Aluminum alloy film, method of producing the same, and thin film transistor
[Object] It is an object of the present invention to provide an aluminum alloy film having excellent bending resistance and heat resistance, and a thin film transistor including the aluminum alloy film. [Solving Means] In order to achieve the above-mentioned object, an aluminum alloy film according to an embodiment of the present invention includes: an Al pure metal that includes at least one type of a first additive element selected from the group consisting of Zr, Sc, Mo, Y, Nb, and Ti. A content of the first additive element is 0.01 atomic % or more and 1.0 atomic % or less. Such an aluminum alloy film has excellent bending resistance and excellent heat resistance. Further, also etching can be performed on the aluminum alloy film.
1. An aluminum alloy film formed by a sputtering method on a substrate, the aluminum alloy film comprising:
an Al pure metal that includes Zr, Sc, and at least one type of a first additive element selected from the group consisting of Mo, Y, Nb, and Ti, the first additive element forming intermetallic compounds of Al;
Mn, Si, and at least one type of a second additive element selected from the group consisting of Mg and Ag, the second additive element being dissolved in Al; and
at least one type of a third additive element selected from the group consisting of Ce, Nd, La, and Gd;
a total content of Zr, Sc, and the first additive element being 0.01 atomic % or more and 1.0 atomic % or less,
a total content of Mn, Si, and the second additive element being 0.2 atomic % or more and 3.0 atomic % or less, and
a total content of the third additive element being 0.1 atomic % or more and 1.0 atomic % or less.
2. The aluminum alloy film according to claim 1 , wherein
the aluminum alloy film has bending resistance that can withstand bending in a case of being bent to a bending radius of 1 mm.
3. The aluminum alloy film according to claim 1 , wherein dry etching and wet etching of the aluminum alloy film are possible under the conditions that:
as the dry etching, an etching gas is a mixed gas of Cl 2 (50 sccm)/Ar (20 sccm), an etching pressure is 1.0 Pa, and discharge power is 400 W in a case where the substrate bias power is 200 W; and
as the wet etching solution, a mixed solution of phosphoric acid/nitric acid/acetate/water is used and a liquid temperature is 40° C.
4. The aluminum alloy film according to claim 1 , wherein
a surface roughness P−V value is 50 nm or less.
5. The aluminum alloy film according to claim 1 , wherein
specific resistance is 10 μ 106 ·cm or less.
6. A thin film transistor, comprising:
a gate electrode including an aluminum alloy film,
the aluminum alloy film including:
an Al pure metal that includes Zr, Se, and at least one type of a first additive element selected from the group consisting of Mo, Y, Nb, and Ti, the first additive element forming intermetallic compounds of Al;
Mn, Si, and at least one type of a second additive element selected from the group consisting of Mg and Ag, the second additive element being dissolved in Al; and
at least one type of a third additive element selected from the group consisting of Ce, Nd, La, and Gd,
a total content of Zr, Sc, and the first additive element being 0.01 atomic % or more and 1.0 atomic % or less,
a total content of Mn, Si, and the second additive element being 0.2 atomic % or more and 3.0 atomic % or less, and
a total content of the third additive element being 0.1 atomic % or more and 1.0 atomic % or less.
7. A production method of an aluminum alloy film, the production method comprising:
including Zr, Sc, and at least one type of a first additive element selected from the group consisting of Mo, Y, Nb, and Ti;
including Mn, Si, and at least one type of a second additive element selected from the group consisting of Mg and Ag;
further including at least one type of a third additive element selected from the group consisting of Ce, Nd, La, and Gd;
by a sputtering method using an Al alloy target in an Al pure metal; and
producing an aluminum alloy film having
a total content of Zr, Sc, and the first additive element of 0.01 atomic % or more and 1.0 atomic % or less on a substrate, the first additive element forming intermetallic compounds of Al,
a total content of Mn, Si, and the second additive element of 0.2 atomic % or more and 3.0 atomic % or less on a substrate, the second additive element being dissolved in Al, and
a total content of the third additive element being 0.1 atomic % or more and 1.0 atomic % or less.