Tires comprising rubber compounds that comprise propylene-α-olefin-diene polymers
Rubber compounds that comprise rubber and propylene-a-olefin-diene (PE(D)M) polymers may be useful in tire-related articles (e.g., tire sidewalls, inner tubes, and innerliners). Such a rubber compound may comprise: about 5 phr to about 50 phr of the PE(D)M polymer that comprises about 65 wt % to about 99.5 wt % propylene, about 0.5 wt % to about 35 wt % a-olefin that is not propylene, and 0 wt % to about 20 wt % diene, said wt % based on the weight of the PE(D)M polymer, and about 50 parts per hundred parts rubber (phr) to about 95 phr of a rubber that comprises one selected from the group consisting of the halogenated isobutylene-based rubber is selected from the group consisting of: natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber, polybutadiene rubber, poly(isoprene-co-butadiene) rubber, styrene-isoprene-butadiene rubber, butyl rubber, star branched butyl rubber, isobutylene-isoprene rubber, poly(isobutylene-co-alkylstyrene), a halogenated isobutylene-based rubber, polychloroprene rubber, nitrile rubber, and any combination thereof.
1. A tire that comprises:
a rubber compound that comprises:
5 phr to 50 phr of a propylene-α-olefin-(optional diene) PE(D)M polymer that comprises about 65 wt % to about 99.5 wt % propylene, about 0.5 wt % to about 35 wt % C 2 or C 4 to C 16 α-olefin, and 0 wt % to about 20 wt % diene, said wt % based on the weight of the PE(D)M polymer, wherein the wt % numbers are uncorrected numbers, and wherein wt % propylene plus wt % of C 2 or C 4 to C 16 α-olefin equals 100%, and wherein the PE(D)M polymer has a heat of fusion (Hf) of less than 1 J/g, and
50 parts per hundred parts rubber (phr) to 95 phr of a rubber that comprises one selected from the group consisting of the halogenated isobutylene-based rubber is selected from the group consisting of: natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber, polybutadiene rubber, poly(isoprene-co-butadiene) rubber, styrene-isoprene-butadiene rubber, butyl rubber, star branched butyl rubber, isobutylene-isoprene rubber, poly(isobutylene-co-alkylstyrene), a halogenated isobutylene-based rubber, polychloroprene rubber, nitrile rubber, and any combination thereof; and
wherein the rubber and the PE(D)M polymer cumulatively are 100 phr, and
wherein the rubber compound is included in a sidewall of the tire, an inner tube of the tire, an innerliner of the tire, or any combination thereof.
2. The tire of claim 1 , wherein the halogenated isobutylene-based rubber is selected from the group consisting of: bromobutyl rubber, chlorobutyl rubber, brominated polymers derived from a copolymer of isobutylene and p-methylstyrene elastomer, and any combination thereof.
3. The tire of claim 1 , wherein the rubber further comprises EP(D)M.
4. The tire of claim 1 , wherein the rubber compound is included in a sidewall of the tire, an inner tube of the tire, an innerliner of the tire, or any combination thereof.
5. The tire of claim 1 , wherein the rubber compound has a Mooney viscosity (ML, 1+4 @100° C.) of about 30 MU to about 100 MU.
6. The tire of claim 1 , wherein the rubber compound has a PICMA tack of about 0.9 kgf or greater.
7. The tire of claim 1 , wherein the rubber compound has a 180° peel strength after curing at 160° C. for 8 minutes of about 3 kgf/cm to about 25 kgf/cm.
8. The tire of claim 1 , wherein the rubber compound has a Shore A hardness after curing at 160° C. for 8 minutes of about 40 to about 70.
9. The tire of claim 1 , wherein the rubber compound has a modulus at 100% elongation after curing at 160° C. for 8 minutes of about 0.7 MPa to about 4 MPa.
10. The tire of claim 1 , wherein the rubber compound has a tensile strength after curing at 160° C. for 8 minutes of about 7 MPa to about 20 MPa.
11. The tire of claim 1 , wherein the rubber compound has an elongation at break after curing at 160° C. for 8 minutes of about 250% to about 800%.
12. The tire of claim 1 , wherein the rubber compound has an energy at break after curing at 160° C. for 8 minutes of about 3 J to about 10 J.
13. The tire of claim 1 , wherein the rubber compound has an abrasion loss after curing at 160° C. for 8 minutes of about 100 mm 3 to about 200 mm 3 .
14. The tire of claim 1 , wherein the rubber compound has a permeance coefficient after curing at 160° C. for 8 minutes of about 1 cc/(m 2 *day·mm·Hg) to about 4 cc/(m 2 *day·mm·Hg).
15. The tire of claim 1 , wherein the rubber compound has a tear resistance after curing at 160° C. for 8 minutes of about 25 N/mm to about 50 N/mm.
16. The tire of claim 1 , wherein the rubber compound has an ozone resistance where a sample of the rubber compound exhibits no cracking after exposure to 50 pphm ozone at 40° C. for about 4 hours to about 200 hours.
17. The tire of claim 1 , wherein the PE(D)M polymer has (a) Mooney viscosity (ML(1+4) @125° C.) of about 5 MU to about 100 MU, and (b) a melt flow rate of about 0.1 g/min to about 100 g/min.
18. The tire of claim 1 , wherein the PE(D)M polymer has a number average molecular weight of 40,000 g/mol to 200,000 g/mol.
19. The tire of claim 1 , wherein the PE(D)M polymer has a weight average molecular weight of 100,000 g/mol to 500,000 g/mol.
20. The tire of claim 1 , wherein the PE(D)M polymer has a polydispersity index of 2.0 to 3.0.
21. The tire of claim 1 , wherein the PE(D)M polymer has a glass transition temperature (° C.) of greater than or equal to −7.386−(87.98*E)+(294*D) and less than or equal to −1.386−(87.98*E)+(294*D) wherein E is a mole fraction of ethylene in the PE(D)M polymer and D is a mole fraction of diene in the PE(D)M polymer.
22. The tire of claim 1 , wherein the PE(D)M polymer has a glass transition temperature (° C.) of greater than or equal to −6.886−(87.98*E)+(294*D) and less than or equal to −1.886−(87.98*E)+(294*D) wherein E is the mole fraction of ethylene in the PE(D)M polymer and D is the mole fraction of diene in the PE(D)M polymer.
23. The tire of claim 1 , wherein the rubber compound is at least partially crosslinked.
24. A method comprising:
producing a master batch at a first temperature, the master batch comprising:
5 phr to 50 phr of a propylene-α-olefin-(optional diene) PE(D)M polymer that comprises about 65 wt % to about 99.5 wt % propylene, about 0.5 wt % to about 35 wt % C 2 or C 4 to C 16 α-olefin, and 0 wt % to about 20 wt % diene, said wt % based on the weight of the PE(D)M polymer, wherein the wt % numbers are uncorrected numbers, and wherein wt % propylene plus wt % of C 2 or C 4 to C 16 α-olefin equals 100%, and wherein the PE(D)M polymer has a heat of fusion (Hf) of less than 1 J/g, and
50 parts per hundred parts rubber (phr) to 95 phr of a rubber that comprises one selected from the group consisting of the halogenated isobutylene-based rubber is selected from the group consisting of: natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber, polybutadiene rubber, poly(isoprene-co-butadiene) rubber, styrene-isoprene-butadiene rubber, butyl rubber, star branched butyl rubber, isobutylene-isoprene rubber, poly(isobutylene-co-alkylstyrene), a halogenated isobutylene-based rubber, polychloroprene rubber, nitrile rubber, and any combination thereof; wherein the rubber and the PE(D)M polymer cumulatively are 100 phr; and
mixing a curative and/or a crosslinking agent into the master batch at a second temperature that is lower than the first temperature.
25. A tire that comprises:
a rubber compound that comprises:
5 phr to 50 phr of a propylene-α-olefin-(optional diene) PE(D)M polymer that comprises about 65 wt % to about 99.5 wt % propylene, about 0.5 wt % to about 35 wt % C 2 or C 4 to C 16 α-olefin, and 0 wt % to about 20 wt % diene, said wt % based on the weight of the PE(D)M polymer, wherein the wt % numbers are uncorrected numbers, and wherein wt % propylene plus wt % of C 2 or C 4 to C 16 α-olefin equals 100%, and wherein the PE(D)M polymer has Mooney viscosity (ML(1+4) @125° C.) of about 5 MU to about 100 MU, and
50 parts per hundred parts rubber (phr) to 95 phr of a rubber that comprises one selected from the group consisting of the halogenated isobutylene-based rubber is selected from the group consisting of: natural rubber, polyisoprene rubber, poly(styrene-co-butadiene) rubber, polybutadiene rubber, poly(isoprene-co-butadiene) rubber, styrene-isoprene-butadiene rubber, butyl rubber, star branched butyl rubber, isobutylene-isoprene rubber, poly(isobutylene-co-alkylstyrene), a halogenated isobutylene-based rubber, polychloroprene rubber, nitrile rubber, and any combination thereof; and
wherein the rubber and the PE(D)M polymer cumulatively are 100 phr, and
wherein the rubber compound is included in a sidewall of the tire, an inner tube of the tire, an innerliner of the tire, or any combination thereof.