Fiber-containing products made with sugar-alcohol-containing binder compositions
Fiber-containing products are described that include a cured binder formed from a binder composition that may include a sugar alcohol having three or more carbon atoms, and a polymeric polycarboxylic acid. The binder composition may be characterized by a mole ratio of hydroxyl groups to carboxylic acid groups greater than or about 1.1:1. The fiber-containing product may also be characterized by a thermal stability that is greater than a comparative fiber-containing product made with a comparative cured binder that includes the polymeric polycarboxylic acid but lacks the sugar alcohol. The fiber-containing products may include thermal insulation products such as building insulation, pipe insulation, duct insulation, and appliance insulation.
1. A fiber-containing product comprising:
a cured binder is formed from a binder composition comprising:
a sugar alcohol; and
a polymeric polycarboxylic acid,
wherein the binder composition is characterized by a mole ratio of hydroxyl groups to carboxylic acid groups greater than or about 1.1:1, and
wherein the fiber-containing product is characterized by a thermal stability that is greater than a comparative fiber-containing product made with a comparative cured binder that includes the polymeric polycarboxylic acid but lacks the sugar alcohol wherein the fiber-containing product exhibits a combustion exotherm at a higher temperature than a comparative fiber-containing product made with a comparative cured binder that includes said polymeric polycarboxylic acid but lacks said sugar alcohol, and wherein the cured binder contains less than or equal to 1 wt. % unpolymerized sugar alcohol.
2. The fiber-containing product of claim 1 , wherein the sugar alcohol includes at least one non-reducing sugar alcohol selected from the group consisting of sorbitol, mannitol, xylitol, maltitol, glycerol, erythritol, threitol, arabitol, ribitol, galactitol, fucitol, iditol, inositol, volemitol, isomalt, lactitol, maltotritol, maltotetraitol, and polyglycitol.
3. The fiber-containing product of claim 1 , wherein the sugar alcohol comprises sorbitol.
4. The fiber-containing product of claim 1 , wherein the polymeric polycarboxylic acid comprises at least one homopolymer or copolymer of at least one unsaturated carboxylic acid or anhydride selected from the group consisting of acrylic acid, maleic acid, maleic anhydride, itaconic acid, itaconic anhydride, methacrylic acid, fumaric acid, crotonic acid.
5. The fiber-containing product of claim 1 , wherein the polymeric polycarboxylic acid comprises at least one polyacrylic acid polymer.
6. The fiber-containing product claim 1 , wherein the cured binder cures at a temperature that is less than a comparative cured binder that includes said polymeric polycarboxylic acid but lacks said sugar alcohol.
7. The fiber-containing product of claim 1 , wherein the mole ratio of hydroxyl groups to carboxylic acid groups in the binder composition is greater than or about 1.25:1.
8. The fiber-containing product of claim 1 , wherein the cured binder is characterized by a humid-aged retention greater than or about 35%.
9. The fiber-containing product of claim 1 , wherein the binder composition is free of long-chain polyols having a molecular weight greater than or about 1500 Daltons.
10. The fiber-containing product of claim 1 , wherein the fiber-containing product comprises thermal insulation.
11. The fiber-containing product of claim 10 , wherein the thermal insulation comprises at least one of building insulation, pipe insulation, duct insulation, or appliance insulation.
12. The fiber-containing product of claim 1 , wherein the fiber-containing product comprises a nonwoven mat or a spunbond mat.
13. The fiber-containing product of claim 12 , wherein the non-woven mat comprises glass fibers.
14. The fiber-containing product of claim 12 , wherein the spunbond mat comprises at least one polyester polymer.