Slurry composition for non-aqueous secondary battery functional layer, separator for non-aqueous secondary battery, and non-aqueous secondary battery
Provided is a slurry composition for a non-aqueous secondary battery functional layer with which it is possible to form a functional layer that has excellent adhesiveness after immersion in electrolyte solution and can cause a secondary battery to display excellent rate characteristics and cycle characteristics while, on the other hand, reducing the amount of gas remaining inside the secondary battery. The slurry composition contains a particulate polymer and a solvent. The particulate polymer has a core-shell structure including a core portion and a shell portion at least partially covering an outer surface of the core portion. The particulate polymer has a glass-transition temperature of 20° C. or higher and has a surface acid content of not less than 0.05 mmol/g and not more than 0.50 mmol/g.
1. A slurry composition for a non-aqueous secondary battery functional layer comprising a particulate polymer, a binder for a functional layer and a solvent, wherein
the particulate polymer has a core-shell structure including a core portion and a shell portion at least partially covering an outer surface of the core portion,
the core portion is formed of a polymer including a nitrile group-containing monomer unit in a proportion of not less than 1 mass % and not more than 20 mass %,
the proportion constituted by an aromatic monovinyl monomer unit included in the polymer of the core portion when all repeating units included in the particulate polymer are taken to be 100 mass % is 30 mass % or more and 50 mass % or less,
the proportion constituted by the nitrile group-containing monomer unit included in the polymer of the core portion when all repeating units included in the particulate polymer are taken to be 100 mass % is 3 mass % or more and 10 mass % or less,
the particulate polymer has a glass-transition temperature of 20° C. or higher and a surface acid content of not less than 0.05 mmol/g and not more than 0.50 mmol/g, and
the amount of the binder for a functional layer per 100 parts by mass of the particulate polymer is 40 parts by mass or less.
2. The slurry composition for a non-aqueous secondary battery functional layer according to claim 1 , wherein
the particulate polymer has a degree of swelling of not less than a factor of 1.0 and not more than a factor of 4.0, by mass, when immersed in an electrolyte solution for measurement for 72 hours, and
the particulate polymer has a degree of swelling of not less than a factor of 8.0 and not more than a factor of 20, by mass, when immersed in the electrolyte solution for measurement for 240 hours,
the electrolyte solution for measurement being a solution obtained by dissolving LiPF 6 with a concentration of 1 mol/L in a mixed solvent obtained by mixing ethylene carbonate, diethyl carbonate, and vinylene carbonate in a volume ratio of ethylene carbonate/diethyl carbonate/vinylene carbonate=68.5/30/1.5.
3. The slurry composition for a non-aqueous secondary battery functional layer according to claim 1 , wherein
the core portion is formed of a polymer including an aromatic monovinyl monomer unit in a proportion of less than 85 mass %, and
the shell portion is formed of a polymer including an aromatic monovinyl monomer unit in a proportion of not less than 85 mass % and not more than 100 mass %.
4. The slurry composition for a non-aqueous secondary battery functional layer according to claim 1 , wherein the binder for a functional layer has a glass-transition temperature of lower than 20° C.
5. The slurry composition for a non-aqueous secondary battery functional layer according to claim 4 , wherein the binder for a functional layer is formed of a polymer including an aromatic monovinyl monomer unit.
6. A separator for a non-aqueous secondary battery comprising: a separator substrate; and a functional layer formed using the slurry composition for a non-aqueous secondary battery functional layer according to claim 1 .
7. The separator for a non-aqueous secondary battery according to claim 6 , wherein the separator substrate includes a porous membrane layer containing non-conductive particles and a binder.
8. A non-aqueous secondary battery comprising a positive electrode, a negative electrode, a separator, and an electrolyte solution, wherein the separator is the separator for a non-aqueous secondary battery according to claim 6 .
9. A non-aqueous secondary battery comprising a positive electrode, a negative electrode, a separator, and an electrolyte solution, wherein the separator is the separator for a non-aqueous secondary battery according to claim 7 .