High flow fiber-reinforced propylene composition having low emissions
A fiber-reinforced polymer composition that contains a polymer matrix and a plurality of long reinforcing fibers that are distributed within the polymer matrix is provided. The polymer matrix contains a propylene polymer and constitutes from about 30 wt. % to about 90 wt. % of the composition. The fibers constitute from about 10 wt. % to about 70 wt. % of the composition. Further, the polymer composition exhibits a spiral flow length of about 450 millimeters or more as determined in accordance with ASTM D3123-09 and a volatile organic content of about 100 micrograms per gram or less as determined by VDA 277.
1. An automotive part comprising a fiber-reinforced polymer composition comprising:
a polymer matrix that contains: a propylene polymer having a melt flow index from about 150 to about 250 g/10 min, wherein melt flow index is determined in accordance with ISO 1133-1:2011 at a load of 2.16 kg and temperature of 230° C., wherein the polymer matrix constitutes from about 30 wt. % to about 90 wt. % of the composition; and
a plurality of long reinforcing fibers that are distributed within the polymer matrix, wherein the fibers constitute from about 10 wt. % to about 70 wt. % of the composition, wherein the polymer composition exhibits a spiral flow length of about 450 millimeters or more as determined in accordance with ASTM D3123-09, and further wherein the composition exhibits a volatile organic content of about 100 μgC/g or less as determined in accordance with VDA 277:1995.
2. The automotive part of claim 1 , wherein the composition exhibits a toluene equivalent volatile organic content of about 250 μg/g or less as determined in accordance with VDA 278:2002.
3. The automotive part of claim 1 , wherein the composition exhibits a fogging content of about 500 μg/g or less as determined in accordance with VDA 278:2002.
4. The automotive part of claim 1 , wherein the propylene polymer is a homopolymer.
5. The automotive part of claim 4 , wherein the homopolymer is metallocene-catalyzed.
6. The automotive part of claim 1 , wherein the propylene polymer is an α-olefin/propylene copolymer.
7. The automotive part of claim 4 , wherein the composition further comprises an α-olefin/propylene copolymer.
8. The automotive part of claim 7 , wherein the homopolymer is metallocene-catalyzed.
9. The automotive part of claim 1 , wherein the fibers are glass fibers.
10. The automotive part of claim 1 , wherein the fibers constitute from about 20 wt. % to about 60 wt. % of the composition.
11. The automotive part of claim 1 , wherein the fibers are oriented in a longitudinal direction of the composition.
12. The automotive part of claim 1 , wherein the part has a wall thickness of about 2.5 millimeters or less.
13. The automotive part of claim 1 , wherein the composition exhibits a toluene equivalent volatile organic content of about 150 μg/g or less as determined in accordance with VDA 278:2002.
14. The automotive part of claim 1 , wherein the composition exhibits a fogging content of about 350 μg/g or less as determined in accordance with VDA 278:2002.
15. The automotive part of claim 1 , wherein the part has a wall thickness of about 2 millimeters or less.
16. The automotive part of claim 1 , wherein the part is injection molded.
17. The automotive part of claim 1 , wherein the part is an interior automotive part.
18. The automotive part of claim 17 , wherein the part is a pedal module, instrument panel, arm rest, console, seat structure, interior module, lift gate, interior organizer, step assist, ash tray, glove box, gear shift lever, or a combination thereof.
19. The automotive part of claim 1 , wherein the automotive part is an exterior automotive part.
20. The automotive part of claim 19 , wherein the exterior automotive part is a fan shroud, sunroof system, door panel, front end module, side body panel, underbody shield, bumper panel, cladding, cowl, spray nozzle body, capturing hose assembly, pillar cover, rocker panel, or a combination thereof.