer, or a combination thereof.

5. The method of claim 1 , wherein the amount of the water soluble polymer used in the treatment fluid is from about 0.6 mg per gram of the at least one hydrophilic, pulp cellulose-based fiber added to 120 mg per gram of the at least one hydrophilic, pulp cellulose-based fiber added.

6. The method of claim 1 , wherein the water soluble polymer comprises a resin.

7. The method of claim 6 , wherein the resin comprises a polyamideamine-epichlorohydrin (PAE) resin, a formaldehyde resin, an epoxide resin, an aldehyde resin, or a combination thereof.

8. The method of claim 1 , wherein the water soluble polymer is modified or functionalized.

9. A treatment fluid comprising:

at least one hydrophilic, pulp cellulose-based fiber, wherein an outer wall of the at least one hydrophilic, pulp cellulose-based fiber is coated with a water soluble polymer comprising carboxymethylcellulose, and the at least one hydrophilic, pulp cellulose-based fiber is dried after being coated with the water soluble polymer; and

at least one crosslinking agent comprising tetraethylenepentamine.

10. The treatment fluid of claim 9 , further comprising a powdered cellulose fiber, a microfibrillated cellulose fiber, a nanofibrillated cellulose fiber, a nanocrystalline cellulose fiber, or a combination thereof.

11. The treatment fluid of claim 9 , wherein a ratio between a length of the at least one hydrophilic, pulp cellulose-based fiber and a width of the at least one hydrophilic, pulp cellulose-based fiber is between about 5 and about 1000.

12. The treatment fluid of claim 9 , wherein an amount of the water soluble polymer in the treatment fluid is from about 0.6 mg per gram of the hydrophilic, pulp cellulose-based fiber added to 120 mg per gram of the hydrophilic, pulp cellulose-based fiber added.

13. The treatment fluid of claim 9 , wherein the at least one crosslinking agent further comprises glutaraldehyde, glyoxal, a zinc-based compound, a zirconium-based compound, or a combination thereof.

14. The treatment fluid of claim 9 , wherein the at least one hydrophilic, pulp cellulose-based fiber is dried before being coated with the water soluble polymer.

15. The treatment fluid of claim 9 , wherein the at least one crosslinking agent comprises a delay agent.

16. The treatment fluid of claim 9 , wherein the at least one hydrophilic, pulp cellulose-based fiber is dried into one or more sheets, one or more pellets, or both, and subsequently added to an aqueous medium.

17. The treatment fluid of claim 9 , comprising a three-dimensional polymerized structure having a plurality of coated fibers cross-linked via the at least one crosslinking agent, wherein each of the plurality of coated fibers comprises:

the hydrophilic, pulp cellulose-based fiber; and

a dried coating disposed on the outer wall of the hydrophilic, pulp cellulose-based fiber, wherein the dried coating comprises the water soluble polymer comprising the carboxymethylcellulose.

18. A treatment fluid comprising:

a hydrophilic fiber network comprising a plurality of coated fibers cross-linked via at least one crosslinking agent comprising tetraethylenepentamine, wherein each of the plurality of coated fibers comprises:

a hydrophilic, pulp cellulose-based fiber; and

a dried coating disposed on an outer wall of the hydrophilic, pulp cellulose-based fiber, wherein the dried coating comprises a water soluble polymer comprising carboxymethylcellulose.

19. The treatment fluid of claim 18 , comprising a carboxyl activating agent including N-(3-Dimethylaminopropyl)-N′-ethylcarbodiimide hydrochloride (EDC).

20. The treatment fluid of claim 18 , wherein the hydrophilic fiber network is configured to bridge fractures within a subterranean formation.

Continuity (3)
Continuation 16340528
Provisional Application 62407213 · Oct 12, 2016
Related Publication 20220403226A1 · Dec 22, 2022
Cited By (1)
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