Conductive structure and antistatic composition including the same
The present application relates to a conductive structure formed by connecting a modified graphene oxide or modified carbon nanotube with a conductive polymer, and an antistatic composition including the same. The antistatic composition of the present application has advantages of an excellent adhesive property, improved surface roughness, mechanical strength, and improved electrical properties.
1. A conductive structure formed by connecting a modified carbon nanotube with a conductive polymer,
wherein the modified carbon nanotube has one or more oligomers selected from an acrylic oligomer and a urethane oligomer binding to the surface of the carbon nanotube through a branch linkage, and
the conductive polymer is connected to the oligomer,
wherein the conductive polymer is poly(3,4-ethylendioxythiopene) (PEDOT); or poly(3,4-ethylenedioxythiopene) (PEDOT) and polystyrene sulfonic acid (PSS); and
wherein the PEDOT has one or more functional groups comprising an NH group.
2. The conductive structure of claim 1 , wherein the PEDOT is represented by Formula 3 below,
wherein A is
or —NH.
3. The conductive structure of claim 1 , wherein the acrylic oligomer and the urethane oligomer comprise one or more of n number of first units with an acrylic group and m number of second units with a urethane group, wherein each of n and m is an integer of 0 to 1000, and n+m is an integer of 1 to 1000.
4. The conductive structure of claim 3 , wherein the first unit is represented by Formula 4, and the second unit is represented by Formula 5,
wherein n is an integer of 0 to 1000,
wherein X 1 is a direct linkage, or a urethane group or a C 1 -C 10 alkylene group,
X 2 is a C 1 -C 10 alkylene group,
X 3 is a direct linkage, O or S, and
m is an integer of 0 to 1000.
5. The conductive structure of claim 1 , wherein the modified carbon nanotube is represented by Formula 6 below,
wherein, in Formula 6,
R is
and
each of n and m is independently an integer of 0 to 1000.
6. The conductive structure of claim 1 , wherein the modified carbon nanotube has one or more functional groups selected from a hydroxyl group (—OH), a formyl group (—CHO), a carbonyl group (—CO), an amine group (—NH 2 ) and a carboxyl group (—COOH) on its surface.
7. The conductive structure of claim 1 , wherein the carbon nanotube:the acrylic oligomer and the urethane oligomer:the conductive polymer are connected in a weight ratio of 2:1:8 to 1:0.2:100.
8. The conductive structure of claim 1 , wherein the conductive structure is represented by Formulas 8 below:
wherein, in Formula 8,
R is
each of n and m is independently an integer of 0 to 1000, and
k is an integer of 1 to 10,000,000.