IP Library Granted Patent US 12,098,091
Granted Patent B2
US 12,098,091 · App. 17/162,661 · Granted Sep 24, 2024

Glass compositions, fiberizable glass compositions, and glass fibers made therefrom

Inventors: Hong Li (Stanley, NC); Paul A. Westbrook (Shelby, NC)
Assignee: Electric Glass Fiber America, LLC.
C03C13/00C03C3/095C08K7/14
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Quick Facts
Patent No.
US 12,098,091
App. No.
17/162,661
Granted
Sep 24, 2024
Kind
B2
Abstract

The present invention relates generally to glass compositions incorporating rare earth oxides (RE 2 O 3 ). In one embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO 2 , 12.5-22 wt. % Al 2 O 3 , 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe 2 O 3 , 0.05 or greater wt. % RE 2 O 3 , and greater than 1 wt. % MnO x . In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO 2 , 12.5-22 wt. % Al 2 O 3 , 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe 2 O 3 , 0.05 or greater wt. % RE 2 O 3 , 0-4 wt. % BaO, 0-4 wt. % SrO, and 0-5.5 wt. % ZnO, wherein the sum of BaO+SrO+ZnO is greater than about 2 wt. %. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO 2 , 12.5-22 wt. % Al 2 O 3 , 0-20 wt. % CaO, 0-11 wt. % MgO, 0.2-1 wt. % Fe 2 O 3 , 0.05 or greater wt. % RE 2 O 3 , and from greater than 0 to 2.5 wt. % Cu 2 O. In another embodiment, a glass composition suitable for fiber forming comprises 51-70 wt. % SiO 2 , 12.5-22 wt. % Al 2 O 3 , 0-20 wt. % CaO, 0-12.5 wt. % MgO, 0.2-1 wt. % Fe 2 O 3 , 0.05 or greater wt. % RE 2 O 3 , and at least one additional feature selected from the group consisting of: La 2 O 3 is present in an amount greater than about 2 weight percent, CaO is present in an amount less than about 2 weight percent, a MgO/CaO ratio less than about 1, and a SiO 2 /Al 2 O 3 ratio greater than about 4. The glass compositions can be used to form glass fibers which can be incorporated into a variety of other fiber glass products (e.g., strands, rovings, fabrics, etc.) and incorporated into various composites.

Claims (31)

1. A glass composition suitable for fiber forming comprising:

SiO 2

51-65 weight percent;

Al 2 O 3

12.5-19 weight percent;

CaO

0-20 weight percent;

MgO

0-12 weight percent;

Na 2 O

0-2.5 weight percent;

K 2 O

is present up to 1 weight percent;

TiO 2

0-3 weight percent;

B 2 O 3

0-3 weight percent;

Fe 2 O 3

present in an amount from greater than

0.2 to 1 weight percent; and

RE 2 O 3

0.05-8 weight percent.

2. The glass composition of claim 1 , further comprising Li 2 O in an amount from 0 weight percent and up to 2 weight percent.

3. The glass composition of claim 1 , further comprising Li 2 O in an amount from 0 weight percent and up to 1 weight percent.

4. The glass composition of claim 1 , wherein RE 2 O 3 is present in an amount greater than 0.5 weight percent and up to 8 weight percent.

5. The glass composition of claim 1 , wherein RE 2 O 3 is present in an amount greater than 1 weight percent and up to 8 weight percent.

6. The glass composition of claim 1 , further comprising P 2 O 5 is an amount from 0 weight percent and up to 3 weight percent.

7. The glass composition of claim 1 , wherein Na 2 O+K 2 O+Li 2 O is greater than 1 weight percent.

8. A glass fiber formed from the composition of claim 1 .

9. An article of manufacture comprising the glass fiber of claim 8 .

10. The article of manufacture of claim 9 , wherein the article is a printed circuit board.

Continuity (6)
Continuation 16047539 · Jul 27, 2018
Continuation 15385083 · Dec 20, 2016
Continuation In Part 15019172 · Feb 9, 2016
Continuation 14325854 · Jul 8, 2014
Provisional Application 61846266 · Jul 15, 2013
Related Publication 20210147283A1 · May 20, 2021