Granted Patent B2

US 12,202,242 · App. 17/779,075 · Granted Jan 21, 2025

Inventors: Wibke Loelsberg (Ludwigshafen, DE); Arne Klinkebiel (Lemfoerde, DE); Eva Guenther (Trostberg, DE); Christian Schmidt (Ludwigshafen, DE); David J. Mihalcik (Northborough, MA); Kathryn Elizabeth Dekrafft (Northborough, MA); Nicholas Zafiropoulos (Northborough, MA); Owen Richards Evans (Northborough, MA); George L. Gould (Northborough, MA)

Assignee: Aspen Aerogels, Inc.

B32B5/18B32B7/12B32B13/045B32B2305/022B32B2307/304B32B2307/3065B32B2307/41B32B2307/732

Abstract

Claims (41)

1. A thermal insulation board (IB) comprising at least two insulating layers (A), wherein the at least two insulating layers (A) are bonded together and wherein at least one of the at least two insulating layers (A) comprises at least one aerogel composite material comprising:

(a1) a plurality of a silica aerogel particles,

(a2) at least one polymer foam comprising an open-cell polymer foam, and

(a3) at least one flame retardant embedded in the silica aerogel particles,

wherein the at least one aerogel composite material comprised in at least one of the at least two insulating layers (A) comprises

20 to 80% by weight of the silica aerogel (a1),

1 to 15% by weight of the at least one polymer foam (a2) and

27 to 60% by weight of the at least one flame retardant (a3),

based in each case on a total weight of the at least one aerogel composite material and

wherein the thermal insulation board is characterized by thermal properties that include a furnace temperature rise less than 50° C., a mass loss of less than 50% and a flame time of less than 20 s determined according to ISO 1182:2010,

wherein the at least one aerogel composite material has a heat of combustion of less than or equal to 3.0 MJ/kg, determined according to EN ISO 1716:2010-11, and has a liquid water uptake of less than or equal to 20% by weight, based on the total weight of the at least one aerogel composite material.

2. The thermal insulation board (IB) according to claim 1 , wherein:

i) the at least two insulating layers (A) are bonded together by at least one first adhesive (AD 1 ), and/or

ii) the at least two insulating layers (A) are bonded together by mechanical fixing (MF), and/or

iii) each of the at least two insulating layers (A) has a thickness of 1 to 500 mm.

3. The thermal insulation board (IB) according to claim 2 , wherein:

i) the at least one first adhesive (AD 1 ) is selected from the group consisting of inorganic adhesives, organic adhesives and inorganic-organic hybrid adhesives, the at least one first adhesive (AD 1 ) being a polyurethane-based one- or two-component adhesive with a calorific value of <40 MJ/kg, optionally filled with inorganic compounds, and/or

ii) the at least one first adhesive (AD 1 ) is applied to at least one surface of at least one of the at least two insulating layers (A), with a thickness of 0.01 to 10 mm, and/or

iii) the at least one first adhesive (AD 1 ) is applied to at least one surface of at least one of the at least two insulating layers (A) with a weight per square meter of 10 to 500 g/m 2 .

4. The thermal insulation board (IB) according to claim 1 , wherein the at least one aerogel composite material comprised in at least one of the at least two insulating layers (A) has:

i) a density of 0.10 to 0.40 g/cm 3 , and/or

ii) a thermal conductivity of less than or equal to 0.030 W/(mK), and/or

iii) a liquid water uptake of less than or equal to 20% by weight, based on the total weight of the at least one aerogel composite material.

5. The thermal insulation board (IB) according to claim 1 , wherein the silica aerogel (a1) comprises in a range from 1 to 25% by weight, of at least one hydrophobic group, based on the total weight of the silica aerogel (a1), wherein the at least one hydrophobic group is bound to at least one silicon atom.

6. The thermal insulation board (IB) according to claim 1 , wherein the at least one polymer foam (a2) comprised in the at least one aerogel composite material has a density of 0.002 to 0.025 g/cm 3 .

7. The thermal insulation board (IB) according to claim 1 , wherein the at least one flame retardant (a3) comprised in the at least one aerogel composite material is selected from inorganic compounds, from the group consisting of clay minerals, low melting glasses, metal oxides, metal oxide hydroxides, metal hydroxides, carbonates and hydrocarbonates.

8. The thermal insulation board (IB) according to claim 1 , wherein the at least one aerogel composite material further comprises at least one infrared absorbing or reflecting opacifier selected from the group consisting of carbon black, graphite, boron carbide, metal oxides and metal carbides.

9. A thermal insulation system (IS) comprising the thermal insulation board (IB) according to claim 1 and a fixing layer (X), wherein the fixing layer (X) affixes the thermal insulation board (IB) on a building wall (BW).

10. The thermal insulation system (IS) according to claim 9 , wherein the fixing layer (X):

i) comprises at least one second adhesive (AD 2 ) selected from the group consisting of inorganic adhesives and organic adhesives, and/or

ii) has a thickness of 0.5 to 30 mm.

11. The thermal insulation system (IS) according to claim 9 , wherein the thermal insulation system (IS) further comprises an upper layer (B) which is bonded to the thermal insulation board (IB) such that in the thermal insulation system (IS) there is the thermal insulation board (IB) between the fixing layer (X) and the upper layer (B).

12. The thermal insulation system (IS) according to claim 11 , wherein the upper layer (B)

i) comprises at least one third adhesive (AD 3 ) selected from the group consisting of inorganic adhesives and organic adhesives, the at least one third adhesive (AD 3 ) comprising mortar, and optionally at least one reinforcing material selected from the group consisting of meshes, fibers, fleeces and fabrics, and/or

ii) has a thickness of 0.5 to 30 mm.

13. The thermal insulation system (IS) according to claim 11 , wherein the thermal insulation system (IS) further comprises a finishing layer (C) bonded to the upper layer (B), wherein:

i) the finishing layer (C) comprises plaster or render, and/or

ii) the finishing layer (C) has a thickness of 0.5 to 40 mm.

14. The thermal insulation system (IS) according to claim 13 , wherein the thermal insulation system (IS) further comprises a surface finishing layer (D) bonded to the finishing layer (C), wherein:

i) the surface finishing layer (D) comprises a coating, a lamination, a film, a foil or a paint, and/or

ii) the surface finishing layer (D) has a thickness of 0.001 to 10 mm.

Assignments (8)

Priority Claims (1)

Continuity (1)

References Cited (36)

Cited By (1)

US 12,331,519