IP Library Granted Patent US 12,266,533
Granted Patent B2
US 12,266,533 · App. 17/721,620 · Granted Apr 1, 2025

Sacrificial capping layer for contact etch

Inventors: Yun Han (Albany, NY); Andrew Metz (Albany, NY); Peter Biolsi (New Windsor, NY)
Assignee: TOKYO ELECTRON LIMITED
H01L21/3065H01L21/02164H01L21/31138H01L21/76829H01L29/66795
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Quick Facts
Patent No.
US 12,266,533
App. No.
17/721,620
Granted
Apr 1, 2025
Kind
B2
Abstract

A method which includes providing a substrate having a source/drain region and an etch stop layer on the source/drain region. A plasma etching process is performed using an etching gas that removes the etch stop layer and forms a sacrificial oxide capping layer on the source/drain region. The sacrificial oxide capping layer is then from the source/drain region.

Claims (41)

1. A method comprising:

providing a substrate comprising an epitaxial source/drain region and an etch stop layer on the epitaxial source/drain region;

performing a plasma etching process using an etching gas that removes the etch stop layer and forms a sacrificial oxide capping layer on the epitaxial source/drain region; and

removing the sacrificial oxide capping layer from the epitaxial source/drain region using an etch process that does not damage the epitaxial source/drain region under the sacrificial oxide capping layer.

2. The method of claim 1 , wherein:

the substrate comprises a metal gate stack separated from the source/drain region by a spacer, and

the etch stop layer is a conformal layer having a first portion covering the epitaxial source/drain region and a second portion covering the spacer and the metal gate stack.

3. The method of claim 2 , wherein:

the performing a plasma etching process comprises completely removing the first portion of the etch stop layer to expose the epitaxial source/drain region before completely removing the second portion of the etch stop layer, and

forming the sacrificial oxide capping layer on the exposed epitaxial source/drain region while completely removing the second portion of the etch stop layer.

4. The method of claim 1 , wherein the epitaxial source/drain region contains Si, Ge, or both Si and Ge.

5. The method of claim 1 , wherein the performing a plasma etching process comprises forming a sacrificial oxide capping layer comprising SiO 2 , GeO 2 , or SiGeO x .

6. The method of claim 1 , wherein the etch stop layer contains a nitride layer.

7. The method of claim 1 , wherein the etch stop layer contains SiN.

8. The method of claim 1 , wherein the performing a plasma etching process comprises using an etching gas comprising a fluorocarbon-containing gas and an oxygen-containing gas.

9. The method of claim 8 , wherein the fluorocarbon-containing gas comprises a fluorocarbon gas, a hydrofluorocarbon gas, or a combination thereof.

10. The method of claim 8 , wherein the oxygen-containing gas comprises O 2 , O 3 , CO, CO 2 , SO 2 or a combination thereof.

11. The method of claim 1 , wherein the removing the sacrificial oxide capping layer comprises performing a wet etch process on the substrate.

12. The method of claim 1 , wherein the removing the sacrificial oxide capping layer performing a dry etch process on the substrate.

13. A method comprising:

providing a substrate comprising and epitaxial source/drain region and a SiN etch stop layer on the epitaxial source/drain region, the epitaxial source/drain region containing Si, Ge, or both Si and Ge;

performing a plasma etching process using an etching gas containing a fluorocarbon-containing gas and an oxygen-containing gas that removes the SiN etch stop layer and forms a sacrificial oxide capping layer on the epitaxial source/drain region; and

removing the sacrificial oxide capping layer from the epitaxial source/drain region using a wet or dry etch process that does not damage the epitaxial source/drain region under the sacrificial oxide capping layer.

14. The method of claim 13 , wherein:

the substrate comprises a metal gate stack separated from the epitaxial source/drain region by a spacer, and

the SiN etch stop layer is a conformal layer having a first portion covering the epitaxial source/drain region and a second portion covering the spacer and the metal gate stack.

15. The method of claim 14 , wherein

the performing a plasma etching process comprises completely removing the first portion of the etch stop layer to expose the epitaxial source/drain region before completely removing the second portion of the etch stop layer, and

forming the sacrificial oxide capping layer on the exposed epitaxial source/drain region while completely removing the second portion of the etch stop layer.

16. The method of claim 13 , wherein the sacrificial oxide capping layer contains SiO 2 , GeO 2 , or SiGeO x .

17. The method of claim 13 , wherein the fluorocarbon-containing gas includes a fluorocarbon gas, a hydrofluorocarbon gas, or a combination thereof.

18. The method of claim 13 , wherein the oxygen-containing gas includes O 2 , O 3 , CO, CO 2 , SO 2 , or a combination thereof.

19. A method comprising:

providing a substrate comprising an epitaxial source/drain region and a SiN etch stop layer on the epitaxial source/drain region, the epitaxial source/drain region containing Si, Ge, or both Si and Ge;

performing a plasma etching process using an etching gas containing CH 3 F gas and O 2 gas that removes the SiN etch stop layer and forms a sacrificial oxide capping layer on the epitaxial source/drain region, the sacrificial oxide capping layer containing SiO 2 , GeO 2 , or SiGeO x ; and

removing the sacrificial oxide capping layer from the epitaxial source/drain region using a wet or dry etch process that does not damage the epitaxial source/drain region under the sacrificial oxide capping layer.

20. The method of claim 19 , wherein:

the substrate comprises a metal gate stack separated from the epitaxial source/drain region by a spacer;

the SiN etch stop layer is a conformal layer having a first portion covering the epitaxial source/drain region and a second portion covering the spacer and the metal gate stack;

the performing a plasma etching process comprises completely removing the first portion of the etch stop layer to expose the epitaxial source/drain region before completely removing the second portion of the etch stop layer, and

forming the sacrificial oxide capping layer on the exposed epitaxial source/drain region while completely removing the second portion of the etch stop layer.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 15, 2022
From: HAN, YUN; METZ, ANDREW; BIOLSI, PETER
To: TOKYO ELECTRON LIMITED
Reel/Frame 059609/0916 →
Continuity (2)
Provisional Application 63195436 · Jun 1, 2021
Related Publication 20220384199A1 · Dec 1, 2022
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