IP Library › Granted Patent US 12,281,017
Granted Patent B2
US 12,281,017 · App. 17/417,328 · Granted Apr 22, 2025

Nanocomposites and related methods

Inventors: Vikas Nandwana (Evanston, IL); Vinayak P. Dravid (Glenview, IL)
Assignee: Northwestern University
C01B32/22B01J20/06B01J20/20B01J20/262B01J20/28007B01J20/28009B01J20/32B01J20/3212B01J20/3236B01J20/324B82Y30/00C01B32/20C02F1/281C02F1/283C02F1/288C09K3/32C10G25/003C10G25/006C11B13/04H01M4/583H01M4/667B82Y40/00C02F2101/32C02F2103/007C02F2303/16C10G2300/1003C10G2300/1014H01M2004/021
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Quick Facts
Patent No.
US 12,281,017
App. No.
17/417,328
Granted
Apr 22, 2025
Kind
B2
Abstract

Methods of forming a nanocomposite of a base material and a plurality of nanoparticles are provided. In embodiments, the method comprises combining a first input stream of flowing fluid comprising a base material having nucleation sites, a second input stream of flowing fluid comprising a nanoparticle precursor material, and a third input stream of flowing fluid comprising a nanoparticle nucleation agent, to form an output stream of flowing fluid; heating or sonicating or both heating and sonicating the output stream for a period of time; and collecting a nanocomposite formed within the fluid of the output stream, the nanocomposite comprising the base material and a plurality of nanoparticles directly anchored onto a surface of the base material via the nucleation sites. The nanocomposites are also provided.

Claims (17)

1. A method of forming a nanocomposite of a base material and a plurality of nanoparticles, the method comprising:

(a) combining a first input stream of flowing fluid comprising a base material having nucleation sites, a second input stream of flowing fluid comprising a nanoparticle precursor material, and a third input stream of flowing fluid comprising a nanoparticle nucleation agent, to form an output stream of flowing fluid;

(b) heating or sonicating or both heating and sonicating the output stream for a period of time; and

(c) collecting a nanocomposite formed within the fluid of the output stream, the nanocomposite comprising the base material and a plurality of nanoparticles directly anchored onto a surface of the base material via the nucleation sites, wherein the method is carried out at room temperature.

2. The method of claim 1 , wherein the base material is a two-dimensional, layered material and wherein the two-dimensional, layered material is graphite and the nanocomposite comprises a multilayer stack of a plurality of layers of graphite interleaved between the plurality of layers of nanoparticles, wherein individual layers of nanoparticles in the plurality of layers of nanoparticles are each directly anchored on a surface of a layer of the plurality of layers of graphite via the nucleation sites, and are each separated by multiple layers of the plurality of layers of graphite.

3. The method of claim 2 , wherein the nanocomposite is free of isolated graphene layers.

4. The method of claim 3 , wherein the nanocomposite is characterized by a (002) peak of graphite as determined by X-ray diffraction and a G peak of graphite having a greater intensity than a 2D peak of graphite as determined by Raman spectroscopy.

5. The method of claim 1 , wherein the nanoparticles and the base material are unfunctionalized.

6. The method of claim 1 , wherein the nanoparticles are magnetic nanoparticles or metal oxide nanoparticles.

7. The method of claim 6 , wherein the nanoparticles are transition metal oxide nanoparticles.

8. The method of claim 7 , wherein the transition metal oxide is an oxide of Cr, Mn, Co, Fe, Cu or Ni, or combinations thereof.

9. The method of claim 7 , wherein the nanoparticles are Fe 3 O 4 nanoparticles.

10. The method of claim 1 , wherein the nanocomposite is free of aggregated nanoparticles.

11. The method of claim 1 , wherein the nanoparticles are magnetic nanoparticles and have an average diameter such that the magnetic nanoparticles exhibit superparamagnetic behavior.

12. The method of claim 1 , wherein the flowing fluid of the first input stream, the second input stream, the third input stream, and the output stream is water or an aqueous solution.

13. The method of claim 12 , wherein the base material is a two-dimensional, layered material; step (b) comprises sonicating the output stream for the period of time; and step (c) further comprises inducing precipitation of the nanocomposite; and wherein the nanocomposite comprises a multilayer stack of a plurality of layers of the two-dimensional, layered material interleaved between a plurality of layers of nanoparticles, wherein individual layers of nanoparticles in the plurality of layers of nanoparticles are each directly anchored on a surface of a layer of the plurality of layers of the two-dimensional, layered material via the nucleation sites, and are each separated by multiple layers of the plurality of layers of the two-dimensional, layered material.

14. The method of claim 1 , wherein the base material is a two-dimensional, layered material; step (b) comprises sonicating the output stream for the period of time; and step (c) further comprises inducing precipitation of the nanocomposite; and wherein the nanocomposite comprises a multilayer stack of a plurality of layers of the two-dimensional, layered material interleaved between a plurality of layers of nanoparticles, wherein individual layers of nanoparticles in the plurality of layers of nanoparticles are each directly anchored on a surface of a layer of the plurality of layers of the two-dimensional, layered material via the nucleation sites, and are each separated by multiple layers of the plurality of layers of the two-dimensional, layered material.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 12, 2021
From: NANDWANA, VIKAS; DRAVID, VINAYAK P.
To: NORTHWESTERN UNIVERSITY
Reel/Frame 057157/0394 →
Continuity (3)
Provisional Application 62788321 · Jan 4, 2019
Provisional Application 62788347 · Jan 4, 2019
Related Publication 20220059839A1 · Feb 24, 2022
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