IP Library › Granted Patent US 11,996,451
Granted Patent B2
US 11,996,451 · App. 17/885,456 · Granted May 28, 2024

Semiconductor device with ferroelectric aluminum nitride

Inventors: Miin-Jang Chen (Hsinchu, TW); Tzong-Lin Jay Shieh (Hsinchu, TW); Bo-Ting Lin (Hsinchu, TW)
Assignees: Taiwan Semiconductor Manufacturing Co., Ltd.; National Taiwan University
H01L29/2003H01L21/02458H01L29/40111H01L29/42356H01L29/516H01L29/66462H01L29/778
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Quick Facts
Patent No.
US 11,996,451
App. No.
17/885,456
Granted
May 28, 2024
Kind
B2
Abstract

Techniques in accordance with embodiments described herein are directed to semiconductor devices including a layer of aluminum nitride AlN or aluminum gallium nitride AlGaN as a ferroelectric layer and a method of making a thin film of AlN/AlGaN that possesses ferroelectric properties. In a ferroelectric transistor, a thin film of AlN/AlGaN that exhibits ferroelectric properties is formed between a gate electrode and a second semiconductor layer, e.g., of GaN.

Claims (40)

1. A structure, comprising:

a substrate;

a first layer of a first group III-V compound material over the substrate;

a second layer of a second group III-V compound material directly over the first layer, the second layer having a ferroelectric property, the second group III-V compound material being Al 1−x Ga x N, with x being in a range between 0 and 0.4 inclusive;

a gate electrode over the second layer; and

a source or drain structure over the first layer and adjacent to the gate electrode.

2. The structure of claim 1 , wherein the source or drain structure is positioned over the second layer of Al 1−x Ga x N.

3. The structure of claim 1 , wherein the second layer of Al 1−x Ga x N has a thickness ranging between about 1 nm and about 20 nm, inclusive.

4. The structure of claim 1 , wherein the first group III-V material includes GaN.

5. The structure of claim 1 , wherein the first group III-V material includes InN.

6. The structure of claim 1 , wherein the substrate includes sapphire.

7. The structure of claim 1 , wherein the substrate is silicon, and further comprising a nucleation layer between the silicon substrate and the first layer.

8. The structure of claim 7 , wherein the first group III-V material includes GaN and the nucleation layer is AlN.

9. A structure, comprising:

a substrate;

a first layer of a first group-III nitride over the substrate;

a second layer of a second group-III nitride over the first group-III nitride layer, the second group-III nitride having a ferroelectric property; and

a first electrode over the second layer of the second group-III nitride,

a second electrode contacting the first layer of the first group-III nitride,

wherein the first group-III nitride includes un-doped GaN and the second group-III nitride includes ferroelectric AlGaN and has a thickness equal to or less than 20 nm.

10. The structure of claim 9 , wherein the second electrode is spaced apart from the first electrode.

11. The structure of claim 9 , further comprising a dielectric layer positioned between the first electrode and the second layer of the second group-III nitride.

12. The structure of claim 9 , wherein the AlGaN of the second layer of the second group-III nitride has a thickness ranging between about 1 nm and about 20 nm, inclusive.

13. The structure of claim 9 , wherein the substrate includes sapphire.

14. The structure of claim 9 , wherein the first layer of the first group-III nitride also includes InN.

15. The structure of claim 9 , wherein the AlGaN of the second group-III nitride is Al 1−x Ga x N, with x being between 0 and 0.4, inclusive.

16. A device, comprising:

a substrate;

a first layer of a first group-III nitride over the substrate, the first group-III nitride including a first in-plane interatomic distance between a group-III atom and a nitrogen atom, the first in-plane interatomic distance being larger than a second in-plane interatomic distance between an aluminum atom and a nitrogen atom in aluminum nitride; and

a second layer of a second group-III nitride over the first layer, the second layer having a thickness equal to or less than 20 nm and having a ferroelectric property,

wherein the second group-III nitride of the second layer includes a same facet direction as the first group-III nitride of the first layer.

17. The device of claim 16 , wherein the first group III nitride is one or more of GaN or InN.

18. The device of claim 16 , wherein the second group-III nitride is Al 1−x Ga x N, with x being between 0 and 0.4, inclusive.

19. A structure, comprising:

a substrate;

a first layer of a first group-III nitride over the substrate;

a second layer of a second group-III nitride over the first group-III nitride layer, the second group-III nitride having a ferroelectric property; and

a first electrode over the second layer of the second group-III nitride,

wherein the second group-III nitride is Al 1−x Ga x N, with x being between 0 and 0.4, inclusive.

20. The structure of claim 19 , wherein the first group III nitride is one or more of GaN or InN.

Continuity (4)
Continuation 17088461 · Nov 3, 2020
Division 16235997 · Dec 28, 2018
Provisional Application 62736954 · Sep 26, 2018
Related Publication 20220384582A1 · Dec 1, 2022